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Encyclopedia > Absorption refrigeration
It has been suggested that this article or section be merged with Absorptive refrigeration

The absorption refrigerator is a refrigerator that utilizes a heat source to provide the energy needed to drive the cooling system rather than being dependent on electricity to run a compressor. These refrigerators are popular where electricity is unreliable, costly, or unavailable, or where surplus heat is available, e.g., from turbine exhausts or industrial processes. Wikipedia does not have an article with this exact name. ... Absorptive refrigeration utilizes a source of heat to provide the energy needed to drive the cooling process. ... It has been suggested that Freezer be merged into this article or section. ... Lightning strikes during a night-time thunderstorm. ... A gas compressor is a mechanical device that increases the pressure of a gas by reducing its volume. ...


An absorption refrigerator is similar to a regular compressor refrigerator in that the refrigeration takes place by evaporating a liquid with a very low (sub-zero) boiling point. In both cases, when a liquid evaporates or boils, it takes some heat away with it, and can continue to do so either until the liquid is all boiled, or until everything has become so cold that the sub-zero boiling point has been reached. The difference between the two is how the gas is changed back into a liquid so that it may be used again. A regular refrigerator uses a compressor to increase the pressure on the gas, forcing it to become a liquid again. An absorption refrigerator uses a different method that requires no moving parts and is powered only by heat.

Contents

Process

A typical absorption refrigerator uses three substances: ammonia, hydrogen gas, and water. Normally, ammonia is a gas at room temperature (with a boiling point of -33°C), but the system is pressurized to the point that the ammonia is a liquid at room temperature. Ammonia is a compound of nitrogen and hydrogen with the formula NH3. ... General Name, Symbol, Number hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1, 1, s Appearance colorless Atomic mass 1. ...


The cooling cycle starts at the evaporator, where liquefied anhydrous ammonia enters. (Anhydrous means there is no water in the ammonia, which is critical for exploiting its sub-zero boiling point.) The "evaporator" contains another gas (in this case, hydrogen), whose presence lowers the partial pressure of the ammonia in that part of the system. The total pressure in the system is still the same, but now not all of the pressure is being exerted by ammonia, as much of it is due to the pressure of the hydrogen. Ammonia doesn't react with hydrogen - the hydrogen is there solely to take up space - creating a void that still has the same pressure as the rest of the system, but not in the form of ammonia. Per Dalton's law, the ammonia behaves only in response to the proportion of the pressure represented by the ammonia, as if there was a vacuum and the hydrogen wasn't there. Because a substance's boiling point changes with pressure, the lowered partial pressure of ammonia changes the ammonia's boiling point, bringing it low enough that it can now boil below room temperature, as though it wasn't under the pressure of the system in the first place. When it boils, it takes some heat away with it from the evaporator - which produces the "cold" desired in the refrigerator. As a general term, a substance is said to be anhydrous if it contains no water. ... In a mixture of ideal gases, each gas has a partial pressure which is the pressure which the gas would have if it alone occupied the volume. ... In chemistry and physics, Daltons law (also called Daltons law of partial pressures) states that the total pressure exerted by a gaseous mixture is equal to the sum of the partial pressures of each individual component in a gas mixture. ... In a mixture of ideal gases, each gas has a partial pressure which is the pressure which the gas would have if it alone occupied the volume. ...


The next step is getting the liquid ammonia back, as now it's a gas and mixed with hydrogen. Getting the hydrogen away is simple, and this is where the "absorber" comes in. Ammonia readily mixes with water, and hydrogen does not. The absorber is simply a downhill flow of tubes in which the mixture of gases flows in contact with water being dripped from above. Once the water reaches the bottom, it's thoroughly mixed with the ammonia, and the hydrogen stays still (though it can flow freely back to the evaporator).


At this point, the ammonia is a liquid mixed with water and still not usable for refrigeration, as the mixture won't boil at a low enough temperature to be a worthwhile refrigerant. It's now necessary to separate the ammonia from the water. This is where the heat from the flame comes in. When the right amount of heat is applied to the mixture, the ammonia bubbles out. This phase is called the "generator". The ammonia isn't quite dry yet - the bubbles contain gas but they're made of water, so the pipe twists and turns and contains a few minor obstacles that pop the bubbles so the gas can move on. The water that results from the bubbles isn't bad - it takes care of another need, and that is the circulation of water through the previous absorption step. Because that water has risen a bit while it was bubbling upwards, the flow of that water falling back down due to gravity can be used for this purpose. The maze that makes the ammonia gas go one way and the bubble water go the other is called the "separator".


The next step is the condenser. The condenser is a sort of heat sink or heat exchanger that cools the hot ammonia gas back down to room temperature. Because of the pressure and the purity of the gas (there is no hydrogen here), the ammonia condenses back into a liquid, and at that point, it's suitable as a refrigerant and the cycle starts over again. This article or section does not cite its references or sources. ... A heat exchanger is a device built for efficient heat transfer from one fluid to another, whether the fluids are separated by a solid wall so that they never mix, or the fluids are directly contacted. ...


History

The absorption refrigerator was invented by Baltzar von Platen and Carl Munters in 1922, while they were still students at the Royal Institute of Technology in Stockholm, Sweden. Commercial production began in 1923 by the newly formed company AB Arctic, which was bought by Electrolux in 1925. Baltzar von Platen ( 1898- 1984) together with Carl Munters was the inventor of the gas absorption refrigerator in 1922 while they were both Swedish engineering students at the Royal Institute of Technology in Stockholm, Sweden. ... 1922 (MCMXXII) was a common year starting on Sunday (see link for calendar). ... The Royal Institute of Technology or Kungliga tekniska högskolan (KTH) is a university in Stockholm, Sweden. ...   (IPA: ; UN/LOCODE: SE STO) is the capital of Sweden, and consequently the site of its Government and Parliament as well as the residence of the Swedish head of state, King Carl XVI Gustaf. ... 1923 (MCMXXIII) was a common year starting on Monday (link will take you to calendar). ... Electrolux is a Swedish company that is the worlds largest manufacturer of kitchen, cleaning and outdoor appliances for both home and professional use. ... 1925 (MCMXXV) was a common year starting on Thursday (link will take you to calendar). ...


Bibliography

In Swedish:

  • Baltzar von Platen and Carl Munters, Om alstring av kyla (1925)

There are few good explanations on the web of how gas absorption refrigerators work, and some very bad ones. A useful reference is:

There is another explanation here with a helpful diagram -- both possibly originated from Elecrolux:

This goes into great detail:

  • Ohio State University Center of Excellence in Absorption Technology: Theory of Heat Pump Operation

This is a home-made absorptive refrigerator:

  • Some home made icyballs including instructions and diagrams

Source

  • Air Conditioning Thermodynamics

See also


  Results from FactBites:
 
Gas-absorption refrigerator - Wikipedia, the free encyclopedia (936 words)
The absorption refrigerator is a refrigerator that utilizes a heat source to provide the energy needed to drive the cooling system rather than being dependent on electricity to run a compressor.
An absorption refrigerator is similar to a regular compressor refrigerator in that the refrigeration takes place by evaporating a liquid with a very low (sub-zero) boiling point.
The absorption refrigerator was invented by Baltzar von Platen and Carl Munters in 1922, while they were still students at the Royal Institute of Technology in Stockholm, Sweden.
Refrigerator - Wikipedia, the free encyclopedia (2031 words)
Practical household refrigerators were introduced in the 1920s and gained wider acceptance in the 1930s as prices fell and non-toxic, nonflammable synthetic refrigerants, such as Freon or R-12 refrigerants were introduced.
The first known artificial refrigeration was demonstrated by William Cullen at the University of Glasgow in the mid 1700s, and relied on the vapor-compression refrigeration process explained by Michael Faraday.
An increasingly important environmental concern is the disposal of old refrigerators - initially because of the freon coolant damaging the ozone layer, but as the older generation of refrigerators disappears it is the destruction of CFC-bearing insulation which causes concern.
  More results at FactBites »


 

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