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Encyclopedia > Adiabatic process (quantum mechanics)

In quantum mechanics, an adiabatic process is an infinitely slow change in the Hamiltonian of a system. Adiabatic processes are important idealizations of "sufficiently slow" processes and bear important consequences for quantum mechanics (see adiabatic theorem).


Note that the term "adiabatic" is traditionally used in thermodynamics to describe processes without the exchange of heat between system and environment (see adiabatic process). The definition above is closer to the thermodynamical concept of a quasistatic process, and has no direct relation with heat exchange. These two different definitions can be the source of much confusion, especially when the two concepts (heat exchange and sufficiently slow processes) are present in a given problem.


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  Results from FactBites:
 
Adiabatic process (1056 words)
Another example is the adiabatic flame temperature, which is the temperature that would be achieved by a flame in the absence of heat loss to the surroundings.
Adiabatic heating and cooling are processes that commonly occur due to a change in the pressure of a gas.
In quantum mechanics, an adiabatic change is a sufficiently slow change in the Hamiltonian which would result only in a change of eigenvalues, not eigenstates.
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