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Encyclopedia > Ammonium carbonate
Ammonium carbonate
Image:Ammonium carbonate.png
General
Systematic name Ammonium carbonate
Molecular formula (NH4)2CO3
Molar mass 96.09 g/mol
Appearance White powder
CAS number [506-87-6]
Properties
Density and phase 1.50 g/cm³, solid
Solubility in water Soluble, decomposes in hot water
Melting point 58 °C
Boiling point Decomposes
Acidity (pKa)  ?
Structure
Crystal structure  ?
Hazards
MSDS External MSDS
Main hazards Irritant
NFPA 704

IUPAC nomenclature is a system of naming chemical compounds and of describing the science of chemistry in general. ... A chemical formula (also called molecular formula) is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... Molar mass is the mass of one mole of a chemical element or chemical compound. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences, mixtures and alloys. ... Density, or volumic mass (ISO 31), is a measure of mass per unit volume. ... In the physical sciences, a phase is a set of states of a macroscopic physical system that have relatively uniform chemical composition and physical properties (i. ... It has been suggested that Solid solubility be merged into this article or section. ... This article describes water from a scientific and technical perspective. ... The melting point of a crystalline solid is the temperature at which it changes state from solid to liquid. ... The boiling point of a substance is the temperature at which it can change its state from a liquid to a gas throughout the bulk of the liquid at a given pressure. ... In chemistry and biochemistry, the acid dissociation constant, the acidity constant, or the acid-ionization constant (Ka) is a specific type of equilibrium constant that indicates the extent of dissociation of hydrogen ions from an acid. ... Enargite crystals In mineralogy and crystallography, a crystal structure is a unique arrangement of atoms in a crystal. ... An example MSDS in a US format provides guidance for handling a hazardous substance and information on its composition and properties. ... The examples and perspective in this article or section may not represent a worldwide view. ... NFPA 704 is a standard maintained by the U.S. National Fire Protection Association. ... Image File history File links NFPA_704. ...

0
2
2
 
Flash point  ?°C
R/S statement R: ?
S: ?
RTECS number  ?
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other anions Ammonium nitrate, ammonium sulfate, ammonium chloride
Other cations  ?
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

Ammonium carbonate. The commercial salt was formerly known as sal volatile or salt of hartshorn and was formerly obtained by the dry distillation of nitrogenous organic matter such as hair, horn, decomposed urine, etc., but is now obtained by heating a mixture of ammonium chloride, or ammonium sulfate and chalk, to redness in iron retorts, the vapours being condensed in leaden receivers. The crude product is refined by sublimation, when it is obtained as a white fibrous mass, which consists of a mixture of ammonium hydrogen carbonate, NH4HCO3, and ammonium carbamate, NH2COONH4, in molecular proportions; on account of its possessing this constitution it is sometimes called ammonium sesquicarbonate. It possesses a strong ammoniacal smell, and on digestion with alcohol the carbamate is dissolved and a residue of ammonium bicarbonate is left; a similar decomposition taking place when the sesquicarbonate is exposed to air. Ammonia gas passed into a strong aqueous solution of the sesquicarbonate converts it into normal ammonium carbonate, (NH4)2CO3, which can be obtained in the crystalline condition from a solution prepared at about 30 °C. This compound on exposure to air gives off ammonia and passes back to ammonium bicarbonate. The flash point of a flammable liquid is the lowest temperature at which it can form an ignitable mixture with air. ... Risk and Safety Statements, also known as R/S statements, R/S numbers, R/S phrases, and R/S sentences, is a system of hazard codes and phrases for labeling dangerous chemicals and compounds. ... R-phrases are defined in Annex III of European Union Directive 67/548/EEC: Nature of special risks attributed to dangerous substances and preparations. ... S-phrases are defined in Annex IV of European Union Directive 67/548/EEC: Safety advice concerning dangerous substances and preparations. ... RTECS, also known as Registry of Toxic Effects of Chemical Substances, is a database of toxicity information compiled from the open scientific literature that is available for charge. ... The refractive index (or index of refraction) of a material is the factor by which the phase velocity of electromagnetic radiation is slowed in that material, relative to its velocity in a vacuum. ... The dielectric constant εr (represented as or K in some cases) is defined as the ratio: where εs is the static permittivity of the material in question, and ε0 is the vacuum permittivity. ... Ultraviolet-Visible Spectroscopy or Ultraviolet-Visible Spectrophotometry (UV/ VIS) involves the spectroscopy of photons (spectrophotometry). ... IR spectrum of a thin film of liquid ethanol. ... Nuclear Magnetic Resonance Spectroscopy most commonly known as NMR Spectroscopy is the name given to the technique which exploits the magnetic properties of nuclei. ... Basic schematic of a mass spectrometer Mass spectrometry (also known as mass spectroscopy (deprecated)[1] or in common speech mass-spec) is an analytical technique used to measure the mass-to-charge ratio of ions. ... Multivalent redirects here. ... This article or section does not cite its references or sources. ... Ammonium sulfate, (NH4)2SO4, sometimes known as Mohrs Salt, is a chemical compound commonly used as a fertilizer. ... Ammonium chloride or Sal Ammoniac (chemically ammonium chloride (NH4Cl); also nushadir salt, zalmiak, sal armagnac, sal armoniac, salmiakki, salmiak and salt armoniack) is, in its pure form, a clear white water-soluble crystalline salt with a biting taste. ... Multivalent redirects here. ... In chemistry, the standard state of a material is its state at 1 bar (100 kilopascals) and 25 degrees Celsius (298. ... Dry distillation is the heating of solid materials to produce liquid or gaseous products (which may condense into solids). ... Ammonium chloride or Sal Ammoniac (chemically ammonium chloride (NH4Cl); also nushadir salt, zalmiak, sal armagnac, sal armoniac, salmiakki, salmiak and salt armoniack) is, in its pure form, a clear white water-soluble crystalline salt with a biting taste. ... Ammonium sulfate, (NH4)2SO4, sometimes known as Mohrs Salt, is a chemical compound commonly used as a fertilizer. ... The Needles, part of the extensive Southern England Chalk Formation. ... General Name, Symbol, Number iron, Fe, 26 Chemical series transition metals Group, Period, Block 8, 4, d Appearance lustrous metallic with a grayish tinge Atomic mass 55. ... For PB or pb as an abbreviation, see PB. General Name, Symbol, Number lead, Pb, 82 Chemical series poor metals Group, Period, Block 14, 6, p Appearance bluish white Atomic mass 207. ...


Ammonium carbonate is used when crushed as a smelling salt. It can be crushed when needed in order to revive someone that has fainted. It is also known as "baker's ammonia" and was a forerunner to the more modern leavening agents baking soda and baking powder. Smelling salts are also known as ammonium carbonate, a whitish, crystalline solid ((NH3)2CO3H2O). ... Sodium bicarbonate (NaHCO3), or sodium hydrogen carbonate, also known as baking soda and bicarbonate of soda, is a soluble white anhydrous or crystalline compound, with a slight alkaline taste resembling that of sodium carbonate. ... Baking powder Baking Powder is a dry chemical leavening agent used in baking and deodorizing. ...


External links

  • Links to external chemical sources

  Results from FactBites:
 
522. Ammonium carbonate and ammonium hydrogen carbonate (WHO Food Additives Series 17) (2713 words)
AMMONIUM SALTS BIOCHEMICAL ASPECTS The principal source of ammonia in the body is the oxidation of glutamate by glutamate dehydrogenase, which is present in liver and other tissues.
The levels of ammonium carbonate and bicarbonate in the diet from food additive use are extremely small compared to the levels required to cause physiological changes and pose no toxicological hazard.
Toxicity of ammonium salts and urea in rabbits and goats, Nippon Chikusangaku Kaiho, 28, 185-191
  More results at FactBites »


 
 

COMMENTARY     

DR Dave (India)
13th February 2009
Sir,
I am interested to know atwhich concentrations(Minimum) of ammonia,CO2 & water, ammonium carbonate or ammonium bicarbamate will be formed?
Suppose,there is 1000 ppm of ammonia passing through 98% CO2 stream at saturation & 40°C & 1.4 kg/cm2 abs pressure. Can it form ammonium carbonate/ammonium carbamate?
Thanks

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