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Encyclopedia > Anhydrous

As a general term, a substance is said to be anhydrous if it contains no water. The way of achieving the anhydrous form differs from one substance to another. Water is a tasteless, odorless substance that is essential to all known forms of life and is known as the universal solvent. ...

Contents

Purpose

In many cases, water can prevent a reaction from happening, or form undesirable such products. To prevent this, anhydrous solvents have to be used when performing the reaction. Examples of reactions requiring the use of anhydrous solvents are the Grignard reaction and the Wurtz reaction. A Grignard Reagent is an alkyl- or aryl- magnesium halide. ... The Wurzt reaction after Charles Adolphe Wurtz is a coupling reaction in organic chemistry and organometallic chemistry where by two alkyl halides are reacted with sodium: 2 R-X + Na → R-R + 2NaX This reaction involves the radical species R.. References A. Wurtz, Ann. ...


The solvents are more commonly rendered anhydrous boiling them in presence of a hygroscopic substance; metallic sodium is one of the most common ones. Other methods include the addition of molecular sieves or alkali bases such as potassium hydroxide or barium oxide. Column solvent purification devices (generally referred to as Grubb's columns) recently became available, reducing the hazards (water reactive substances, heat) from the classical dehydrating methods.[1] General Name, Symbol, Number sodium, Na, 11 Chemical series alkali metals Group, Period, Block 1, 3, s Appearance silvery white Atomic mass 22. ... A molecular sieve is a material containing tiny pores of a precise and uniform size that is used as an adsorbent for gases and liquids. ... The chemical compound potassium hydroxide, (KOH) sometimes known as caustic potash, potassa, potash lye, and potassium hydrate, is a metallic base. ... ...


Ionic crystals

An example of anhydration can be seen in copper (II) sulfate. If the water of crystallization is removed from blue crystals of copper (II) sulfate, a white powder (anhydrous copper (II) sulfate) is formed. Copper (II) sulfate (CuSO4) is the most common copper salt, made by the action of sulfuric acid on the base copper oxide. ... Water of crystallization is water that is tightly associated with crystalline metal salts, and remains after drying in a fixed proportion to the salt. ...


The formula for anhydration of pentahydrate copper (II) sulfate (CuSO4·5H2O) is as follows:


CuSO4·5H2O + heat → CuSO4 + 5H2O


Another example is in the heating of magnesium sulfate heptahydrate, MgSO4·7H2O. On heating, it undergoes the following reaction:


MgSO4·7H2O + heat → MgSO4 + 7H2O


Gases

Several substances that exist as gases at standard conditions of temperature and pressure are commonly used as concentrated aqueous solutions. To clarify that it is the gaseous form that is being referred to, the term anhydrous is prepended to the name of the substance: Temperature and air pressure can vary from one place to another on the Earth, and can also vary in the same place with time. ...

  • gaseous ammonia is generally referred to as anhydrous ammonia to distinguish it from household ammonia, which is an ammonium hydroxide aqueous solution.
  • gaseous hydrogen chloride is generally referred to as anhydrous to distinguish it from the more commonly used 37% w/w solution in water.

Ammonia is a compound of nitrogen and hydrogen with the formula NH3. ... Main article: ammonia Ammonium hydroxide, although it doesnt exist as an isolatable chemical compound, is a name sometimes given to an aqueous solution of ammonia. ... R-phrases , S-phrases , , , , Flash point non-flammable Supplementary data page Structure and properties n, εr, etc. ...

References

  1. ^ Guidelines for solvent purification at UC Davis

  Results from FactBites:
 
Safe Handling of Anhydrous Ammonia, AEX-594 (1761 words)
Anhydrous ammonia is caustic and will cause severe bums to the eyes, skin and respiratory tract.
Anhydrous ammonia is a strong alkali that can cause death or severe injury to body tissue due to its caustic, corrosive, freezing and dehydrating action.
Anhydrous ammonia tanks should not be used to store other materials such as propane or liquefied petroleum gas.
NASD: Play it Safe with Anhydrous Ammonia (1235 words)
Anhydrous ammonia is a hydroscopic compound, which means that it seeks water from the nearest source, including the human body.
Most deaths from anhydrous ammonia are caused by severe damage to the throat and lungs from a direct blast to the face.
Anhydrous ammonia is a hydroscopic compound, which means it seeks out moisture.
  More results at FactBites »


 

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