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Encyclopedia > Arene substitution patterns

Arene substitution patterns are part of organic chemistry IUPAC nomenclature and pinpoint the position of substituents other than hydrogen in relation to each other on an aromatic hydrocarbon. Organic chemistry is the scientific study of the structure, properties, composition, reactions, and synthesis of organic compounds that by definition contain carbon. ... IUPAC nomenclature is a systematic way of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). ... In organic chemistry, a substituent is an atom or group of atoms subsituted in place of a hydrogen atom on the parent chain of a hydrocarbon. ... General Name, Symbol, Number hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1, 1, s Appearance colorless Atomic mass 1. ... An aromatic hydrocarbon (abbreviated as AH), or arene is a hydrocarbon, the molecular structure of which incorporates one or more planar sets of six carbon atoms that are connected by delocalised electrons numbering the same as if they consisted of alternating single and double covalent bonds. ...

Arene substitution patterns

In ortho-substitution, two substituents share positions next to each other and in meta-substitution the substituents occupy positions 1 and 3. In para-substitution the substituents occupy the opposite ends (positions 1 and 4). The toluidines serve as an example for this type of substitution. In special cases ipso-substitution describes two substituents sharing the same ring position in an intermediate compound in an electrophilic aromatic substitution. Meso-substitution is observed in compounds such as calixarenes and acridines and refer to the substituent occupying a benzylic position. An electrophilic aromatic substitution is a chemical reaction in which a hydrogen atom of an aromatic ring is replaced by an electrophile. ... A calixarene is a macrocycle or cyclic oligomer based on a hydroxyalkylation product of a phenol and an aldehyde [1]. The word calixarene is derived from calix or chalice because this type of molecule resembles a vase and from the word arene that refers to the aromatic building block. ... This article needs cleanup. ... Benzyl is the Organic chemistry term for the radical C6H5CH2-. It is obtained by removing a proton from benzene. ...

peri substitution

In naphtalenes substitution specifically in the 1 and 8 positions is called peri-substitution. Naphthalene (also known as naphthalin, naphthaline, tar camphor, white tar, albocarbon, or naphthene) is a crystalline white solid hydrocarbon with a typical mothball odor. ...


  Results from FactBites:
 
Aromatic hydrocarbon - Wikipedia, the free encyclopedia (434 words)
They undergo electrophilic substitution reactions and nucleophilic aromatic substitutions.
Examples of benzene compounds with just one substituent are phenol which carries a hydroxyl group and toluene with an methyl group.
When there is more than one substituent present on the ring their spatial relationship becomes important for which the arene substitution patterns ortho, meta and para are devised.
Oxidation of Methyl-Substituted Naphthalenes: Pathways in a Versatile Sphingomonas paucimobilis Strain -- Dutta et al. ... (2728 words)
The numbers of the metabolites detected are the numbers in Table 1, and the substitution patterns of the methylnaphthalene precursors are indicated in parentheses.
Bioconversion of substituted naphthalenes to the corresponding 1,2-dihydro-1,2-dihydroxy derivatives.
Arene oxides as intermediates in the oxidative metabolism of aromatic compounds.
  More results at FactBites »


 

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