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Encyclopedia > Calorie

The calorie is a unit of energy, in particular heat.[1] In most fields, its use is archaic, and the SI unit of energy, the joule, has become accepted. However, it remains in common use as a unit of food energy. It was first defined by Professor Nicolas Clément in 1824 as a kilogram-calorie, and this definition entered French and English dictionaries between 1841 and 1867. Etymology: French calorie, from Latin calor (heat). Image File history File links Question_book-3. ... For other uses, see Heat (disambiguation) In physics, heat, symbolized by Q, is energy transferred from one body or system to another due to a difference in temperature. ... Look up si, Si, SI in Wiktionary, the free dictionary. ... The joule (IPA: or ) (symbol: J) is the SI unit of energy. ... Food energy is the amount of energy in food that is available through digestion. ... Nicolas Clément (1779, Dijon - 1842) was a French physicist and chemist. ...


The unit calorie has historically been used in two major alternate definitions that differ by a factor of 1000:

  • The small calorie, gram calorie, or calorie (symbol: cal) is the amount of heat (energy) required to raise the temperature of one gram of water by 1 °C.
  • The large calorie, kilogram calorie, kilocalorie (symbol: kcal), or Calorie (capital C) is the amount of heat (energy) needed to increase the temperature of one kg of water by 1 °C, exactly 1000 small calories, or about 4.184 kJ.

The second form is the one commonly used to express food energy. Its most common name is calorie; kilocalorie is sometimes used, more often in the symbol "kcal" than in the spelled out word. The degree Celsius (symbol: °C) is an SI derived unit of temperature. ... Kg redirects here. ... A kilojoule (abbreviation: kJ) is a unit of energy equal to 1000 joules. ... Food energy is the amount of energy in food that is available through digestion. ...


Apart from these two major alternate definitions, there exist also minor variants of the definition of this unit, which differ in the exact experimental conditions used, most notably the start temperature of the water (see section below).


The factors used to convert measurements in calories to their equivalents in joules are numerically equivalent to expressions of the specific heat capacity of water in SI units. See "Versions" below for an explanation of the units. Specific heat capacity, also known simply as specific heat, is the measure of the heat energy required to increase the temperature of a unit quantity of a substance by a certain temperature interval. ... Impact from a water drop causes an upward rebound jet surrounded by circular capillary waves. ... The International System of Units (symbol: SI) (for the French phrase Système International dUnités) is the most widely used system of units. ...

1 calIT = 4.1868 J (1 J = 0.23885 calIT) (International Steam Table calorie, 1956)
1 calth = 4.184 J (1 J = 0.23901 calth) (Thermochemical calorie)
1 cal15 = 4.18580 J (1 J = 0.23890 cal15) (15°C calorie)

Versions

The energy needed to increase the temperature of a gram of water by 1 degree Celsius depends on the starting temperature and is difficult to measure precisely. Accordingly, there have been several definitions of the calorie: The degree Celsius (symbol: °C) is an SI derived unit of temperature. ...

  • Thermochemical calorie (calth): 4.184 J exactly.[1]
  • 15 °C calorie (cal15): the amount of energy required to warm 1 g of air-free water from 14.5 °C to 15.5 °C at a constant pressure of 101.325 kPa (1 atm). Experimental values of this calorie ranged from 4.1852 J to 4.1858 J. The CIPM in 1950 published a mean experimental value of 4.1855 J, noting an uncertainty of 0.0005 J.[1]
  • 20 °C calorie: the amount of energy required to warm 1 g of air-free water from 19.5 °C to 20.5 °C at a constant pressure of 101.325 kPa (1 atm). This is about 4.182 J.
  • 4 °C calorie: the amount of energy required to warm 1 g of air-free water from 3.5 °C to 4.5 °C at a constant pressure of 101.325 kPa (1 atm).
  • Mean calorie: 1/100 of the amount of energy required to warm 1 g of air-free water from 0 °C to 100 °C at a constant pressure of 101.325 kPa (1 atm). This is about 4.190 J
  • International Steam Table Calorie (1929): (1/860) W h = (180/43) J exactly. This is approximately 4.1868 J.
  • International Steam Table Calorie (1956) (calIT): 1.163 mW h = 4.1868 J exactly. This definition was adopted by the Fifth International Conference on Properties of Steam (London, July 1956).[1]
  • IUNS calorie: 4.182 J exactly. This is a definition implied by the Committee on Nomenclature of the International Union of Nutritional Sciences.[citation needed]

The two perhaps most popular definitions used in older literature are the "15 °C calorie" and the "thermochemical calorie". Since the many different definitions are a source of confusion and error, all calories are now deprecated in favour of the SI unit for heat and energy: the joule (J). The world’s first ice-calorimeter, used in the winter of 1782-83, by Antoine Lavoisier and Pierre-Simon Laplace, to determine the heat evolved in various chemical changes; calculations which were based on Joseph Black’s prior discovery of latent heat. ... Standard atmosphere (symbol: atm) is a unit of pressure. ... The Comité international des poids et mesures or The International Committee for Weights and Measures (CIPM) consists of eighteen persons from Member States of the Metre Convention. ... Standard atmosphere (symbol: atm) is a unit of pressure. ... Standard atmosphere (symbol: atm) is a unit of pressure. ... Standard atmosphere (symbol: atm) is a unit of pressure. ... For other uses, see Watt (disambiguation). ... For other uses, see Watt (disambiguation). ... Look up Deprecation in Wiktionary, the free dictionary. ... Look up si, Si, SI in Wiktionary, the free dictionary. ... The joule (IPA: or ) (symbol: J) is the SI unit of energy. ...


References

  1. ^ a b c d International Standard ISO 31-4: Quantities and units – Part 4: Heat. Annex B (informative): Other units given for information, especially regarding the conversion factor. International Organization for Standardization, 1992.
ISO 31-4 is the part of international standard ISO 31 that defines names and symbols for quantities and units related to heat. ... “ISO” redirects here. ...

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