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Encyclopedia > Chemical law

Chemical Laws are the Laws of nature relevant to chemistry. The most fundamental concept in chemistry is the law of conservation of mass, which states that there is no detectable change in the quantity of matter during an ordinary chemical reaction. Modern physics shows that it is actually energy that is conserved, and that energy and mass are related; a concept which becomes important in nuclear chemistry. Conservation of energy leads to the important concepts of equilibrium, thermodynamics, and kinetics. The Laws of Nature are claimed in the United States Declaration of Independence to be the work of the Creator of unalienable rights identified as Natures God. ... Chemistry (derived from the Arabic word kimia, alchemy, where al is Arabic for the) is the science of matter that deals with the composition, structure, and properties of substances and with the transformations that they undergo. ... The law of conservation of mass states that the mass of a system of substances will always remain constant, regardless of the processes acting inside the system. ... A chemical reaction is a process that results in the interconversion of Chemical substances . ... For other topics related to Einstein see Einstein (disambiguation). ... Nuclear chemistry is a subfield of chemistry dealing with radioactivity, nuclear processes and nuclear properties. ... Conservation of energy is possibly the most important, and certainly the most practically useful of several conservation laws in physics. ... Chemical equilibrium is the state in which a chemical reaction proceeds at the same rate as its reverse reaction; the rates of the forward and reverse reactions are equal, and the concentration of the reactants and products stop changing. ... Thermodynamics (from the Greek thermos meaning heat and dynamis meaning power) is a branch of physics that studies the effects of temperature, pressure, and volume changes on physical systems at the macroscopic scale. ... In physical chemistry, chemical kinetics or reaction kinetics study reaction rates in a chemical reaction. ...


Further laws of chemistry elaborate on the law of conservation of mass. Joseph Proust's law of definite composition says that pure chemicals are composed of elements in a definite formulation; we now know that the structural arrangement of these elements is also important. Joseph Louis Proust (September 26, 1754 - July 5, 1826) was a French chemist. ... One of the fundamental observations of modern chemistry, the law of definite proportions states that, in a pure compound, the elements combine in definite proportions to each other. ...


Dalton's law of multiple proportions says that these chemicals will present themselves in proportions that are small whole numbers (i.e. 1:2 O:H in water); although in many systems (notably biomacromolecules and minerals) the ratios tend to require large numbers, and are frequently represented as a fraction. Such compounds are known as non-stoichiometric compounds John Dalton John Dalton (September 6, 1766 – July 27, 1844) was a British chemist and physicist, born at Eaglesfield, near Cockermouth in Cumberland. ... In chemistry, the law of multiple proportions is one of the basic laws of stoichiometry, alongside the law of definite proportions. ... In chemistry, stoichiometry is the study and calculation of quantitative (measurable) relationships of the reactants and products in chemical reactions (chemical equations). ...


More modern laws of chemistry define the relationship between energy and transformations.

  • In equilibrium, molecules exist in mixture defined by the transformations possible on the timescale of the equilibrium, and are in a ratio defined by the intrinsic energy of the molecules—the lower the intrinsic energy, the more abundant the molecule.
  • Transforming one structure to another requires the input of energy to cross an energy barrier; this can come from the intrinsic energy of the molecules themselves, or from an external source which will generally accelerate transformations. The higher the energy barrier, the slower the transformation occurs.
  • There is a hypothetical intermediate, or transition structure, that corresponds to the structure at the top of the energy barrier. The Hammond-Leffler Postulate states that this structure looks most similar to the product or starting material which has intrinsic energy closest to that of the energy barrier. Stabilizing this hypothetical intermediate through chemical interaction is one way to achieve catalysis.
  • All chemical processes are reversible (law of microscopic reversibility) although some processes have such an energy bias, they are essentially irreversible.


 
 

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