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Encyclopedia > Chemical resonance

Resonance structures are diagrammatic tools in organic chemistry to symbolize resonant bonds between atoms in molecules. Essentially, these resonance bonds are the movement of "delocalized" electrons through the molecule. Resonance structures all have the same chemical formula and same general shape. However, unshared pairs of electrons and electron pairs making double bonds will often move around between bonds and molecules. For simple molecules like benzene, there are only two resonance forms. For more complex molecules, there are hundreds of possible resonance forms. Organic chemistry is the scientific study of the structure, properties, composition, reactions, and synthesis of organic compounds. ... Properties For alternative meanings see atom (disambiguation). ... In science, a molecule is the smallest particle of a pure chemical substance that still retains its chemical composition and properties. ... In chemistry, delocalized electrons are electrons in a molecule that do not belong to a single atom or a covalent bond. ... Properties The electron (sometimes called negatron; commonly represented as e−) is a subatomic particle. ... A chemical formula (also called molecular formula) is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... Covalent bonding is a form of chemical bonding characterized by the sharing of one or more pairs of electrons between atoms, in order to produce a mutual attraction, which holds the resultant molecule together. ... Benzene, C6 H6, PhH, or benzol is a colorless and flammable liquid with a pleasant, sweet smell. ...


For example, for benzene rings, the alternating structure of double bonds in the ring structure are often drawn as a circle. Benzene, C6H6, PhH, or benzol is a colorless and flammable liquid with a pleasant, sweet smell. ...


It is important to note that resonance structures do not represent different structures at all. In the example of benzene, for example, there are two important resonance structures. However, this doesn't mean there are two types of benzene; rather, the true structure of benzene is somewhere in between, constantly in flux. This is why a benzene ring is often shown with a circle inside rather than alternating double bonds — the latter example is theoretically incorrect.


Resonance occurs because of the properties of certain bonds. Double bonds are made up of pi bonds, which connect 2p orbitals. The electrons in these pi bonds, however, are considered to be delocalized; if possible, they will move around. Unshared electrons can be moved about as well, but only if they're in a position to do so. Electrons MUST be in the pi bonds to be delocalized. Often, a sp2 hybrid orbital will be filled with a pair of unshared electrons. While it seems reasonable that they'd want to move about, it is geometrically impossible. The sp2 hybridized orbital is perpendicular to the 2p orbital the pi bonds will be interested in. Geometry of the water molecule Molecules have fixed equilibrium geometries--bond lengths and angles--that are dictated by the laws of quantum mechanics. ... The term orbital has several meanings: in physics and chemistry it is used to describe an atomic electron configuration, see also molecular orbital and atomic orbital. ...


Resonance is essential to stability, and stability is a "goal" for all molecules. It would be incorrect to apply a human emotion to a molecule, but it is a reasonable analogy: molecules "want" to be as stable as possible. The movement of the electrons through the pi bonds increases this stability.


To be an important resonance structure, the atomic structure of the atom must be the same throughout all resonance forms. In more scientific terms, the sigma skeleton must remain the same (sigma bonds are single bonds). Furthermore, it must be a correct Lewis Structure, and it must have the same charge. Arbitrary separation of charge causes the importance of a resonance form to go down considerably. However, unimportant does not mean impossible — simply improbable. Geometry of the water molecule Molecules have fixed equilibrium geometries--bond lengths and angles--that are dictated by the laws of quantum mechanics. ... Categories: Chemistry stubs | Chemistry ... Electric charge is a fundamental FATTY STASHEconserved property of some subatomic particles, which determines their electromagnetic interactions. ...


Resonance is an important concept of organic chemistry. It will usually be tested for on the MCAT, and is essential to learning the basics of organic chem. Organic chemistry is the scientific study of the structure, properties, composition, reactions, and synthesis of organic compounds. ... The Medical College Admission Test (MCAT) is a standardized test administered by the Association of American Medical Colleges (AAMC) to prospective medical students as a means to standardise comparison between them for purposes of admission to medical school. ...


[diagrams soon to come]


  Results from FactBites:
 
Resonance (chemistry) - Wikipedia, the free encyclopedia (892 words)
Resonance contributors for the same molecule all have the same chemical formula and same sigma framework, but the pi electrons will be distributed differently among the atoms.
Resonance occurs because of the overlap of orbitals.
Resonance should also not be confused with a chemical equilibrium or tautomerism which are equilibria between distinct compounds that have different sigma bonding patterns.
Kostas Gavroglu and Ana Simões : The Americans, the Germans, and the beginnings of quantum chemistry: The ... (13261 words)
With an eye to future chemical applications Mulliken remarked that, besides their purely theoretical importance, a knowledge of the numerous excited states and chemically unstable molecules was indispensable in deducing the electron configurations for stable molecules and the intermediate steps in chemical reactions.
The chemical behavior of molecules was the primary concern of the pragmatic chemist, rather than the imposition of an electronic notation complicated by metaphysical speculations.
Mulliken suggested that chemical binding could best be understood in terrms of quantum numbers of individual electrons and their changes in moving from the united atom to the molecule, as well as in tenns of the energy relations resulting when going from the separated atoms to the molecule.
  More results at FactBites »


 

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