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Encyclopedia > Chloropicrin
Chloropicrin
Discovery
Discovered by ?
Discovered in ?
Chemical characteristics
Chemical name Trichloronitromethane
Chemical family ?
Chemical formula CCl3NO2
CAS number 76-06-2
Boiling point 112 °C (234 °F)
Freezing/melting point -69.2 °C (-92.6 °F)
Vapor pressure ? mmHg (? Pa) at 25 °C
Vapor relative density (air=1) ?
Solubility in water ?
Density at 25 °C ? g/cm3
Appearance and color Colorless / faint yellow

Chloropicrin is a slightly oily, colorless or faintly yellow liquid of the formula CCl3NO2. Its freezing point is -69.2 °C and its boiling point is 112 °C, where it partially decomposes to phosgene and nitrosyl chloride. It is denser than water. It is more toxic than chlorine but less than phosgene. Its CAS number is [76-06-2][1]. Image File history File links Download high resolution version (1083x844, 19 KB) Summary Description: Structural formula of chloropicrin (Trichloronitromethane; CCl3NO2). ... The International Union of Pure and Applied Chemistry (IUPAC) is an international non-governmental organization devoted to the advancement of chemistry. ... A chemical formula (also called molecular formula) is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences, mixtures and alloys. ... The boiling point of a substance is the temperature at which it can change its state from a liquid to a gas throughout the bulk of the liquid at a given pressure. ... The melting point of a solid is the temperature at which it changes state from solid to liquid. ... Vapor pressure is the pressure of a vapor in equilibrium with its non-vapor phases. ... Relative density (also known as specific gravity) is a measure of the density of a material. ... A substance is soluble in a fluid if it dissolves in that fluid. ... Density (symbol: ρ - Greek: rho) is a measure of mass per unit of volume. ... Variation in the physical appearance of humans is believed by anthropologists to be an important factor in the development of personality and social relations in particular physical attractiveness. ... Color is an important part of the visual arts. ... General Name, Symbol, Number carbon, C, 6 Chemical series nonmetals Group, Period, Block 14, 2, p Appearance black (graphite) colorless (diamond) Atomic mass 12. ... General Name, Symbol, Number chlorine, Cl, 17 Chemical series halogens Group, Period, Block 17, 3, p Appearance yellowish green Atomic mass 35. ... General Name, Symbol, Number nitrogen, N, 7 Chemical series nonmetals Group, Period, Block 15, 2, p Appearance colorless Atomic mass 14. ... General Name, Symbol, Number oxygen, O, 8 Chemical series Nonmetals, chalcogens Group, Period, Block 16, 2, p Appearance colorless Atomic mass 15. ... Phosgene (also known as carbonyl chloride, COCl2) is a highly toxic gas or refrigerated liquid that was used as a chemical weapon in World War I. It has no color, but is detectable in air by its odor, which resembles moldy hay. ... General Name, Symbol, Number chlorine, Cl, 17 Chemical series halogens Group, Period, Block 17, 3, p Appearance yellowish green Atomic mass 35. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences and alloys. ...


Chloropicrin vapor is highly poisonous if inhaled. In WWI it was used as a poison gas. After WW II, however, the importance of Chloropikrin for military use decreased and, today, has vanished. In the chemical industry, it is widely used for organic synthesis, in fumigants, in fungicides and insecticides, and for the extermination of rats. Chloropicrin is a relatively stable liquid that is prepared by the reaction of picric acid with calcium hypochlorite, by the addition of nitrogen to chlorinated hydrocarbons, or by chlorinating nitromethane. In environment it undergoes photolysis. Dressing the wounded during a gas attack by Austin O. Spare, 1918. ... Organic synthesis is the construction of organic molecules via chemical processes. ... Fumigation is a method of pest control that completely fills an area with gaseous pesticides to suffocate or poison the pests within. ... A Fungicide is one of three main methods of pest control- chemical control of fungi in this case. ... A insecticide is a pesticide used against insects in all development forms. ... Species 50 species; see text *Several subfamilies of Muroids include animals called rats. ... Picric acid is the common term for the chemical compound 2,4,6-trinitrophenol, also known as TNP; the material is a yellow crystalline solid. ... It has been suggested that this article or section be merged with Calcium oxy chloride. ... Flash point 35 °C R/S statement R: S: RTECS number PA9800000 Related compounds Related nitro compounds nitroethane Related compounds methyl nitrite methyl nitrate Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references Nitromethane is an organic... Photolysis refers to any chemical reaction in which a compound is broken down by light. ...


Chloropicrin was used in World War I as a chemical weapon, called PS by British, Aquinite by French, and Klop (green cross) by Germans. See also Use of poison gas in World War I. Combatants Allies: Serbia, Russia, France, Romania, Belgium, British Empire, United States, Italy, and others Central Powers: Germany, Austria-Hungary, Bulgaria, Ottoman Empire Casualties Military dead: 5 million Civilian deaths: 3 million Total of dead: 8 million Military dead: 4 million Civilian deaths: 3 million Total dead: 7 million The First... Dressing the wounded during a gas attack by Austin O. Spare, 1918. ... A poison gas attack in World War I. The use of poison gas was a major military innovation of the First World War. ...


Chloropicrin is used for fumigation, to sterilize soil and seed. Fumigation is a method of pest control that completely fills an area with gaseous pesticides to suffocate or poison the pests within. ... Sterilization can mean: Sterilization (surgical procedure) - an operation which renders an animal or human unable to procreate Sterilization (microbiology) - the removal of microbiological organisms This is a disambiguation page — a navigational aid which lists other pages that might otherwise share the same title. ... Soil is the material on the surface of a lithosphere subject to weathering, and especially the earthy portion of that material. ... A ripe red jalapeno cut open to show the seeds For other uses, see Seed (disambiguation). ...


As a chemical warfare agent it is known as PS and it is a powerful irritant from the group of pulmonary agents. It causes lachrymation, vomiting, bronchitis, and pulmonary edema; the lung injury can be fatal. Very low concentrations cause burning sensation of the eyes, which may serve as a warning. Because of its relative inertness and the small size of its molecule, chloropicrin penetrates gas mask filters. It then causes vomiting, which makes the victim remove the gas mask. For this reason, it is often mixed with other chemical weapons. Chemical warfare is warfare (and associated military operations) using the toxic properties of chemical substances to kill, injure or incapacitate an enemy. ... Categories: Chemical weapons | Stub ... Tears trickling down the cheeks Lacrimation is the bodys process of producing tears, which are a liquid to clean and lubricate the eyes. ... Although it has probably evolved as a mechanism for expelling ingested poisons, vomiting (or emesis)may result from many causes not related to poisoning, ranging from gastritis to brain tumors, or elevated intracranial pressure (ICP). ... Bronchitis is an obstructive pulmonary disease characterized by inflammation of the bronchi of the lungs. ... Pulmonary edema is swelling and/or fluid accumulation in the lungs. ... The lungs flank the heart and great vessels in the chest cavity. ... Belgian 1930s era L.702 model civilian mask A gas mask, is a mask worn on the face to protect the body from airborne pollutants and toxic materials. ...



This article forms part of the series
Chemical warfare
Blood agents: Cyanogen chloride (CK) – Hydrogen cyanide (AC)
Blister agents: Lewisite (L) – Sulfur mustard gas (HD, H, HT, HL, HQ) – Nitrogen mustard gas (HN1, HN2, HN3)
Nerve agents: G-Agents: Tabun (GA) – Sarin (GB) – Soman (GD) – Cyclosarin (GF) | V-Agents: VEVGVMVX
Pulmonary agents: ChlorineChloropicrin (PS) – Phosgene (CG) – Diphosgene (DP)
Incapacitating agents: Agent 15 (BZ) – KOLOKOL-1
Riot control agents: Pepper spray (OC) – CS gasCN gasCR gas .

  Results from FactBites:
 
U.S. EPA: Chloropicrin on California Strawberries (1765 words)
Chloropicrin currently appears to offer advantages as a soil fumigant because its use parameters are relatively familiar to applicators and its efficacy on economically important pests has been well documented.
Chloropicrin is not considered to pose a threat to the ozone layer, it undergoes rapid degradation in sunlight, it is metabolized in soil to form carbon dioxide, and is not expected to accumulate in plant tissue.
Chloropicrin is best known for its wide spectrum effectiveness in controlling soilborne fungi; however, it has particular effectiveness in controlling several genera, including Ceratobasidium, Colletotrichum, Cylindrocarpon, Fusarium, Idriella, Phytophthora, Pyrenochaeta, Pythium, Rhizoctonia, and Verticillium, all of which are known to cause root rot and/or wilt diseases in strawberries (Wilhelm and Westerlund 1993, Maas 1984).
Chloropicrin - Wikipedia, the free encyclopedia (359 words)
Chloropicrin is a relatively stable liquid that is prepared by the reaction of picric acid with calcium hypochlorite, by the addition of nitrogen to chlorinated hydrocarbons, or by chlorinating nitromethane.
Chloropicrin was used in World War I as a chemical weapon, called PS by British, Aquinite by French, and Klop (green cross) by Germans.
Chloropicrin is used for fumigation, to sterilize soil and seed.
  More results at FactBites »


 
 

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