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Encyclopedia > Cycloalkane
cyclobutane
cyclobutane

Cycloalkanes (also called naphthenes) are chemical compounds with one or more carbon rings to which hydrogen atoms are attached according to the formula CnH2n. Cycloalkanes with a single ring are named analogously to their normal alkane counterpart of the same carbon count: cyclopropane, cyclobutane, cyclopentane, cyclohexane, etc. The larger cycloalkanes, with greater than 20 carbon atoms are typically called cycloparaffins. from rozeta File links The following pages link to this file: Cycloalkane Categories: Public domain images ineligible for copyright ... A chemical compound is a chemical substance consisting of two or more different chemically bonded chemical elements, with a fixed ratio determining the composition. ... General Name, Symbol, Number carbon, C, 6 Chemical series nonmetals Group, Period, Block 14, 2, p Appearance black (graphite) colorless (diamond) Standard atomic weight 12. ... General Name, Symbol, Number hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1, 1, s Appearance colorless Atomic mass 1. ... Chemical structure of methane, the simplest alkane Alkanes are chemical compounds that consists only of the elements carbon (C) and hydrogen (H) (i. ... Molecule structure formula of cyclopropane Cyclopropane is a cycloalkane molecule with the molecular formula C3H6 consisting of three carbon atoms linked to each other to form a ring, with each carbon atom bearing two hydrogen atoms. ... Cyclobutane, C4H8, with a molecular mass of 56. ... Cyclopentane is a highly flammable alicyclic hydrocarbon with chemical formula C5H10 and CAS number 287-92-3, consisting of a ring of five carbon atoms each bonded with two hydrogen atoms above and below the plane. ... Cyclohexane is a cycloalkane with the molecular formula C6H12. ...


Cycloalkanes are classified into small, normal and bigger cycloalkanes, where cyclopropane and cyclobutane are the small ones, cyclopentane, cyclohexane, cycloheptane are the normal ones, and the rest are the bigger ones.


Nomenclature

See also: IUPAC nomenclature
bicyclo[2,2,1]heptane

The naming of polycyclic alkanes such as bicyclic alkanes and spiro alkanes is more complex, with the base name indicating the number of carbons in the ring system, a prefix indicating the number of rings (eg, "bicyclo"), and a flip numeric prefix before that indicating the number of carbons in each part of each ring, exclusive of vertices. For instance, a bicyclooctane which consists of a six-member ring and a four member ring, which share two adjacent carbon atoms which form a shared edge, is [4.2.0]-bicyclooctane. That part of the six-member ring, exclusive of the shared edge has 4 carbons. That part of the four-member ring, exclusive of the shared edge, has 2 carbons. The edge itself, exclusive of the two vertices that define it, has 0 carbons. IUPAC nomenclature is a system of naming chemical compounds and of describing the science of chemistry in general. ... Image File history File links Bicyclo2-1-1heptane. ... Image File history File links Bicyclo2-1-1heptane. ... The structure of a bicyclic molecule contains two usually fused rings. ... A spiro compound is a bicyclic organic compound with rings connected through just one atom. ...


The group of cycloalkanes are also known as naphthenes, as they are compounds of petroleum or naphtha. Pumpjack pumping an oil well near Lubbock, Texas Ignacy Łukasiewicz - inventor of the refining of kerosene from crude oil. ... Naphtha is a group of various volatile flammable liquid hydrocarbon mixtures used primarily as feedstocks in refineries for the reforming process and in the petrochemical industry for the production of olefins in steam crackers. ...


Reactions

The simple and the bigger cycloalkanes are very stable, like alkanes, and their reactions for example radical chain reactions, are like alkanes. An alkane in organic chemistry is a type of hydrocarbon in which the molecule has the maximum possible number of hydrogen atoms and so has no double bonds (they are saturated). ... In Organic chemistry, a radical substitution reaction is a substitution reaction where a radical is the intermediate and the product is an alkyl halide. ...


The small cycloalkanes - particularly cyclopropane - have a lower stability due to Baeyer strain and ring strain. They react similarly to alkenes, though they don't react in electrophilic addition but in nucleophilic aliphatic substitution. These reactions are ring opening reactions or ring cleavage reactions of alkyl cycloalkanes. Cycloalkanes can be formed in a Diels-Alder reaction followed by a catalytic hydrogenation. Baeyer strain theory or strain theory explains specific behaviour of chemical compounds in terms of bond angle strain. ... Ring strain is an organic chemistry term that describes the destabilization of a cyclic molecule—such as a cycloalkane—due to the non-favorable high energy spatial orientations of its atoms. ... An alkene is one of the three classes of unsaturated hydrocarbons that contain at least one carbon-carbon double bond and have the general molecular formula of CnH2n (the other two being alkynes and arenes). ... In organic chemistry, an electrophilic addition reaction is an addition reaction where in chemical compound a pi bond is removed by the creation of two new covalent bonds. ... In chemistry, nucleophilic substitution is a class of substitution reaction in which an electron-rich nucleophile attacks a molecule and replaces a group or atom, called the leaving group. ... Alkyl cycloalkanes are chemical compounds with an alkyl group with a single ring of carbons to which hydrogens are attached according to the formula CnH2n. ... The Diels-Alder reaction The Diels-Alder reaction is an organic chemical reaction (specifically, a cycloaddition) between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene system. ...


  Results from FactBites:
 
Polymerization process for cis-1,4-polybutadiene using cycloalkane solvents and an aromatic polymerization regulator - ... (0 words)
It was unexpectedly found that when a cycloalkane was used as the chief solvent in the polymerization of butadiene, the polymerization proceeded at too fast a rate as a result of which it was difficult to control the polymerization temperature.
Thus the present invention is an improved process of butadiene-1,3 polymerization employing a cycloalkane solvent and from 0.1 to 2 percent by weight of an alkyl substituted benzene as a polymerization regulator.
Cycloalkanes useful in the process are those having 5 to 8 carbon atoms in the rings.
radio SAW - Superhits für Sachsen-Anhalt (789 words)
Natürlich vorkommende Cycloalkane (Cyclopentan, Cyclohexan, Cycloheptan) wurden zuerst vom Chemiker Wladimir Wassiljewitsch Markownikow in der Rohbenzin-Fraktion, auch Naphtha genannt, des kaukasischen Erdöls gefunden.
In der Sprache der Erdölwirtschaft ist Naphthen noch heute eine gebräuchliche Bezeichnung für diese Cycloalkane.
Cycloalkane mit einem Kohlenstoffanteil von 14 bis 18 kommen zum Beispiel in Riechstoffen wie dem Moschus vor, der aus einer Drüse der Moschushirsche (Moschidae) gewonnen wird.
  More results at FactBites »


 

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