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Encyclopedia > Dehydrohalogenation

Dehydrohalogenation is an organic chemistry reaction from which an alkene is obtained from an alkyl halide. It is also called the β-Elimination reaction. Ethanolic potassium hydroxide when reacted with alkyl halide gives alkene. Organic chemistry is the part of chemistry concerned with the composition, structure, properties, reactions and synthesis of organic compounds. ... An alkene in organic chemistry is an unsaturated hydrocarbon containing at least one carbon to carbon double bond. ... In chemistry, an alkyl halide is an organic molecule of the form R_X, where X is a halide and R contains a carbon atom bonded to other functional groups or hydrogens. ...


In this reaction, the halogen on the carbon in the alkyl halide reacts with hydrogen present on the β-carbon releasing hydrogen chloride. Hence an alkene is formed due to formation of a double bond between the α- and β-carbon. The halogens are a chemical series. ... Covalent bonding is a form of chemical bonding characterized by the sharing of one or more pairs of electrons between atoms, in order to produce a mutual attraction, which holds the resultant molecule together. ...


Reactions

Image:Beta elimination.jpg


Here ethyl chloride reacts with potassium hydroxide dissolved in ethanol, giving ethane. Similarly 1 - chloropropane or 2 - chloropropane gives propane. Ethanol, also known as ethyl alcohol or grain alcohol, is a flammable, colorless chemical compound, one of the alcohols that is most often found in alcoholic beverages. ... Ethane is a chemical compound with chemical formula C2H6. ... Propane is a three-carbon alkane. ...


Chlorobenzene does not react with alcoholic potassium hydroxide. Chlorobenzene is an aromatic organic compound with the chemical formula C6H5Cl. ...


References

Dehydrohalogenation


  Results from FactBites:
 
Process and catalyst for the dehydrohalogenation of halogenated hydrocarbons - Patent 4816609 (2138 words)
What is needed is an efficient dehydrohalogenation process that would avoid the waste disposal and halogen loss problems of prior methods by providing a means for safely and economically removing any salt or hydrogen halide produced by the dehydrohalogenation reaction.
It has surprisingly been found that such a catalyst does not rapidly deactivate in typical dehydrohalogenation reactions when the catalyst is used in the presence of an alkanol and oxygen.
The process of present invention comprises contacting a halogenated hydrocarbon and an alkanol in the presence of the catalyst described hereinbefore under reaction conditions sufficient to form the corresponding unsaturated halohydrocarbon or unsaturated hydrocarbon.
E2 Elimination Reaction (1207 words)
This reaction illustrates the base-induced dehydrohalogenation of alkyl halides with strong base and is used extensively for the preparation of alkenes.
Base-induced elimination (dehydrohalogenation) of alkyl halides is a general reaction and is an excellent method for preparing alkenes.
Dehydrohalogenation of alkyl halides in the presence of strong base (E2) is often accompanied by the formation of substitution (S
  More results at FactBites »


 

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