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Encyclopedia > Delrin

Delrin is the brand name for an acetal resin engineering plastic invented and sold by DuPont. Often marketed and used as a metal substitute, Delrin is a lightweight, low-friction, and wear-resistant plastic capable of operating in temperatures in excess of 90 degrees celsius (approx 200 degrees Fahrenheit). Image File history File links Download high-resolution version (2064x1318, 18 KB) File links The following pages on the English Wikipedia link to this file (pages on other projects are not listed): Polyoxymethylene ... Image File history File links Download high-resolution version (2064x1318, 18 KB) File links The following pages on the English Wikipedia link to this file (pages on other projects are not listed): Polyoxymethylene ... It has been suggested that Delrin be merged into this article or section. ... Engineering plastics are plastics which regain their original shape after deformation. ... This article is about the DuPont company. ... Hot metal work from a blacksmith In chemistry, a metal (Greek: Metallon) is an element that readily loses electrons to form positive ions (cations) and has metallic bonds between metal atoms. ... In materials science, wear is the erosion of material from a solid surface by the action of another solid. ... Celsius is, or relates to, the Celsius temperature scale (previously known as the centigrade scale). ... Fahrenheit is a temperature scale named after the German physicist Daniel Gabriel Fahrenheit (1686–1736), who proposed it in 1724. ...


Other names for this compound include: polyoxymethylene (POM), acetal resin, polytrioxane and polyformaldehyde. It has been suggested that Delrin be merged into this article or section. ...

Contents

Uses

The Food and Drug Administration has approved Delrin for use in the food industry. Delrin was used by Mattel from 1968 to 1972 to produce the low-friction wheel bearings found on redline Hot Wheels. Delrin is made from acetal homopolymer resin & when extruded into large basic shapes (i.e.- sheets, rods & tubes) tends to be subject to porosity problems. These porosity problems can make the product less reliable in certain applications. Acetal copolymer (Acetron GP) is often used as a replacement for Delrin (acetal homopolymer) when porosity risk is a factor in material selection. The Food and Drug Administration (FDA) is an agency of the United States Department of Health and Human Services and is responsible for regulating food (humans and animal), dietary supplements, drugs (human and animal), cosmetics, medical devices (human and animal) and radiation emitting devices (including non-medical devices), biologics, and... Mattel Inc. ... Hot Wheels Car — Dodge viper Hot Wheels is a brand of die cast toy car, introduced by American toymaker Mattel in 1968. ...


It is also used extensively in paintball markers, where it is used to make bolts, pump handles and many other parts. Its low cost, adequate strength, light weight and self lubricating properties make it ideal for markers. Its competition in this area, Nylatron, while slightly lighter is more prone to swelling. A swelled part can make the mechanism impossible to operate and sometimes even damages the marker. Nylon-based products such as Nylatron have better wear-resistance than Delrin, but do not have good moisture-resistance, and therefore not suitable to high-humidity or underwater applications. A tournament player shooting from behind an inflatable bunker. ... Corrosion is deterioration of essential properties in a material due to reactions with its surroundings. ...


Delrin's resistance to liquids and low coefficient of friction have also made it useful as a bearing-replacement in casters and wheels, to be selected in cases where corrosive environments make a traditional roller or ball bearing impractical. Caster angle is the angular measure from the vertical of the suspension of a steered wheel in a car or other vehicle, measured in the longitudinal direction. ... A needle roller bearing A needle roller bearing is a bearing which uses small cylindrical rollers. ... A 4 point contact ball bearing A ball bearing is a common type of rolling-element bearing, a kind of bearing. ...


Another recent use for Delrin is in the manufacturing of Irish flutes (traditionally made of wood) and tin whistles (traditionally made of metal). Delrin flutes sound similar or identical to wooden flutes but have none of the shrinkage or cracking issues usually associated with wooden instruments in hot, cold, or dry environments. Builders such as Des Seery, Michael Cronnolly of M&E Flutes, and Tony Dixon all build Delrin flutes. To meet Wikipedias quality standards, this article or section may require cleanup. ... Tin whistles in a variety of makes and keys. ...


Delrin has become an increasingly popular material in the fabrication of guitar picks. It has excellent durability; it is much more resistant to wear than nylon at the point of string contact, especially on round wound strings. Delrin does not crack or break like celluloid or polyvinyl chloride (PVC), provides a solid, slip-free grip, and develops a "memory" over time—that is, it gradually develops a slight curvature that conforms to the user's grip. Various guitar picks. ... Nylon is a generic designation for a family of synthetic polymers first produced on February 28, 1935 by Gerard J. Berchet of Wallace Carothers research group at DuPont. ... The strings of a harp A string is the vibrating element which is the source of vibration in string instruments, such as the guitar, harp, piano, and members of the violin family. ... Celluloid is the name of a class of compounds created from nitrocellulose and camphor, plus dyes and other agents, generally regarded to be the first thermoplastic. ... Polyvinyl chloride Polyvinyl chloride, (IUPAC Polychloroethene) commonly abbreviated PVC, is a widely used thermoplastic polymer. ...


Delrin is also much treasured by many makers and players of harpsichords, being used for the plectra which pluck the strings when a key is pressed. Delrin has been found to provide a tonal quality very similar to the bird-quill used in the heyday of the instrument, while being far more durable and consistent. A harpsichord is the general term for a family of European keyboard instruments, including the large instrument nowadays called a harpsichord, but also the smaller virginals, the muselar virginals and the spinet. ... A plectrum is a device for plucking or strumming a stringed instrument. ...


Delrin is used to make the combination wheels in most high security safe locks. Using delrin in the wheels makes the lock resistant to decoding by x-raying because of delrin's low density. However, neutron bombardment techniques may still be used to decode delrin combination wheels. Delrin also increases the locks resistance to wear.


It is also used to make frame sliders and knee pucks for motorcycle riders/racers.


Delrin is gaining popularity for the manufacture of diving equipment, due to its light weight and its low porosity to gas under pressure. Some other plastics can absorb gas under pressure, and swell or deform.


Delrin has been used increasingly to create body piercing jewelry, especially tunnels or plugs for use in stretched holes. While viewed by many as relatively safe for daily wear, the safety of this practice is still hotly debated within the piercing community. Body piercing jewelry is jewelry manufactured specifically for use in body piercing. ... various fleshtunnels a stylus being passed through a 00ga (10 mm) metal flesh tunnel with a single flare A flesh tunnel is a type of body piercing jewelry, and IT IS COMPLETELY GROSS AND NASTY AND DISGUSTING AND VULGAR ABD WRONG AND THE PEOPLE WHO DO IT GO TO HELL... This article or section does not cite its references or sources. ...


Delrin is also commonly being used as a substitute for horn in the koiguchi on modern-made japanese swords.


Bonding

Acetal polymers are typically very difficult to bond. Special processes and treatments have been developed to improve bonding of acetal. Typically these processes involve surface etching, flame treatment or mechanical abrasion. Typical etching processes involve chromic acid at elevated temperatures. Dupont has a patented process for treating acetal homopolymer called satinizing which creates anchor points on the surface which give that adhesive something to grab. There are also processes involving oxygen plasma and corona discharge[1]. In chemistry, chromic acid is a hypothetical chromium (Cr) compound, yet to be isolated, that would have the formula H2CrO4. ...


Once the surface is prepared a number of adhesives can be used for bonding. These include epoxies, polyurethanes, and cyanoacrylates. Epoxies have shown 150-500 psi shear strength on mechanically abraded surfaces and 500-1000 psi on chemically treated surfaces (500psi approx 3,4MPa). Cyanoacrylates are useful for bonding to metal, leather, rubber and other plastics. Epoxy or polyepoxide is a thermosetting epoxide polymer that cures (polymerizes and crosslinks) when mixed with a catalyzing agent or hardener. Most common epoxy resins are produced from a reaction between epichlorohydrin and bisphenol-A. The first commercial attempts to prepare resins from epichlorohydrin occurred in 1927 in the United... A polyurethane is any polymer consisting of a chain of organic units joined by urethane links. ... A tube of Super glue Cyanoacrylate is the generic name for substances such as methyl-2-cyanoacrylate, which is typically sold under trademarks like Superglue and Krazy Glue, and 2-octyl cyanoacrylate or n-butyl-cyanoacrylate, which are used in medical glues such as Dermabond and Traumaseal. ...


Solvent welding is typically unsuccessful on acetal polymers due to the excellent solvent resistance of acetal. Thermal welding through various methods have been used successfully on both homopolymer and copolymer.


History

Delrin was first synthesized by DuPont's research chemists around 1952. The company filed for patent protection of the material in 1956 and completed construction of plant to produce the material at Parkersburg, West Virginia in 1960. Parkersburg is the county seat of Wood CountyGR6. ...


Notes

  1. ^ Snogren, R. C. (1974). Handbook of Surface Preparation. New York: Palmerton Publishing Co.. 

External links

  • DuPont overview of Delrin
  • Links to external chemical sources

  Results from FactBites:
 
DuPont Heritage: Delrin® (285 words)
Delrin® acetal resin emerged from DuPont's efforts to capitalize on the success of nylon and the growing post World War II market for plastics and other synthetic materials.
Despite its troubled beginnings, Delrin® thrived in the long run and has been steadily improved over the years.
Today, Delrin® is a mainstay of DuPont's engineering polymers line and is widely acclaimed as a lightweight but durable low wear, low friction plastic for electronic office equipment, advanced conveyor technology, and automotive applications.
Delrin® Global Product (555 words)
Delrin® bridges the gap between metals and ordinary plastics with a unique combination of strength, stiffness, hardness, dimensional stability, toughness, fatigue resistance, solvent and fuel resistance, abrasion resistance, low wear and low friction.
Crastin® PBT Delrin® POM Elvamide® PA Hytrel® TPC-ET Minlon® PA Rynite® PET Zenite® LCP Zytel® PA Zytel® HTN PPA
You can choose from a wide range of general-purpose Delrin® resins to meet most property and molding requirements.
  More results at FactBites »


 

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