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Encyclopedia > Dismutation

Dismutation is a chemical reaction in which a single compound serves both as an oxidizing and a reducing agent. Also known as disproportionation. The most fundamental reactions in chemistry are the redox processes. ... Reduction or reducing has several meanings: In mathematics, reduction is the process of manipulating a series of equations or matrices into a desired simpler format. ... jfkdjdfdfd--69. ...


An example of dismutation is the catalysis of hydrogen peroxide to water and oxygen by the enzyme catalase which occurs in two stages: Hydrogen peroxide (H2O2) is a clear liquid, slightly more viscous than water, that has strong oxidizing properties and is therefore a powerful bleaching agent that has found use as a disinfectant, as an oxidizer, and in rocketry (particularly in high concentrations as high test peroxide (HTP)) as a monopropellant and... Ribbon diagram of the catalytically perfect enzyme TIM. An enzyme is a protein that catalyzes, or speeds up, a chemical reaction. ... link title Catalase Catalase (human erythrocyte catalase: PDB 1DGF, EC 1. ...

H2O2 + Fe(III)-E → H2O + O=Fe(IV)-E (oxidation of Fe(III) to Fe(IV))
H2O2 + O=Fe(IV)-E → H2O + Fe(III)-E + O2 (reduction of Fe(IV) back to Fe(III))

(Where Fe-E represents the iron centre of the heme group attached to the enzyme.) Hydrogen peroxide (H2O2) is a clear liquid, slightly more viscous than water, that has strong oxidizing properties and is therefore a powerful bleaching agent that has found use as a disinfectant, as an oxidizer, and in rocketry (particularly in high concentrations as high test peroxide (HTP)) as a monopropellant and... General Name, Symbol, Number iron, Fe, 26 Chemical series transition metals Group, Period, Block 8, 4, d Appearance lustrous metallic with a grayish tinge Atomic mass 55. ... A hæm or heme is a metal-containing cofactor that consists of an iron atom contained in the center of a large heterocyclic organic ring called a porphyrin. ...


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  Results from FactBites:
 
Professor Charles Dismukes: Publication List (3715 words)
Kinetics and Mechanism of Hydrogen Peroxide Dismutation," (1994) J.
Shank, V. Barynin and G. Dismukes, "Protein Coordination to Manganese Determines the High Catalytic Rate of the Dimanganese Catalases.
Boelrijk, A.E.M. and G.C. Dismukes, "The mechanism of hydrogen peroxide dismutation by a dimanganese catalase mimic: Dominant role of an intramolecular base on substrate binding affinity and rate acceleration." Inorganic Chemistry, 2000, 39:3020-3028
  More results at FactBites »


 

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