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Encyclopedia > Disproportionation

Disproportionation is a concept in chemistry and is a redox reaction where a reactant is both oxidised and reduced in the same chemical reaction. Chemistry (derived from the Arabic word kimia, alchemy, where al is Arabic for the) is the science that deals with the properties of organic and inorganic substances and their interactions with other organic and inorganic substances. ... Redox reactions include all chemical processes in which atoms have their oxidation number (oxidation state) changed. ... A reactant or reagent is any substance initially present in a chemical reaction. ...


Examples:

The ionic equation for this reaction is as follows: General Name, Symbol, Number chlorine, Cl, 17 Chemical series halogens Group, Period, Block 17, 3, p Appearance yellowish green Atomic mass 35. ... Flash point non flammable Supplementary data page Structure and properties n, εr, etc. ... Flash point Non-flammable R/S statement R: none S: none RTECS number VZ4725000 Supplementary data page Structure and properties n, εr, etc. ... R-phrases R9, R22, R51/53 S-phrases S2, S13, S17, S46, S61 Flash point none Supplementary data page Structure and properties n, εr, etc. ... Water (from the Old English word wæter; c. ...


Cl2 + 6OH- -> Cl- + ClO3- + 3H2O


In the above equation, the initial oxidation number of Chlorine is 0.


In the products, Cl- has an oxidation number of -1, having been reduced, whereas the oxidation number of Chlorine in the Chlorate ion is +5, indicating that it has been oxidised.

Disproportionation is the opposite of synproportionation. The Cannizzaro reaction named after Stanislao Cannizzaro is a chemical reaction that involves disproportionation of any aldehyde lacking a hydrogen atom in the alpha position, in the presence of a strong base. ... An aldehyde is either a functional group consisting of a terminal carbonyl group or a compound containing a terminal carbonyl group. ... For other uses, see Alcohol (disambiguation). ... Structure of a carboxylic acid Carboxylic acids are organic acids characterized by the presence of a carboxyl group, which has the formula -C(=O)-OH, usually written as COOH. In general, the salts and anions of carboxylic acids are called carboxylates. ... The Tishchenko reaction is a chemical reaction that involves disproportionation of an aldehyde lacking a hydrogen atom in the alpha position in the presence of an alkoxide. ... Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds. ... General formula of an ester of a carboxylic acid. ... Synproportionation is a concept in chemistry and is a redox reaction where two reactants that share an atom but differ in oxidation number react to a single reaction product. ...


  Results from FactBites:
 
Disproportionation Summary (467 words)
Literally, disproportionation is a chemical reaction in which a single metal ion species undergoes an internal redox reaction and forms two different products in stoichiometric quantities.
Disproportionation is a reaction that is more characteristic of the heavier transition elements and the f-block elements.
Disproportionation or dismutation is a type of reaction in redox chemistry in which a reactant is both oxidised and reduced in the same chemical reaction forming 2 separate compounds.
Olefin metathesis catalyst - Patent 4567159 (3672 words)
By the term "disproportionation" or "metathesis" throughout this specification is meant the conversion of the feed olefinic (or unsaturated) hydrocarbon to a mixture of olefinic (or unsaturated) hydrocarbons having different numbers of carbon atoms than the feed hydrocarbons.
The disproportionation reaction can be carried out by contacting the olefins to be disproportionated with the catalyst in the liquid phase or the gas phase, depending on structure and molecular weight of the olefins, temperature and pressure.
The length of time during which the olefinically unsaturated compounds to be disproportionated are contacted with the catalyst depends upon several factors such as the activity of the catalyst, temperature, pressure, and structure of the olefinically unsaturated compound to be disproportionated.
  More results at FactBites »


 

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