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Encyclopedia > Gadolinium
64 europiumgadoliniumterbium
-

Gd

Cm
General
Name, Symbol, Number gadolinium, Gd, 64
Chemical series lanthanides
Group, Period, Block n/a, 6, f
Appearance silvery white
Standard atomic weight 157.25(3) g·mol−1
Electron configuration [Xe] 4f7 5d1 6s2
Electrons per shell 2, 8, 18, 25, 9, 2
Physical properties
Phase solid
Density (near r.t.) 7.90 g·cm−3
Liquid density at m.p. 7.4 g·cm−3
Melting point 1585 K
(1312 °C, 2394 °F)
Boiling point 3546 K
(3273 °C, 5923 °F)
Heat of fusion 10.05 kJ·mol−1
Heat of vaporization 301.3 kJ·mol−1
Heat capacity (25 °C) 37.03 J·mol−1·K−1
Vapor pressure (calculated)
P(Pa) 1 10 100 1 k 10 k 100 k
at T(K) 1836 2028 2267 2573 2976 3535
Atomic properties
Crystal structure hexagonal
Oxidation states 3
(mildly basic oxide)
Electronegativity 1.20 (Pauling scale)
Ionization energies
(more)
1st: 593.4 kJ·mol−1
2nd: 1170 kJ·mol−1
3rd: 1990 kJ·mol−1
Atomic radius 180 pm
Atomic radius (calc.) 233 pm
Miscellaneous
Magnetic ordering ferromagnetic
Electrical resistivity (r.t.) (α, poly)
1.310 µΩ·m
Thermal conductivity (300 K) 10.6 W·m−1·K−1
Thermal expansion (100 °C) (α, poly)
9.4 µm/(m·K)
Speed of sound (thin rod) (20 °C) 2680 m/s
Young's modulus (α form) 54.8 GPa
Shear modulus (α form) 21.8 GPa
Bulk modulus (α form) 37.9 GPa
Poisson ratio (α form) 0.259
Vickers hardness 570 MPa
CAS registry number 7440-54-2
Selected isotopes
Main article: Isotopes of gadolinium
iso NA half-life DM DE (MeV) DP
152Gd 0.20% 1.08×1014 y α 2.205 148Sm
154Gd 2.18% Gd is stable with 90 neutrons
155Gd 14.80% Gd is stable with 91 neutrons
156Gd 20.47% Gd is stable with 92 neutrons
157Gd 15.65% Gd is stable with 93 neutrons
158Gd 24.84% Gd is stable with 94 neutrons
160Gd 21.86% >1.3×1021y β-β- 1.7 160Dy
References

Gadolinium (IPA: /ˌgadəˈlɪniəm/) is a chemical element in the periodic table that has the symbol Gd and atomic number 64. General Name, Symbol, Number europium, Eu, 63 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 151. ... General Name, Symbol, Number terbium, Tb, 65 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 158. ... General Name, Symbol, Number curium, Cm, 96 Chemical series actinides Group, Period, Block ?, 7, f Appearance silvery Atomic mass (247) g/mol Electron configuration [Rn] 5f7 6d1 7s2 Electrons per shell 2, 8, 18, 32, 25, 9, 2 Physical properties Phase solid Density (near r. ... Gadolinium table image created for Wikipedia by schnee on June 24, 2003, 11:26 UTC. File links The following pages link to this file: Gadolinium User:Femto/elements e8 Categories: Public domain images ... This is a standard display of the periodic table of elements. ... This extended periodic table was suggested by Glenn T. Seaborg in 1969. ... This is a list of chemical elements, sorted by name and color coded according to type of element. ... A table of chemical elements ordered by atomic number and color coded according to type of element. ... A group, also known as a family, is a vertical column in the periodic table of the chemical elements. ... The lanthanide series comprises the 15 elements from lanthanum to lutetium on the periodic table, with atomic numbers 57 through 71. ... A group, also known as a family, is a vertical column in the periodic table of the chemical elements. ... In the periodic table of the elements, a period is a horizontal row of the table. ... A block of the periodic table of elements is a set of adjacent groups. ... 6 *Lanthanides 7 **Actinides IUPAC has not recommended a specific format for the periodic table, so different conventions are permitted and are often used for the group number of lanthanides and actinides. ... A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the elements, including the Lanthanides. ... The f-block of the periodic table of elements consists of those elements for which, in the atomic ground state, the highest-energy electrons occupy f-orbitals. ... Color is an important part of the visual arts. ... Gadolinium sample. ... The atomic mass (ma) is the mass of an atom at rest, most often expressed in unified atomic mass units. ... To help compare different orders of magnitude we list here masses between 60. ... Hydrogen = 1 List of Elements in Atomic Number Order. ... Electron atomic and molecular orbitals In atomic physics and quantum chemistry, the electron configuration is the arrangement of electrons in an atom, molecule, or other physical structure (eg, a crystal). ... General Name, Symbol, Number xenon, Xe, 54 Chemical series noble gases Group, Period, Block 18, 5, p Appearance colorless Atomic mass 131. ... e- redirects here. ... Example of a sodium electron shell model An electron shell, also known as a main energy level, is a group of atomic orbitals with the same value of the principal quantum number n. ... In the physical sciences, a phase is a set of states of a macroscopic physical system that have relatively uniform chemical composition and physical properties (i. ... For other uses, see Solid (disambiguation). ... In physics, density is defined as mass m per unit volume V. For the common case of a homogeneous substance, it is expressed as: where, in SI units: ρ (rho) is the density of the substance, measured in kg·m-3 m is the mass of the substance, measured in kg... Room temperature describes a certain temperature within enclosed space that is uses for various purposes by human beings. ... In physics, density is defined as mass m per unit volume V. For the common case of a homogeneous substance, it is expressed as: where, in SI units: ρ (rho) is the density of the substance, measured in kg·m-3 m is the mass of the substance, measured in kg... The melting point of a crystalline solid is the temperature at which it changes state from solid to liquid. ... The melting point of a crystalline solid is the temperature at which it changes state from solid to liquid. ... The Kelvin scale is a thermodynamic (absolute) temperature scale where absolute zero—the lowest possible temperature where nothing could be colder and no heat energy remains in a substance—is defined as zero kelvin (0 K). ... Celsius is, or relates to, the Celsius temperature scale (previously known as the centigrade scale). ... Fahrenheit is a temperature scale named after the German physicist Daniel Gabriel Fahrenheit (1686–1736), who proposed it in 1724. ... The boiling point of a substance is the temperature at which it can change its state from a liquid to a gas throughout the bulk of the liquid at a given pressure. ... The Kelvin scale is a thermodynamic (absolute) temperature scale where absolute zero—the lowest possible temperature where nothing could be colder and no heat energy remains in a substance—is defined as zero kelvin (0 K). ... Celsius is, or relates to, the Celsius temperature scale (previously known as the centigrade scale). ... Fahrenheit is a temperature scale named after the German physicist Daniel Gabriel Fahrenheit (1686–1736), who proposed it in 1724. ... Heat of fusion is the amount of heat energy which must be absorbed or lost for 1 gram of a substance to change states from a solid to a liquid or vice versa. ... The joule per mole (symbol: J·mol-1) is an SI derived unit of energy per amount of material. ... The standard enthalpy change of vaporization, ΔvHo, also (less correctly) known as the heat of vaporization is the energy required to transform a given quantity of a substance into a gas. ... The joule per mole (symbol: J·mol-1) is an SI derived unit of energy per amount of material. ... To meet Wikipedias quality standards, this article or section may require cleanup. ... In chemistry and physics, Vapor pressure is the pressure of a vapor in equilibrium with its non-vapor phases. ... Enargite crystals In mineralogy and crystallography, a crystal structure is a unique arrangement of atoms in a crystal. ... The oxidation number of an element in a molecule or complex is the charge that it would have if all the ligands were removed along with the electron pairs that were shared with the central atom[1]. It is used in the inorganic nomenclature of inorganic compounds. ... Acids and bases: Acid-base reaction theories pH Self-ionization of water Buffer solutions Systematic naming Electrochemistry Acid-base extraction Acids: Strong acids Weak acids Mineral acids Organic acids Bases: Strong bases Weak bases Organic bases edit In chemistry, a base is most commonly thought of as a substance that... Electronegativity is a measure of the ability of an atom or molecule to attract electrons in the context of a chemical bond. ... The ionization energy (IE) of an atom or of a molecule is the energy required to strip it of an electron. ... These tables list the ionization energy in kJ/mol necessary to remove an electron from a neutral atom (first energy), respectively from a singly, doubly, etc. ... Kilojoule per mole are an SI derived unit of energy per amount of material, where energy is measured in units of 1000 joules, and the amount of material is measured in mole units. ... The atomic radius is the distance from the atomic nucleus to the outermost stable electron orbital in an atom that is at equilibrium. ... You have big harry skanky balls ... One picometre is defined as 1x10-12 metres, in standard units. ... You have big harry skanky balls ... Magnetic lines of force of a bar magnet shown by iron filings on paper In physics, magnetism is one of the phenomena by which materials exert an attractive or repulsive force on other materials. ... Ferromagnetism is the phenomenon by which materials, such as iron, in an external magnetic field become magnetized and remain magnetized for a period after the material is no longer in the field. ... // Headline text POOP!! Danny Hornsby (also known as Gnome) is a measure indicating how strongly a Gnome can opposes the flow of electric current. ... Room temperature describes a certain temperature within enclosed space that is uses for various purposes by human beings. ... In physics, thermal conductivity, k, is the intensive property of a material that indicates its ability to conduct heat. ... During heat transfer, the energy that is stored in the intermolecular bonds between atoms changes. ... The speed of sound is a term used to describe the speed of sound waves passing through an elastic medium. ... Metre per second (U.S. spelling: meter per second) is an SI derived unit of both speed (scalar) and velocity (vector), defined by distance in metres divided by time in seconds. ... This article does not adequately cite its references or sources. ... In materials science, shear modulus S, sometimes referred to as the modulus of rigidity, is defined as the ratio of shear stress to the shear strain: S = shear stress/shear strain = (F/A)/Φ. Another commonly accepted symbol is G. Shear modulus is usually measured in ksi (kips per square... The bulk modulus (K) of a substance essentially measures the substances resistance to uniform compression. ... Figure 1: Rectangular specimen subject to compression, with Poissons ratio circa 0. ... A Vickers hardness tester The Vickers hardness test was developed in the early 1920s as an alternative method to measure the hardness of materials. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences, mixtures and alloys. ... Gadolinium (Gd) Standard atomic mass: 157. ... Isotopes are any of the several different forms of an element each having different atomic mass (mass number). ... Natural abundance refers to the prevalence of different isotopes of an element as found in nature. ... Half-Life For a quantity subject to exponential decay, the half-life is the time required for the quantity to fall to half of its initial value. ... OK : Radioactive and Radioactivity redirect here. ... The decay energy is the energy released by a nuclear decay. ... The electronvolt (symbol eV, or, rarely and incorrectly, ev) is a unit of energy. ... In nuclear physics, a decay product, also known as a daughter product, is a nuclide resulting from the radioactive decay of a parent or precursor nuclide. ... A year is the time between two recurrences of an event related to the orbit of the Earth around the Sun. ... Alpha decay is a form of radioactive decay in which an atomic nucleus ejects an alpha particle through electromagnetic force and transforms into a nucleus with mass number 4 less and atomic number 2 less. ... General Name, Symbol, Number samarium, Sm, 62 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 150. ... This article needs to be cleaned up to conform to a higher standard of quality. ... This article or section does not adequately cite its references or sources. ... This article needs to be cleaned up to conform to a higher standard of quality. ... This article or section does not adequately cite its references or sources. ... This article needs to be cleaned up to conform to a higher standard of quality. ... This article or section does not adequately cite its references or sources. ... This article needs to be cleaned up to conform to a higher standard of quality. ... This article or section does not adequately cite its references or sources. ... This article needs to be cleaned up to conform to a higher standard of quality. ... This article or section does not adequately cite its references or sources. ... A year is the time between two recurrences of an event related to the orbit of the Earth around the Sun. ... In nuclear physics, beta decay (sometimes called neutron decay) is a type of radioactive decay in which a beta particle (an electron or a positron) is emitted. ... General Name, Symbol, Number dysprosium, Dy, 66 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 162. ... Recommended values for many properties of the elements, together with various references, are collected on these data pages. ... Not to be confused with the NATO phonetic alphabet, which has also informally been called the “International Phonetic Alphabet”. For information on how to read IPA transcriptions of English words, see IPA chart for English. ... The periodic table of the chemical elements A chemical element, or element for short, is a type of atom that is defined by its atomic number; that is, by the number of protons in its nucleus. ... The periodic table of the chemical elements is a tabular method of displaying the chemical elements, first devised in 1869 by the Russian chemist Dmitri Mendeleev. ... It has been suggested that List of elements by atomic number be merged into this article or section. ...

Contents

Gadolinium >99.9% purity
Gadolinium >99.9% purity


Image File history File links ~100g Gadolinium chunk, purity >99. ... Image File history File links ~100g Gadolinium chunk, purity >99. ...


Notable characteristics

Gadolinium is a silvery white, malleable and ductile rare earth metal with a metallic luster. It crystallizes in hexagonal, close-packed alpha form at room temperature; when heated to 1508 K, it transforms into its beta form, which has a body-centered cubic structure. A rare earth is an oxide of a rare earth element. ... A regular hexagon. ... The Kelvin scale is a thermodynamic (absolute) temperature scale where absolute zero—the lowest possible temperature where nothing could be colder and no heat energy remains in a substance—is defined as zero kelvin (0 K). ... In crystallography, the cubic crystal system is the most symmetric of the 7 crystal systems. ...


Unlike other rare earth elements, gadolinium is relatively stable in dry air; however, it tarnishes quickly in moist air and forms a loosely adhering oxide that spalls off and exposes more surface to oxidation. Gadolinium reacts slowly with water and is soluble in dilute acid. An oxide is a chemical compound containing an oxygen atom and other elements. ...


Gadolinium has the highest thermal neutron capture cross-section of any (known) element, 49,000 barns, but it also has a fast burn-out rate, limiting its usefulness as a nuclear control rod material. This article does not cite its references or sources. ... The process of neutron capture can proceed in two ways - as a rapid process (an r-process) or a slow process (an s-process). ... A barn (symbol b) is a unit of area. ... A nuclear control rod is removed from or inserted into the core of a nuclear reactor in order to increase or decrease the number of neutrons which will split further uranium atoms. ...


Gadolinium becomes superconductive below a critical temperature of 1.083 K. It is strongly magnetic at room temperature, and exhibits ferromagnetic properties below room temperature. A magnet levitating above a high-temperature superconductor, cooled with liquid nitrogen. ... Magnetic lines of force of a bar magnet shown by iron filings on paper In physics, magnetism is one of the phenomena by which materials exert an attractive or repulsive force on other materials. ... Ferromagnetism is a phenomenon by which a material can exhibit a spontaneous magnetization, and is one of the strongest forms of magnetism. ...


Gadolinium demonstates a magnetocaloric effect whereby its temperature increases when it enters a magnetic field and decreases when it leaves the magnetic field. The effect is considerably stronger for the gadolinium alloy Gd5(Si2Ge2) [1]. Magnetic refrigeration is a cooling technology based on the magnetocaloric effect. ... An alloy is a combination, either in solution or compound, of two or more elements, at least one of which is a metal, and where the resulting material has metallic properties. ... It has been suggested that Silicons ranking be merged into this article or section. ... General Name, Symbol, Number germanium, Ge, 32 Chemical series metalloids Group, Period, Block 14, 4, p Appearance grayish white Atomic mass 72. ...


Applications

Gadolinium is used for making gadolinium yttrium garnets, which have microwave applications, and gadolinium compounds are used for making phosphors for colour TV tubes. Gadolinium is also used for manufacturing compact discs and computer memory. Gadolinium Yttrium Garnet (Gd:YAG) is a variation of Nd:YAG with microwave and laser applications. ... Microwaves are electromagnetic waves with wavelengths longer than those of terahertz (THz) frequencies, but relatively short for radio waves. ... A phosphor is a substance that can exhibit the phenomenon of fluorescence (glowing during absorption of radiation of another kind) or phosphorescence (sustained glowing without further stimulus). ... “TV” redirects here. ... This article or section does not cite its references or sources. ... The terms storage (U.K.) or memory (U.S.) refer to the parts of a digital computer that retain physical state (data) for some interval of time, possibly even after electrical power to the computer is turned off. ...


Gadolinium is used in nuclear marine propulsion systems as a burnable poison. The gadolinium slows the initial reaction rate, but as it decays other neutron poisons accumulate, allowing for long-running cores. Gadolinium is also used as a secondary, emergency shut-down measure in some nuclear reactors, particularly of the CANDU type. This article does not adequately cite its references or sources. ... For information on radioactive toxins see Radiation poisoning A nuclear poison is a substance with a large neutron absorption cross-section in applications, such as nuclear reactors, when absorbing neutrons is an undesirable effect. ... A nuclear poison, also called a neutron poison is a substance with a large neutron absorption cross-section in applications, such as nuclear reactors, when absorbing neutrons is an undesirable effect. ... The CANDU reactor is a Pressurized Heavy Water Reactor developed initially in the late 1950s and 1960s by a partnership between Atomic Energy of Canada Limited (AECL), the Hydro-Electric Power Commission of Ontario (now known as Ontario Power Generation), Canadian General Electric (now known as GE Canada), as well...


Gadolinium also possesses unusual metallurgic properties, with as little as 1% of gadolinium improving the workability and resistance of iron, chromium and related alloys to high temperatures and oxidation. Metallurgy is a domain of materials science and of materials engineering that studies the physical and chemical behavior of metallic elements, their intermetallic compounds, and their mixtures, which are called alloys. ... General Name, Symbol, Number iron, Fe, 26 Chemical series transition metals Group, Period, Block 8, 4, d Appearance lustrous metallic with a grayish tinge Atomic mass 55. ... General Name, Symbol, Number chromium, Cr, 24 Chemical series transition metals Group, Period, Block 6, 4, d Appearance silvery metallic Atomic mass 51. ... An alloy is a combination, either in solution or compound, of two or more elements, at least one of which is a metal, and where the resulting material has metallic properties. ... The most fundamental reactions in chemistry are the redox processes. ...


Because of their paramagnetic properties, solutions of organic gadolinium complexes and gadolinium compounds are used as intravenous radiocontrast agents to enhance images in medical magnetic resonance imaging. Magnevist is the most widespread example. Simple Illustration of a paramagnetic probe made up from miniature magnets. ... Organic chemistry is a specific discipline within chemistry which involves the scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of chemical compounds consisting of primarily carbon and hydrogen, which may contain any number of other elements, including nitrogen, oxygen, halogens as well... Synthesis of copper(II)-tetraphenylporphine, a metal complex, from tetraphenylporphine and copper(II) acetate monohydrate. ... An intravenous drip in a hospital Intravenous therapy or IV therapy is the administration of liquid substances directly into a vein. ... Radiocontrast agents (or simply contrast agents) are compounds used to improve the visibility of internal bodily structures in an X-ray image. ... Magnetic Resonance Image showing a median sagittal cross section through a human head. ... Magnevist (gadopentetate dimeglumine), is a contrast agent extensively used in Magnetic Resonance Imaging. ...


Besides MRI, gadolinium (Gd) is also used in other imaging. In X-ray, gadolinium is contained in the phosphor layer suspending in a polymer matrix at the detector. Terbium-doped gadolinium oxysulfide (Gd2O2S: Tb) at the phosphor layer is to convert the X-rays releasing from the source into light. Gd can emit at 540nm (green light spectrum = 520 – 570nm), which is very useful for enhancing the imaging quality of the X-ray that are exposed to the photographic film. Beside Gd's spectrum range, the compound also has a K-edge at 50 kiloelectron volt (keV), which means its absorption of X-ray through photoelectric interactions is great. The energy conversion of Gd is up to 20%, which means, one-fifth of the X-ray striking on the phosphor layer can be converted into light photons. The mri are a fictional alien species in the Faded Sun Trilogy of C.J. Cherryh. ... In the NATO phonetic alphabet, X-ray represents the letter X. An X-ray picture (radiograph) taken by Röntgen An X-ray is a form of electromagnetic radiation with a wavelength approximately in the range of 5 pm to 10 nanometers (corresponding to frequencies in the range 30 PHz... General Name, Symbol, Number terbium, Tb, 65 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 158. ... In semiconductor production, doping refers to the process of intentionally introducing impurities into an intrinsic semiconductor in order to change its electrical properties. ... Gadolinium oxysulfide (Gd2O2S), also called gadolinium sulfoxylate or GOS, is an inorganic compound, a mixed oxide-sulfide of gadolinium. ... In most modern usages of the word spectrum, there is a unifying theme of between extremes at either end. ... In the NATO phonetic alphabet, X-ray represents the letter X. An X-ray picture (radiograph) taken by Röntgen An X-ray is a form of electromagnetic radiation with a wavelength approximately in the range of 5 pm to 10 nanometers (corresponding to frequencies in the range 30 PHz... In the NATO phonetic alphabet, X-ray represents the letter X. An X-ray picture (radiograph) taken by Röntgen An X-ray is a form of electromagnetic radiation with a wavelength approximately in the range of 5 pm to 10 nanometers (corresponding to frequencies in the range 30 PHz... The photoelectric effect is the emission of electrons from matter upon the absorption of electromagnetic radiation, such as visible light or ultraviolet radiation. ...


Gadolinium oxyorthosilicate (GSO) is a single crystal that is used as a scintillator in medical imaging equipment like as Positron Emission Tomography (PET). Another new scintillator for detecting neutron is cerium-doped gadolinium orthosilicate (GSO - Gd2SiO5:Ce). A scintillator is a device or substance that absorbs high energy (ionizing) electromagnetic or charged particle radiation then, in response, fluoresces photons at a characteristic Stokes-shifted (longer) wavelength, releasing the previously absorbed energy. ... Image of a typical positron emission tomography (PET) facility Positron emission tomography (PET) is a nuclear medicine medical imaging technique which produces a three dimensional image or map of functional processes in the body. ... It has been suggested that Residential pets be merged into this article or section. ... General Name, Symbol, Number cerium, Ce, 58 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 140. ...


Gadolinium gallium garnet (Gd3Ga5O12) is a material with good optical properties, and is used in fabrication of various optical components and as substrate material for magneto–optical films. Gadolinium Gallium Garnet (GGG, Gd3Ga5O12) is a synthetic crystalline material of the garnet group, with good mechanical, thermal, and optical properties. ...


In the future, gadolinium ethyl sulfate, which has extremely low noise characteristics, may be used in masers. Furthermore, gadolinium's high magnetic movement and low Curie temperature (which lies just at room temperature) suggest applications as a magnetic component for sensing hot and cold. A Hydrogen RF discharge, the first element inside a Hydrogen Maser (see description below), courtesy NASA/JPL-Caltech. ... In physics, the Curie point, or Curie temperature, is the temperature above which a ferromagnet loses its ferromagnetic ability to possess a net (spontaneous) magnetization in the absence of an external magnetic field. ...


Due to extremely high neutron cross-section of gadolinium, this element is very effective for use with neutron radiography.


History

In 1880, Swiss chemist Jean Charles Galissard de Marignac observed spectroscopic lines due to gadolinium in samples of didymium and gadolinite; French chemist Paul Émile Lecoq de Boisbaudran separated gadolinia, the oxide of Gadolinium, from Mosander's yttria in 1886. The element itself was isolated only recently. Year 1880 (MDCCCLXXX) was a leap year starting on Thursday (link will display the full calendar). ... A chemist pours from a round-bottom flask. ... Jean Charles Galinard de Marignac (April 24, 1817–April 15, 1894) was a Swiss chemist whose work with atomic weights suggested the possibility of isotopes and the packing fraction of nuclei and whose study of the rare earth elements led to his discovery of ytterbium in 1878 and codiscovery of... Didymium is a mixture of the elements praseodymium and neodymium. ... Gadolinite is a mineral of a nearly black color and vitreous luster, and consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with formula: (Ce,La,Nd,Y)2FeBe2Si2O10. ... Paul Émile (François) Lecoq de Boisbaudran (April 18, 1838 - May 28, 1912) was a French chemist born in Cognac. ... I wont stop until Dat dere cell-tech is on the English language article: Ronnie coleman! ... An oxide is a chemical compound containing an oxygen atom and other elements. ... Yttrium oxide is an oxide of yttrium. ... 1886 (MDCCCLXXXVI) is a common year starting on Friday (click on link to calendar) // Events January 18 - Modern field hockey is born with the formation of The Hockey Association in England. ...


Gadolinium, like the mineral gadolinite, is named after Finnish chemist and geologist Johan Gadolin. It is the only element in the first 92 elements to be named after a person. Gadolinite is a mineral of a nearly black color and vitreous luster, and consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with formula: (Ce,La,Nd,Y)2FeBe2Si2O10. ... the are cool The Geologist by Carl Spitzweg A geologist is a contributor to the science of geology, studying the physical structure and processes of the Earth and planets of the solar system (see planetary geology). ... Johan Gadolin Johan Gadolin (June 5, 1760 — August 15, 1852) was a Finnish chemist, physicist and mineralogist. ...


In older literature the natural form of the element is often called an "earth", meaning that element came from the Earth. Accordingly - Gadolinium is the element that comes from the earth, gadolinia. Earths are compounds of the element and one or more other elements. Two common combining elements are oxygen and sulfur. For example, gadolinia contains gadolinium oxide (Gd2O3).


Biological role

Gadolinium has no known biological role. It is used as a component of MRI contrast agents as in the 3+ oxidation state the metal has 7 unpaired f electrons. This causes water around the contrast agent to relax quickly enhancing the quality of the MRI scan.


Occurrence

Gadolinium is never found in nature as the free element, but is contained in many rare minerals such as monazite and bastnäsite. It occurs only in trace amounts in the mineral gadolinite which was also named after Johan Gadolin. Today, it is prepared by ion exchange and solvent extraction techniques, or by the reduction of its anhydrous fluoride with metallic calcium. Monazite powder In geology, the mineral monazite is a reddish-brown phosphate containing rare earth metals and an important source of thorium, lanthanum, and cerium. ... The mineral bastnäsite is one of a family of three carbonate-fluoride minerals. ... Gadolinite is a mineral of a nearly black color and vitreous luster, and consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with formula: (Ce,La,Nd,Y)2FeBe2Si2O10. ... Johan Gadolin Johan Gadolin (June 5, 1760 — August 15, 1852) was a Finnish chemist, physicist and mineralogist. ... Ion exchange is a process in which ions are exchanged between a solution and an ion exchanger, an insoluble solid or gel. ... In chemistry, liquid-liquid extraction (or more briefly, solvent extraction) is a useful method to separate components (compounds) of a mixture. ... General Name, Symbol, Number calcium, Ca, 20 Chemical series alkaline earth metals Group, Period, Block 2, 4, s Appearance silvery white Atomic mass 40. ...


Value

In 1994, the cost of gadolinium was about US$ 0.12 per gram, and it has only increased in value by about US$ 0.01 per gram since then.[2]: 1994 (MCMXCIV) was a common year starting on Saturday of the Gregorian calendar, and was designated as the International Year of the Family and the International Year of the Sport and the Olympic Ideal by United Nations. ... ISO 4217 Code USD User(s) the United States, the British Indian Ocean Territory[1], the British Virgin Islands, East Timor, Ecuador, El Salvador, the Marshall Islands, Micronesia, Palau, Panama, Turks and Caicos Islands, and the insular areas of the United States Inflation 2. ... BIC pen cap, about 1 gram. ...

1994.....$55 per pound (or $0.115 per gram)
1995.....$55 per pound (or $0.115 per gram)
1996.....$115 per kilogram (or $0.115 per gram)
1997.....$115 per kilogram (or $0.115 per gram)
1998.....$115 per kilogram (or $0.115 per gram)
1999.....$115 per kilogram (or $0.115 per gram)
2000.....$130 per kilogram (or $0.13 per gram)
2001.....$130 per kilogram (or $0.13 per gram)
2002.....$130 per kilogram (or $0.13 per gram)
2003.....$130 per kilogram (or $0.13 per gram)
2004.....$130 per kilogram (or $0.13 per gram)
2005.....$130 per kilogram (or $0.13 per gram)

The pound (abbreviations: lb or, sometimes in the United States, #) is a unit of mass in a number of different systems, including various systems of units of mass that formed part of English units, Imperial units, and United States customary units. ... The U.S. National Prototype Kilogram, which currently serves as the primary standard for measuring mass in the U.S. It was assigned to the United States in 1889 and is periodically recertified and traceable to the primary international standard, The Kilogram, held at the Bureau International des Poids et...

Compounds

Compounds of gadolinium include:

See also gadolinium compounds. Fluoride is the ionic form of fluorine. ... The chloride ion is formed when the element chlorine picks up one electron to form an anion (negatively-charged ion) Cl−. The salts of hydrochloric acid HCl contain chloride ions and are also called chlorides. ... Gadolinium(III) chloride is a white crystalline solid. ... A bromide is a phrase, or person who uses phrases, which have been used and repeated so many times as to become either insincere in their meaning, or seem like an attempt at trying to explain the obvious. ... An iodide ion is an iodine atom with a −1 (negative one) charge. ... An oxide is a chemical compound containing an oxygen atom and other elements. ... I wont stop until Dat dere cell-tech is on the English language article: Ronnie coleman! ... Formally, sulfide is the dianion, S2−, which exists in strongly alkaline aqueous solutions formed from H2S or alkali metal salts such as Li2S, Na2S, and K2S. Sulfide is exceptionally basic and, with a pKa > 14, it does not exist in appreciable concentrations even in highly alkaline water. ... Definition The nitride ion is very very gay and retarded A nitride (compound) is a compound that has nitrogen with more electropositive elements. ... Benzene is the simplest of the arenes, a family of organic compounds An organic compound is any member of a large class of chemical compounds whose molecules contain carbon and hydrogen; therefore, carbides, carbonates, carbon oxides and elementary carbon are not organic (see below for more on the definition controversy... Gadodiamide is a gadolinium based contrast agent used in MR imaging procedures to assist in the visualization of blood vessels. ...


Isotopes

Naturally occurring gadolinium is composed of 5 stable isotopes, 154Gd, 155Gd, 156Gd, 157Gd and 158Gd, and 2 radioisotopes, 152Gd and 160Gd, with 158Gd being the most abundant (24.84% natural abundance). 30 radioisotopes have been characterized with the most stable being 160Gd with a half-life of more than 1.3×1021 years (the decay is not observed, only the lower limit on the half-life is known), alpha-decaying 152Gd with a half-life of 1.08×1014 years, and 150Gd with a half-life of 1.79×106 years. All of the remaining radioactive isotopes have half-lives that are less than 74.7 years, and the majority of these have half-lives that are less than 24.6 seconds. This element also has 4 meta states with the most stable being 143mGd (t½ 110 seconds), 145mGd (t½ 85 seconds) and 141mGd (t½ 24.5 seconds). Gadolinium (Gd) Standard atomic mass: 157. ... Isotopes are any of the several different forms of an element each having different atomic mass (mass number). ... A radionuclide is an atom with an unstable nucleus. ... Natural abundance refers to the prevalence of different isotopes of an element as found in nature. ... A radionuclide is an atom with an unstable nucleus. ... Half-Life For a quantity subject to exponential decay, the half-life is the time required for the quantity to fall to half of its initial value. ... Radioactive decay is the set of various processes by which unstable atomic nuclei (nuclides) emit subatomic particles. ... A nuclear isomer is a metastable state of an atom caused by the excitation of a proton or neutron in its nucleus so that it requires a change in spin before it can release its extra energy. ...


The primary decay mode before the most abundant stable isotope, 158Gd, is electron capture and the primary mode after is beta minus decay. The primary decay products before 158Gd are element Eu (Europium) isotopes and the primary products after are element Tb (Terbium) isotopes. In physics, the decay mode describes a particular way a particle decays. ... Electron capture is a decay mode for isotopes that will occur when there are too many protons in the nucleus of an atom, and there isnt enough energy to emit a positron; however, it continues to be a viable decay mode for radioactive isotopes that can decay by positron... In nuclear physics, beta decay (sometimes called neutron decay) is a type of radioactive decay in which a beta particle (an electron or a positron) is emitted. ... In nuclear physics, a decay product, also known as a daughter product, is a nuclide resulting from the radioactive decay of a parent or precursor nuclide. ... General Name, Symbol, Number europium, Eu, 63 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 151. ... General Name, Symbol, Number terbium, Tb, 65 Chemical series lanthanides Group, Period, Block n/a, 6, f Appearance silvery white Atomic mass 158. ...


Precautions

As with the other lanthanides, gadolinium compounds are of low to moderate toxicity, although their toxicity has not been investigated in detail. Also, in patients on dialysis, there are data suggesting that it may cause Nephrogenic Systemic Fibrosis, formerly known as Nephrogenic Dermopathy. [3] // Toxic and Intoxicated redirect here – toxic has other uses, which can be found at Toxicity (disambiguation); for the state of being intoxicated by alcohol see Drunkenness. ...


References

  1. ^ Karl Gschneidner, Jr. and Kerry Gibson (December 7, 2001). MAGNETIC REFRIGERATOR SUCCESSFULLY TESTED. Ames Laboratory News Release. Ames Laboratory. Retrieved on 2006-12-17.
  2. ^ James B. Hedrick (1994). "Rare Earths". USGS Commodity Statistics and Information: 72. [1]. 
  3. ^ Grobner T. Related Articles, Gadolinium--a specific trigger for the development of nephrogenic fibrosing dermopathy and nephrogenic systemic fibrosis? Nephrol Dial Transplant. 2006 Apr;21(4):1104-8. Epub 2006 Jan 23.

For the Manfred Mann album, see 2006 (album). ... December 17 is the 351st day of the year (352nd in leap years) in the Gregorian Calendar. ...

External links

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  Results from FactBites:
 
gadolinium - multiple sclerosis encyclopaedia (346 words)
Gadolinium is the common name given to a range of componds of the chemical element gadolinium that are used to enhance magnetic resonance images (MRI).
In multiple sclerosis, Gadolinium enhancing lesions tend to be associated with an inflammatory response.
Gadolinium (Gd) is the 64th chemical in the periodic table.
Gadolinium (600 words)
Gadolinium has been used for years in adults and children in the United States, Europe and Japan, without any serious complications in thousands of patients.
Gadolinium should be used in pregnant patients or nursing mothers only when the benefits outweigh the risk.
Gadolinium used in MRI is many times safer than the iodine type contrast used in CT scans.
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