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Encyclopedia > Glycosylamine

Glycosylamine is a compound consisting of an amine with a β-N-glycosidic bond to a carbohydrate. The general structure of an amine Amines are organic compounds and a type of functional group that contain nitrogen as the key atom. ... Lactose is a disaccharide found in milk. ...


Examples

  • Ribofuranosylamine

  Results from FactBites:
 
Uli.Iserloh.Blog » Birch Reactions on Carbohydrates (255 words)
In N-linked glycopeptides 4, the asparagine carboxamide is glycosylated with a conserved (high mannose) pentasaccharide core structure.
Within the cellular context, this linkage is generated via glycosylation of the asparagine amide side-chain, while a common chemical synthesis approach involves peptide-bond formation between a glycosylamine 2 and the side-chain carboxylate of a uniquely disposed aspartate 3.
In many cases, the requisite glycosylamine 2 is generated via standard Kochetkov-Lansbury amination (NH O, 25° C) from the globally deprotected parent saccharide 1, featuring a free anomeric hydroxyl-group.
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