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Encyclopedia > Graphite

See also: Graphene
Graphite

General
Category Native mineral
Chemical formula Carbon, C
Identification
Color Steel black, to gray
Crystal habit Tabular, six-sided foliated masses, granular to compacted masses
Crystal system Hexagonal (6/m 2/m 2/m)
Cleavage Perfect in one direction
Fracture Flaky, otherwise rough when not on cleavage
Mohs Scale hardness 1 - 2
Luster metallic, earthy
Refractive index Opaque
Pleochroism None
Streak Black
Density 2.09–2.23 g/cm³
Solubility Molten Ni

Graphite (named by Abraham Gottlob Werner in 1789 from the Greek γραφειν (graphein): "to draw/write", for its use in pencils) is one of the allotropes of carbon. Unlike diamond, graphite is an electrical conductor, and can be used, for instance, in the electrodes of an arc lamp. Graphite holds the distinction of being the most stable form of solid carbon ever discovered. It may be considered the highest grade of coal, just above anthracite and alternatively called meta-anthracite, although it is not normally used as fuel because it is hard to ignite. Graphite may refer to: graphite, one of the allotropes of carbon. ... It has been suggested that Quasam be merged into this article or section. ... Graphite. ... For other uses, see Mineral (disambiguation). ... A chemical formula is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... For other uses, see Carbon (disambiguation). ... In mineralogy, shape and size give rise to descriptive terms applied to the typical appearance, or habit of crystals. ... Foliation is any penetrative planar fabric present in rocks. ... A crystal system is a category of space groups, which characterize symmetry of structures in three dimensions with translational symmetry in three directions, having a discrete class of point groups. ... In crystallography, the hexagonal crystal system is one of the 7 lattice point groups. ... Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite planes, creating smooth surfaces, of which there are several named types: Basal cleavage: cleavage parallel to the base of a crystal, or to the plane of the lateral axes. ... For other uses, see Fracture (disambiguation). ... Mohs scale of mineral hardness characterizes the scratch resistance of various minerals through the ability of a harder material to scratch a softer. ... Lustre (American English: luster) is a description of the way light interacts with the surface of a crystal, rock or mineral. ... The refractive index (or index of refraction) of a medium is a measure for how much the speed of light (or other waves such as sound waves) is reduced inside the medium. ... Pleochroism is an optical phenomenon in which grains of a rock appear to be different colors when observed at different angles,under a petrographic microscope. ... The streak (also called powder color) of a mineral is the color of the powder produced when it is dragged across a unweathered surface. ... For other uses, see Density (disambiguation). ... Solubility is a chemical property referring to the ability for a given substance, the solute, to dissolve in a solvent. ... Abraham Gottlob Werner Abraham Gottlob Werner (1749 or 1750 - 1817), was born in Wehrau, a city in Prussian Silesia, southeastern Germany. ... This article is about the handwriting instrument. ... Eight allotropes of carbon: a) Diamond, b) Graphite, c) Lonsdaleite, d) C60 (Buckminsterfullerene or buckyball), e) C540, f) C70, g) Amorphous carbon, and h) single-walled carbon nanotube or buckytube. ... This article is about the mineral. ... In science and engineering, conductors, such as copper or aluminum, are materials with atoms having loosely held valence electrons. ... Alternative meanings: There is also an Electric-type Pokémon named Electrode. ... 15 kW Xenon short-arc lamp. ... Coal Example chemical structure of coal Coal (pronounced ) is a fossil fuel formed in swamp ecosystems where plant remains were saved by water and mud from oxidization and biodegradation. ... Anthracite coal Anthracite (Greek Ανθρακίτης, literally a form of coal, from Anthrax [Άνθραξ], coal) is a hard, compact variety of mineral coal that has a high luster. ...


There are three principal types of natural graphite, each occurring in different types of ore deposit: (1) Crystalline flake graphite (or flake graphite for short) occurs as isolated, flat, plate-like particles with hexagonal edges if unbroken and when broken the edges can be irregular or angular; (2) Amorphous graphite occurs as fine particles and is the result of thermal metamorphism of coal, the last stage of coalification, and is sometimes called meta-anthracite. Very fine flake graphite is sometimes called amorphous in the trade; (3) Lump graphite (also called vein graphite) occurs in fissure veins or fractures and appears as massive platy intergrowths of fibrous or acicular crystalline aggregates, and is probably hydrothermal in origin.


The name "graphite fiber" is also sometimes used to refer to carbon fibre or carbon fibre reinforced plastic. Carbon fiber composite is a strong, light and very expensive material. ... Carbon fiber reinforced plastic or (CFRP or CRP), is a strong, light and very expensive composite material or fiber reinforced plastic. ...

Contents

Occurrence

Graphite ore
Graphite ore
Graphite output in 2005
Graphite output in 2005

Minerals associated with graphite include quartz, calcite, micas, iron meteorites, and tourmalines. China is usually the top producer of graphite, followed by India and Brazil. Graphite ore. ... Graphite ore. ... Image File history File links Size of this preview: 800 × 351 pixelsFull resolution (1425 × 625 pixel, file size: 57 KB, MIME type: image/png)This bubble map shows the global distribution of graphite output in 2005 as a percentage of the top producer (China - 1,650,000 tonnes). ... Image File history File links Size of this preview: 800 × 351 pixelsFull resolution (1425 × 625 pixel, file size: 57 KB, MIME type: image/png)This bubble map shows the global distribution of graphite output in 2005 as a percentage of the top producer (China - 1,650,000 tonnes). ... For other uses, see Quartz (disambiguation). ... Doubly refracting Calcite from Iceberg claim, Dixon, New Mexico. ... Rock with mica Mica sheet Mica flakes The mica group of sheet silicate minerals includes several closely related materials having highly perfect basal cleavage. ... For other uses, see Iron (disambiguation). ... Willamette Meteorite A meteorite is a natural object originating in outer space that survives an impact with the Earths surface without being destroyed. ... The tourmaline mineral group is chemically one of the most complicated groups of silicate minerals. ...


Graphite has various other characteristics. Thin flakes are flexible but inelastic, the mineral can leave black marks on hands and paper, it conducts electricity, and displays superlubricity. Its best field indicators are softness, luster, density and streak. Superlubricity is a certain phenomenon in which friction can vanish almost completely. ...


According to the USGS, world production of natural graphite in 2006 was 1.03 million tonnes and in 2005 was 1.04 million tonnes (revised), of which the following major exporters produced: China produced 720,000 tonnes in both 2006 and 2005, Brazil 75,600 tonnes in 2006 and 75,515 tonnes in 2005 (revised), Canada 28,000 tonnes in both years, and Mexico (amorphous) 12,500 tonnes in 2006 and 12,357 tonnes in 2005 (revised). In addition, there are two specialist producers: Sri Lanka produced 3,200 tonnes in 2006 and 3,000 tonnes in 2005 of lump or vein graphite, and Madagascar produced 15,000 tonnes in both years, a large portion of it "crucible grade" or very large flake graphite. Some other producers produce very small amounts of "crucible grade". The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


According to the USGS, U.S. (synthetic) graphite electrode production in 2006 was 132,000 tonnes valued at $495 million and in 2005 was 146,000 tonnes valued at $391 million, and high-modulus graphite (carbon) fiber production in 2006 was 8,160 tonnes valued at $172 million and in 2005 was 7,020 tonnes valued at $134 million. The United States Geological Survey (USGS) is a scientific agency of the United States government. ...

Detailed properties

The acoustic and thermal properties of graphite are highly anisotropic, since phonons propagate very quickly along the tightly-bound planes, but are slower to travel from one plane to another. Acoustics is the branch of physics concerned with the study of sound (mechanical waves in gases, liquids, and solids). ... Example of a thermal column between the ground and a cumulus This article is about the atmospheric phenomenon. ... This article is being considered for deletion in accordance with Wikipedias deletion policy. ... A phonon is a quantized mode of vibration occurring in a rigid crystal lattice, such as the atomic lattice of a solid. ...


Graphite can conduct electricity due to the vast electron delocalization within the carbon layers. These valence electrons are free to move, so are able to conduct electricity. However, the electricity is only conducted within the plane of the layers. Conduction is the movement of electrically charged particles through a transmission medium (electrical conductor). ... For other uses, see Electron (disambiguation). ... In chemistry, delocalized electrons are electrons in a molecule that do not belong to a single atom or a covalent bond. ...


Graphite and graphite powder is valued in industrial applications for its self-lubricating and dry lubricating properties. There is a common belief that graphite's lubricating properties are solely due to the loose interlamellar coupling between sheets in the structure. However, it has been shown that in a vacuum environment (such as in technologies for use in space), graphite is a very poor lubricant. This observation led to the discovery that the lubrication is due to the presence of fluids between the layers, such as air and water, which are naturally adsorbed from the environment. This molecular property is unlike other layered, dry lubricants such as molybdenum disulfide. Recent studies suggest that an effect called superlubricity can also account for graphite's lubricating properties. The use of graphite is limited by its tendency to facilitate pitting corrosion in some stainless steels, and to promote galvanic corrosion between dissimilar metals (due to its electrical conductivity). It is also corrosive to aluminium in presence of moisture. For this reason, the US Air Force banned its use as a lubricant in aluminium aircraft [1], and discouraged its use in aluminium-containing automatic weapons [2]. Even graphite pencil marks on aluminium parts may facilitate corrosion [3]. Another high-temperature lubricant, hexagonal boron nitride, has the same molecular structural as graphite. It is sometimes called white graphite, due to its similar properties. A lubricant (colloquially, lube) is a substance (often a liquid) introduced between two moving surfaces to reduce the friction and wear between them. ... Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite planes, creating smooth surfaces, of which there are several named types: Basal cleavage: cleavage parallel to the base of a crystal, or to the plane of the lateral axes. ... Look up Vacuum in Wiktionary, the free dictionary. ... Layers of Atmosphere - not to scale (NOAA)[1] Outer space, sometimes simply called space, refers to the relatively empty regions of the universe outside the atmospheres of celestial bodies. ... In chemistry, a molecule is adsorbed onto a surface when temporary bonds are formed between the surface and the molecule. ... Molybdenum disulfide, also called molybdenum sulfide or molybdenum(IV) sulfide, with the formula MoS2, is a black crystalline sulfide of molybdenum. ... Superlubricity is a certain phenomenon in which friction can vanish almost completely. ... Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the creation of small holes in the metal. ... The 630 foot (192 m) high, stainless-clad (type 304) Gateway Arch defines St. ... For the hazard, see corrosive. ... Seal of the Air Force. ... This article is about the handwriting instrument. ... Boron nitride is a binary chemical compound, consisting of equal proportions of boron and nitrogen, with formula BN. Structurally, it is isoelectronic to carbon and takes on similar physical forms: a hexagonal, graphite-like one, and a cubic, diamond-like one. ...


When a large number of crystallographic defects binds these planes together, graphite loses its lubrication properties and becomes what is known as pyrolytic carbon. This material is useful for blood-contacting implants such as prosthetic heart valves. It is also highly diamagnetic, thus it will float in mid-air above a strong magnet. Pyrolytic carbon is a material similar to graphite, but with some covalent bonding between its graphene sheets. ... A United States soldier demonstrates Foosball with two prosthetic limbs In medicine, a prosthesis is an artificial extension that replaces a missing part of the body. ... Grays Fig. ... Diamagnetism is a very weak form of magnetism that is only exhibited in the presence of an external magnetic field. ...


Graphite forms intercalation compounds with some metals and small molecules. In these compounds, the host molecule or atom gets "sandwiched" between the graphite layers, resulting in compounds with variable stoichiometry. A prominent example of an intercalation compound is potassium graphite, denoted by the formula KC8. Graphite intercalation compounds are intercalation compounds with a graphite host. ...


Natural and crystalline graphites are not often used in pure form as structural materials, due to their shear-planes, brittleness and inconsistent mechanical properties.


History

Some time before 1565 (some sources say as early as 1500), an enormous deposit of graphite was discovered at the site of Seathwaite Fell near Borrowdale, Cumbria, England, which the locals found very useful for marking sheep. This particular deposit of graphite was extremely pure and solid, and could easily be sawn into sticks. This remains the only deposit of graphite found in this solid form.[1] Seathwaite Fell is an area of the Lake District in Cumbria, England. ... Cumbria is an administrative county located in the northwest area of England. ...


Uses

According to the USGS, U.S. consumption of natural graphite in 2005-06 averaged 41,850 tonnes in end uses such as refractories, steelmaking, expanded graphite, brake linings, and foundry facings-lubricants. GAN (Graphite Advocate News) import-export statistics for 2006 and 2007 indicate the consumption will continue at that level unless steelmaking carbon raiser takes a drastic drop. The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Refractories

This end-use begins before 1900 with the graphite crucible used to hold molten metal; this is now a minor part of refractories. In the mid1980s, the carbon-magnesite brick became important, and a bit later the alumina-graphite shape. Currently the order of importance is alumina-graphite shapes, carbon-magnesite brick, monolithics (gunning and ramming mixes), and then crucibles. Crucibles began using very large flake graphite, and carbon-magnesite brick requiring not quite so large flake graphite; for these and others there is now much more flexibility in size of flake required, and amorphous graphite is no longer restricted to low-end refractories. Alumina-graphite shapes are used as continuous casting ware, such as nozzles and troughs, to convey the molten steel from ladle to mould, and carbon magnesite bricks line steel converters and electric arc furnaces to withstand extreme temperatures. High-purity monolithics are often used as a continuous furnace lining instead of the carbon-magnesite bricks. The U.S. and European refractories industry had a crisis in 2000-2003, with an indifferent market for steel and a declining refractory consumption per tonne of steel underlying firm buyouts and many plant closings. Many of the plant closings resulted from the RHI acquisition of Harbison-Walker Refractories; some plants had their equipment auctioned off. Since much of the lost capacity was for carbon-magnesite brick, graphite consumption within refractories area moved towards alumina-graphite shapes and monolithics, and away from the brick. The major source of carbon-magnesite brick is now imports from China. Almost all of the above refractories are used to make steel and account for 75% of refractory consumption; the rest is used by a variety of industries, such as cement. According to the USGS, 2006 U.S. natural graphite consumption in refractories was 11,000 tonnes and in 2005 11,800 tonnes. This article is about heat resistance. ... For other uses, see Crucible (disambiguation). ... The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Steelmaking

Natural graphite in this end use mostly goes into carbon raising in molten steel, although it can be used to lubricate the dies used to extrude hot steel. Supplying carbon raiser is very competitive, therefore subject to cut-throat pricing from alternatives such as synthetic graphite powder, petroleum coke, and other forms of carbon. A carbon raiser is added to increase the carbon content of the steel to the specified level. A GAN consumption estimate based on USGS U.S. graphite consumption statistics indicates that 10,500 tonnes was used in this end-use in 2005. The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Expanded Graphite

Expanded graphite is made by immersing natural flake graphite in a bath of chromic acid, then concentrated sulfuric acid, which forces the crystal lattice planes apart, thus expanding the graphite. The expanded graphite can be used to make graphite foil or used directly as "hot top" compound to insulate molten metal in a ladle or red-hot steel ingots and decrease heat loss, or as firestops fitted around a firedoor (During a fire, the graphite expands and chars to resist fire penetration and spread.), or to make high-performance gasket material for high-temperature use. After being made into graphite foil, the foil is machined and assembled into the bipolar plates in fuel cells. The foil is made into heat sinks for laptop computers which keeps them cool while saving weight, and is made into a foil laminate that can be used in valve packings or made into gaskets. Old-style packings are now a minor member of this grouping: fine flake graphite in oils or greases for uses requiring heat resistance. A GAN estimate of current U.S. natural graphite consumption in this end use is 7,500 tonnes. In chemistry, chromic acid is a chromium (Cr) compound, yet to be isolated, with the formula H2CrO4. ... R-phrases S-phrases , , , Flash point Non-flammable Related Compounds Related strong acids Selenic acid Hydrochloric acid Nitric acid Related compounds Hydrogen sulfide Sulfurous acid Peroxymonosulfuric acid Sulfur trioxide Oleum Supplementary data page Structure and properties n, εr, etc. ... A fuel cell is an electrochemical device similar to a battery, but differing from the latter in that it is designed for continuous replenishment of the reactants consumed; i. ... Laptop with touchpad. ...


Brake Linings

Natural amorphous and fine flake graphite are used in brake linings or brake shoes for heavier (nonautomotive) vehicles, and became important with the need to substitute for asbestos. This use has been important for quite some time, but nonasbestos organic (NAO) compositions are beginning to cost graphite market share. A brake-lining industry shake-out with some plant closings has not helped either, nor has an indifferent automotive market. According to the USGS, U.S. natural graphite consumption in brake linings was 6,510 tonnes in 2005. A brake is a device for slowing or stopping the motion of a machine or vehicle, and to keep it from starting to move again. ... For other uses, see Asbestos (disambiguation). ... The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Foundry facings and lubricants

A foundry facing or mold wash is a water-based paint of amorphous or fine flake graphite. Painting the inside of a mold with it and letting it dry leaves a fine graphite coat that will ease separation of the object cast after the hot metal has cooled. Graphite lubricants are specialty items for use at very high or very low temperatures, as a wire die extrusion lubricant, an antiseize agent, a gear lubricant for mining machinery, and to lubricate locks. Having low-grit graphite, or even better no-grit graphite (ultra high purity), is highly desirable. It can be used as a dry powder, in water or oil, or as colloidal graphite (a permanent suspension in a liquid). An estimate based on USGS graphite consumption statistics indicates that 2,200 tonnes was used in this end-use in 2005. A lubricant (colloquially, lube) is a substance introduced between two moving surfaces to reduce the friction and wear between them. ... The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Other uses

Natural graphite is the substance used as the marking material ("lead") in common pencils, in zinc-carbon batteries, in electric motor brushes, and in some other minor uses. This article is about the handwriting instrument. ... Zinc-carbon batteries of different sizes. ... For other kinds of motors, see motor. ...


Uses of synthetic graphite

Electrodes

These electrodes carry the electricity that heats electric arc furnaces, the vast majority steel furnaces. They are made from petroleum coke after it is mixed with petroleum pitch, extruded and shaped, then baked to sinter it, and then graphitized by heating it above the temperature that converts carbon to graphite. They can vary in size from 6 in. long to 6 ft. in diameter. The graphite electrode market is shrinking: plasma-arc furnaces (no electrodes) are often replacing electric arc furnaces, and the electric arc furnace itself is getting more efficient and making more steel per tonne of electrode. An estimate based on USGS data indicates that graphite electrode consumption was 197,000 tonnes in 2005. Petroleum coke (often abbreviated petcoke) is a carbonaceous solid derived from oil refinery coker units or other cracking processes. ... The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Powder and scrap

The powder is made by heating powdered petroleum coke above the temperature of graphitization, sometimes with minor modifications. The graphite scrap comes from pieces of unusable electrode material (in the manufacturing stage or after use) and lathe turnings, usually after crushing and sizing. Most synthetic graphite powder goes to carbon raising in steel (competing with natural graphite), with some used in batteries and brake linings. According to the USGS, U.S. synthetic graphite powder and scrap production was 95,000 tonnes in 2001 (latest data). Petroleum coke (often abbreviated petcoke) is a carbonaceous solid derived from oil refinery coker units or other cracking processes. ... The United States Geological Survey (USGS) is a scientific agency of the United States government. ...


Other uses

Graphite (carbon) fiber and carbon nanotubes are also used in carbon fiber reinforced plastics, and in heat-resistant composites such as reinforced carbon-carbon (RCC). Products made from carbon fiber graphite composites include fishing rods, golf clubs, and bicycle frames, and have been successfully employed in reinforced concrete. The mechanical properties of carbon fiber graphite-reinforced plastic composites and grey cast iron are strongly influenced by the role of graphite in these materials. In this context, the term "(100%) graphite" is often loosely used to refer to a pure mixture of carbon reinforcement and resin, while the term "composite" is used for composite materials with additional ingredients. 3D model of three types of single-walled carbon nanotubes. ... Tail of a RC helicopter, made of CFRP Carbon fiber reinforced plastic or (CFRP or CRP), is a very strong, light and expensive composite material or fiber reinforced plastic. ... Mock-up of a space shuttle leading edge, showing brittle failure of RCC due to foam impact reproducing the conditions of Columbias final launch. ... A fiberglass spinning rod and reel circa 1997. ... Reinforced concrete at Sainte Jeanne dArc Church (Nice, France): architect Jacques Dror, 1926–1933 Reinforced concrete, also called ferroconcrete in some countries, is concrete in which reinforcement bars (rebars) or fibers have been incorporated to strengthen a material that would otherwise be brittle. ... Cast iron usually refers to grey cast iron, but can mean any of a group of iron-based alloys containing more than 2% carbon (alloys with less carbon are carbon steel by definition). ... Composite materials (or composites for short) are engineering materials made from two or more components. ...


Synthetic graphite also finds use as a matrix and neutron moderator within nuclear reactors. Its low neutron cross section also recommends it for use in proposed fusion reactors. Care must be taken that reactor-grade graphite is free of neutron absorbing materials such as boron, widely used as the seed electrode in commercial graphite deposition systems-- this caused the failure of the Germans' World War II graphite-based nuclear reactors. Since they could not isolate the difficulty they were forced to use far more expensive heavy water moderators. Graphite used for nuclear reactors is often referred to as Nuclear Graphite. However, with the public abhorrence of nuclear power and nuclear activities, this use is minor and likely to stay so. This does not cite any references or sources. ... Core of a small nuclear reactor used for research. ... In nuclear and particle physics, the concept of a cross section is used to express the likelihood of interaction between particles. ... Also try: fusion power This article is about a fictional warship in the game Halo. ... For other uses, see Boron (disambiguation). ... Combatants Allied powers: China France Great Britain Soviet Union United States and others Axis powers: Germany Italy Japan and others Commanders Chiang Kai-shek Charles de Gaulle Winston Churchill Joseph Stalin Franklin Roosevelt Adolf Hitler Benito Mussolini Hideki Tōjō Casualties Military dead: 17,000,000 Civilian dead: 33,000... Heavy water is dideuterium oxide, or D2O or 2H2O. It is chemically the same as normal water, H2O, but the hydrogen atoms are of the heavy isotope deuterium, in which the nucleus contains a neutron in addition to the proton found in the nucleus of any hydrogen atom. ... Nuclear graphite refers specifically to grades of graphite, usually electro-graphite, specifically manufactured for use as a moderator or reflector within nuclear reactors. ...


Graphite has been used in at least three radar absorbent materials. It was mixed with rubber in Sumpf and Schornsteinfeger, which were used on U-boat snorkels to reduce their radar cross section. It was also used in tiles on early F-117 Nighthawks. Radar absorbent material, or RAM, is a class of materials used in stealth technology to disguise a vehicle or structure from radar detection. ... Typical RCS diagram (B-26 Invader) Radar cross section (RCS) describes the extent to which an object reflects an incident electromagnetic wave. ... This article is about the stealth fighter. ...


Graphite mining, beneficiation, and milling

Graphite is mined around the world by both open pit and underground methods. While flake graphite and amorphous graphite are both mined open pit and underground, lump (vein) graphite is only mined underground in Sri Lanka. The open pit mines usually employ equipment (i.e. bulldozers) to scoop up the ore, which is usually put in trucks and moved to the plant. Since the original rock is usually lateritized or weathered, this amounts to moving dirt with flecks or pieces of graphite in it from the pit (blasting is seldom required). The underground graphite mines employ drilling and blasting to break up the hard rock (ore), which is then moved by mine cars pulled by a locomotive, or moved by automotive vehicles, to the surface and then to the plant. In less-developed areas of the world, the ore can be mined by pick and shovel and transported by mine cars pushed by a laborer or by women carrying baskets of ore on their heads.


Graphite usually needs beneficiation, although thick-bedded amorphous graphite and vein graphite is almost always beneficiated, if beneficiated at all, by laborers hand-picking out the pieces of gangue (rock) and hand-screening the product. The great majority of world flake graphite production is crushed and ground if necessary and beneficiated by flotation. Treating graphite by flotation encounters one big difficulty: graphite is very soft and "marks" (coats) the particles of gangue. This makes the "marked" gangue particles float off with the graphite to yield a very impure concentrate. There are two ways of obtaining a saleable concentrate or product: regrinding and floating it again and again (up to seven times) to obtain a purer and purer concentrate, or by leaching (dissolving) the gangue with hydrofluoric acid (for a silicate gangue) or hydrochloric acid (for a carbonate gangue).


In the milling process, the incoming graphite products and concentrates can be ground before being classified (sized or screened), with the coarser flake size fractions (above 8 mesh, 8 mesh to 20 mesh, 20 mesh to 50 mesh) carefully preserved, and then the carbon contents are determined. Then some standard blends can be prepared from the different fractions, each with a certain flake size distribution and carbon content. Custom blends can also be made for individual customers who want a certain flake size distribution and carbon content. If flake size is unimportant, the concentrate can be ground more freely. Typical final products include a fine powder for use as a slurry in oil drilling; in zirconium silicate, sodium silicate and isopropyl alcohol coatings for foundry molds; and a carbon raiser in the steel industry ( Synthetic graphite powder and powdered petroleum coke can also be used as carbon raiser)(Earth Metrics, 1989). Rough graphite is typically classified, ground, and packaged at a graphite mill; often the more complex formulations are also mixed and packaged at the mill facility. Environmental impacts from graphite mills consist of air pollution including fine particulate exposure of workers and also soil contamination from powder spillages leading to heavy metals contaminations of soil. Dust masks are normally worn by workers during the production process to avoid worker exposure to the fine airborne graphite and zircon silicate. An oil well is a laymans term for any perforation through the Earths surface designed to find and release both petroleum oil and gas hydrocarbons. ... General Name, Symbol, Number zirconium, Zr, 40 Chemical series transition metals Group, Period, Block 4, 5, d Appearance silvery white Standard atomic weight 91. ... In chemistry, a silicate is a compound containing an anion in which one or more central silicon atoms are surrounded by electronegative ligands. ... Sodium silicate, also known as water glass or liquid glass, available in aqueous solution and in solid form, is a compound used in cements, passive fire protection, refractories, textile and lumber processing. ... Isopropyl alcohol (also isopropanol or rubbing alcohol) is a common name for propan-2-ol, a colorless, flammable chemical compound with a strong odor. ... A foundry is a factory which produces castings of metal, both ferrous and non-ferrous. ... For other uses, see Steel (disambiguation). ... Excavation of leaking underground storage tank causing soil contamination Soil pollution comprises the pollution of soils with materials, mostly chemicals, that are out of place or are present at concentrations higher than normal which may have adverse effects on humans or other organisms. ... For other uses, see Heavy metal (disambiguation). ... Zircon is a mineral belonging to the group of nesosilicates. ...


Graphite recycling

The most common way graphite is recycled occurs when synthetic graphite electrodes (or anodes or cathodes) are either manufactured and pieces are cut off or lathe turnings are discarded, or the electrode (or other) are used all the way down to the electrode holder. A new electrode replaces the old one , but a sizeable piece of the old electrode remains. This is crushed and sized, and the resulting graphite powder is mostly used to raise the carbon content of molten steel. Graphite-containing refractories are sometimes also recycled , but often not because of their graphite: the largest-volume items, such as carbon-magnesite bricks that contain only 15%-25% graphite, usually contain too little graphite. However, some recycled carbon-magnesite brick is used as the basis for furnace repair materials, and also crushed carbon-magnesite brick is used in slag conditioners. While crucibles have a high graphite content, the volume of crucibles used and then recycled is very small.


A high-quality flake graphite product that closely resembles natural flake graphite can be made from steelmaking kish. Kish is a large-volume near-molten waste skimmed from the molten iron feed to a basic oxygen furnace, and is a mix of graphite (precipitated out of the supersaturated iron), lime-rich slag, and some iron. The iron is recycled on site, so what is left is a mixture of graphite and slag. The best recovery process uses hydraulic classification (Which utilizes a flow of water to separate minerals by specific gravity: graphite is light and settles nearly last.) to get a 70% graphite rough concentrate. Leaching this concentrate with hydrochloric acid gives a 95% graphite product with a flake size ranging from 10 mesh down.


Pencils

Many people think that lead is in pencils. But they are wrong. There is really no such thing as a 'lead pencil' now in the 21st century. The 'lead' in pencils is graphite. It is simple and safe to use. When you write with a pencil, a very thin layer of graphite comes off your pencil and onto your paper.


Media

  • Graphite animation

    Image:graphite stereo animation.gif
    Rotating graphite stereogram. (2.79 MB, animated GIF format).


    Animation of a rotating graphite structure. ... Animation of a rotating graphite structure. ... Stereogram may also refer to an integrated high fidelity system or music centre. ... ReBoot character, see Megabyte (ReBoot). ... GIF (Graphics Interchange Format) is a bitmap image format that is widely used on the World Wide Web, both for still images and for animations. ...

  • Problems seeing the videos? See media help.

See also

Carbon fiber composite is a strong, light and very expensive material. ... An intumescent is a substance which swells as a result of heat exposure, thus increasing in volume, and decreasing in density. ... Fire-resistance rated wall assembly with fire door, cable tray penetration and intumescent [1] cable coating. ... Pyrolytic carbon is a material similar to graphite, but with some covalent bonding between its graphene sheets. ... This article is about the mineral. ... Lonsdaleite is a hexagonal allotrope of the carbon allotrope diamond, believed to form when meteoric graphite falls to Earth. ... It has been suggested that Quasam be merged into this article or section. ... 3D model of three types of single-walled carbon nanotubes. ... The Icosahedral Fullerene C540 C60 and C-60 redirect here. ... This article is about the handwriting instrument. ...

References

  1. ^ Pencil (2007-08-07). Retrieved on 2007-08-07.
  • C.Michael Hogan, Marc Papineau et al., Phase I Environmental Site Assessment, Asbury Graphite Mill, 2426-2500 Kirkham Street, Oakland, California, Earth Metrics report 10292.001, December 18, 1989
  • Klein, Cornelis and Cornelius S. Hurlbut, Jr. (1985) Manual of Mineralogy: after Dana 20th ed. ISBN 0-471-80580-7
  • Taylor, Harold A., "Graphite", Financial Times Executive Commodity Reports (London: Mining Journal Books ltd.) 2000 ISBN 1-84083-332-7
  • Taylor, Harold A., "Graphite", Industrial Minerals and Rocks, 7th ed. (Littleton, CO AIME-Society of Mining Engineers) 2005 ISBN 0-87335-233-5

Year 2007 (MMVII) is the current year, a common year starting on Monday of the Gregorian calendar and the AD/CE era in the 21st century. ... is the 219th day of the year (220th in leap years) in the Gregorian calendar. ... Year 2007 (MMVII) is the current year, a common year starting on Monday of the Gregorian calendar and the AD/CE era in the 21st century. ... is the 219th day of the year (220th in leap years) in the Gregorian calendar. ... Any piece of real estate can be the subject of a Phase I ESA. A Phase I Environmental Site Assessment is a report prepared for a real estate holding which identifies potential or existing environmental contamination liabilities. ...

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Graphite (802 words)
Graphite is intended to serve as the principal non-Roman renderer for the
Graphite development list is for those who would like to participate in the development of the Graphite system, either by seeing new features added, porting to other platforms, or integrating Graphite support into an application.
Graphite fonts list is for those are interested in using Graphite to create smart fonts.
Graphite - Wikipedia, the free encyclopedia (712 words)
In its pure glassy (isotropic) synthetic forms, pyrolytic graphite and carbon fiber graphite is an extremely strong, heat-resistant (to 3000 °C) material, used in reentry shields for missile nosecones, solid rocket engines, high temperature reactors, brake shoes, electric motor brushes and as electrodes in EDM electrical discharge machines.
During a fire, the graphite intumesces (expands and chars) to resist fire penetration and reduce the likelihood of the spread of fire and fumes.
Care must be taken that reactor-grade graphite is free of neutron absorbing materials such as boron, widely used as the seed electrode in commercial graphite deposition systems-- this caused the failure of the Germans' World War II graphite-based nuclear reactors.
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