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Encyclopedia > Ideal gas constant
Values of R
8.314570 (J)(K-1)(mol-1)
0.0820578 (L)(atm)(K-1)(mol-1)
62.3639 (L)(torr)(K-1)(mol-1)
1.987 (cal)(K-1)(mol-1)

Molar gas constant (also known as universal gas constant, usually denoted by symbol R) is the constant occurring in the universal gas equation, i.e. the equation of state of an ideal gas:

Here p is the pressure of gas, V the volume it occupies, n the number of moles of gas, and T its temperature.


It can be shown that R is an universal constant, equal for all gases. Real gases obey this equation only in an approximation of very diluted gases.


R also appears in the Nernst equation as well as in the Lorentz-Lorenz formula.


Its value is:

R = 8.314570[70] J K-1 mol-1

The two digits in brackets signify the uncertainty (standard deviation) in the last two digits of the value.


The Boltzmann constant kB is defined as a ratio of molar gas constant and the Avogadro's number:

With it we can write the universal gas equation

with n now the actual number of molecules.


Density of gas

At standard temperature and pressure (273.15 K, 101 325 Pa) we get a volume per mole of 8.314570*273.15/101325 = 0.0224 cubic metre, is 22.4 litre.


Conversely, a cubic metre contains 1000/22.4 = 44.6 mole. Thus the density in kg/m3 is 0.0446 times the average molecular mass.


Examples:

  • hydrogen: molecular mass is 2, gives density of 0.089 kg/m3
  • air: average molecular mass is 29, gives density of 1.23 kg/m3
  • radon: molecular mass is 222, gives density of 9.9 kg/m3 (actually it is 9.73)

The small deviation may be because of not being an ideal gas.


The volume of space available per molecule is 37.2 nm3.


  Results from FactBites:
 
Ideal gas - Wikipedia, the free encyclopedia (934 words)
An ideal gas or perfect gas is a hypothetical gas consisting of identical particles of negligible volume, with no intermolecular forces.
The thermodynamic properties of an ideal gas can be described by two equations: The equation of state of a classical ideal gas is given by the ideal gas law.
Any gas behaves as an ideal gas at high enough temperature and low enough density, but at the point where the Sackur-Tetrode equation begins to break down, the gas will begin to behave as a quantum gas, composed of either bosons or fermions.
Gas constant - Wikipedia, the free encyclopedia (191 words)
The gas constant (also known as the universal or ideal gas constant, usually denoted by symbol R) is a physical constant used in equations of state to relate various groups of state functions to one another.
The gas constant occurs in the simplest equation of state, the ideal gas equation, as follows:
The gas constant is conversion factor between gas units.
  More results at FactBites »


 

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