FACTOID # 98: Members of the armed forces and the police cannot vote in the Dominican Republic.
 
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Encyclopedia > Locant

See the definition at CancerWEB's online medical dictionary.


A locant can be used in organic chemistry to indicate the position of a functional group within a molecule. For example, there are at least two isomers of the linear form of pentanone, a ketone that contains a chain of exactly five carbon atoms. There is an oxygen atom bonded to one of the middle three carbons (if it were bonded to an end carbon, the molecule would be an aldehyde, not a ketone), but where? Organic chemistry is the scientific study of the structure, properties, composition, reactions, and synthesis of organic compounds that by definition contain carbon. ... In ecology functional groups are collections of organisms based on morphological, physiological, behavioral, biochemical, or environmental responses or on trophic criteria. ... A molecule is the smallest particle of a pure chemical substance that still retains its chemical composition and properties. ... In chemistry, isomers are molecules with the same chemical formula and often with the same kinds of bonds between atoms, but in which the atoms are arranged differently. ... A ketone is either the functional group characterized by a carbonyl group linked to two other carbon atoms or a compound that contains this functional group. ... General Name, Symbol, Number carbon, C, 6 Chemical series nonmetals Group, Period, Block 14, 2, p Appearance black (graphite) colorless (diamond) Atomic mass 12. ... General Name, Symbol, Number oxygen, O, 8 Chemical series nonmetals Group, Period, Block 16, 2, p Appearance colorless Atomic mass 15. ... An aldehyde is either a functional group consisting of a terminal carbonyl group, or a compound containing a terminal carbonyl group. ...


First number the carbons from one to five, starting at one end and proceeding sequentially along the chain. Now the position of the oxygen atom can be defined as on carbon atom number two, three or four. In fact atoms two and four are exactly equivalent - imagine turning the molecule around by 180 degrees, and you will see that this is the case. It just depends on which end you choose to start numbering the carbons.


The locant is the number of the carbon atom to which the oxygen atom is bonded. If the oxygen is bonded to the middle carbon, the locant is 3. If the oxygen is bonded to an atom on either side (adjacent to an end carbon), the locant is 2 or 4; given the choice here, where the carbons are exactly equivalent, always choose the lower number. So the locant is either 2 or 3 in this molecule. Properties For alternative meanings see atom (disambiguation). ...


The locant is incorporated into the name of the molecule to remove ambiguity. Thus the molecule is named either pentan-2-one or pentan-3-one, depending on the position of the oxygen atom. This can also be called diethyl ketone. ...


  Results from FactBites:
 
Locant - Wikipedia, the free encyclopedia (300 words)
A locant can be used in organic chemistry to indicate the position of a functional group within a molecule.
The locant is the number of the carbon atom to which the oxygen atom is bonded.
If the oxygen is bonded to an atom on either side (adjacent to an end carbon), the locant is 2 or 4; given the choice here, where the carbons are exactly equivalent, always choose the lower number.
Enynes (263 words)
The alkene suffix "ene" minus the last "e" is inserted after the root with its locant before the root.
The chain is numbered in accord with the first point of difference rule to either the alkene or alkyne units the lowest possible locant.
The locant for the lowest numbered carbon of the alkene or alkyne is used in the name.
  More results at FactBites »


 

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