Mariner 1 and Mariner2 - As the first spacecraft to fly by another planet, Mariner2 was built as a backup to Mariner 1, which failed shortly after launch to Venus.
Mariner 5 - The Mariner 5 spacecraft launched to Venus on June 14, 1967 and arrived in the vicinity of the planet in October 1967.
Mariner 10 was the first spacecraft to use a gravity assist trajectory, accelerating as it entered the gravitational influence of Venus, then being flung by the planet's gravity onto a slightly different course to reach Mercury.
The scientific instruments onboard the Mariner spacecraft were two radiometers (microwave and infrared) mounted on a tilting platform, a micrometeorite sensor, a solar plasma sensor, a charged particle sensor, and a magnetometer.
Mariner2 consisted of a hexagonal base, 1.04 meters across and 0.36 meters thick, which contained six magnesium chassis housing the electronics for the science experiments, communications, data encoding, computing, timing, and attitude control, and the power control, battery, and battery charger, as well as the attitude control gas bottles and the rocket engine.
Mariner2 approached Venus from 30 degrees above the dark side of the planet, and passed below the planet at its closest distance of 34,773 km at 19:59:28 UT 14 December 1962.