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Encyclopedia > Methoxymethane
Dimethyl ether
Dimethyl ether
General
Systematic name methoxymethane
Other names DME, wood ether
dimethyl oxide
Demeon, Dymel A
Molecular formula C2H6O
SMILES COC
Molar mass 46.07 g/mol
Appearance colourless gas with
typical smell
CAS number [115-10-6]
Properties
Density and phase 1.59, gas (vs air)
668 kg/m3, liquid
Solubility in water 328 g/100 ml (20°C)
in methanol,
ethanol, toluene
soluble
Melting point -138.5°C (134.6 K)
Boiling point -24.9°C (248.2 K)
Structure
Molecular shape  ?
Dipole moment  ? D
Hazards
MSDS External MSDS
Main hazards highly flammable
NFPA 704 Image:nfpa_h1.png Image:nfpa_f4.png Image:nfpa_r1.png
Flash point -41°C
R/S statement R: 12
S: 2, 9, 16, 33
RTECS number PM3780000
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Related ethers diethyl ether
crown ether
polyethylene glycol
Related compounds methanol
Except where noted otherwise, data are given for
materials in their standard state (at 25°C, 100 kPa)
Infobox disclaimer and references

Dimethyl ether, also known as methoxymethane, methyl ether, wood ether, and DME, is a colorless gaseous ether with with an ethereal smell. Dimethyl ether gas is water soluble. It has the formula CH3OCH3. Dimethyl ether is used as an aerosol spray propellant. Dimethyl ether is also a clean-burning alternative to liquified petroleum gas, liquified natural gas, diesel and gasoline. It can be made from natural gas, coal, or biomass. IUPAC nomenclature is a systematic way of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). ... A chemical formula (also called molecular formula) is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... The simplified molecular input line entry specification or SMILES is a specification for unambiguously describing the structure of chemical molecules using short ASCII alpha-numeric strings. ... Molar mass is the mass of one mole of an element or chemical compound. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences, mixtures and alloys. ... Density (symbol: ρ - Greek: rho) is a measure of mass per unit of volume. ... In the physical sciences, a phase is a set of states of a macroscopic physical system that have relatively uniform chemical composition and physical properties (i. ... A substance is soluble in a fluid if it dissolves in the fluid. ... Water is in dynamic equilibrium between the liquid and solid states at standard temperature and pressure. ... Methanol, also known as methyl alcohol or wood alcohol, is a chemical compound with chemical formula CH3OH. It is the simplest alcohol, and is a light, volatile, colourless, flammable, poisonous liquid that is used as an antifreeze, solvent, fuel, and as a denaturant for ethyl alcohol. ... Ethyl alcohol, also known as ethanol or grain alcohol, is a flammable, colorless chemical compound, one of the alcohols that is most often found in alcoholic beverages. ... Toluene, also known as methylbenzene or phenylmethane is a clear water-insoluble liquid with the typical smell of paint thinners, reminiscent of the sweet smell of the related compound benzene. ... The melting point of a solid is the temperature at which it changes state from solid to liquid. ... The boiling point of a substance is the temperature at which it can change state from a liquid to a gas throughout the bulk of the liquid. ... In chemistry, hybridisation is the mixing of atomic orbitals to form new orbitals suitable for bonding. ... A dipole (Greek: dyo = two and polos = pivot) is a pair of electric charges or magnetic poles of equal magnitude but opposite polarity (opposite electronic charges), separated by some (usually small) distance. ... The debye (symbol: D) is a derived CGS unit of electrical dipole moment. ... A material safety data sheet or MSDS is a form containing data regarding the properties of a particular substance. ... Worker safety and health is the prevention and reduction of the number of occupational safety and health hazards at the places of employment, providing safe and healthful working conditions. ... NFPA 704 is a standard maintained by the National Fire Protection Association. ... Image File history File links File history Legend: (cur) = this is the current file, (del) = delete this old version, (rev) = revert to this old version. ... Image File history File links File history Legend: (cur) = this is the current file, (del) = delete this old version, (rev) = revert to this old version. ... Image File history File links File history Legend: (cur) = this is the current file, (del) = delete this old version, (rev) = revert to this old version. ... The flashpoint of a fuel is the lowest temperature at which it can form an ignitable mix with air. ... Risk and Safety Statements, also known as R/S statements, R/S numbers, R/S phrases, and R/S sentences, is a system of hazard codes and phrases for labeling dangerous chemicals and compounds. ... RTECS, also known as Registry of Toxic Effects of Chemical Substances, is a database of toxicity information compiled from the open scientific literature that is available for charge. ... The refractive index of a material is the factor by which electromagnetic radiation is slowed down (relative to vacuum) when it travels inside the material. ... The dielectric constant εr (represented as or K in some cases) is defined as the ratio: where εs is the static permittivity of the material in question, and ε0 is the vacuum permittivity. ... Ultraviolet-Visible spectroscopy or Ultraviolet-Visible spectrophotometry (UV/ VIS) involves the spectroscopy of photons (spectrophotometry). ... IR spectrum of a thin film of liquid ethanol. ... Nuclear Magnetic Resonance Spectroscopy is the name given to the technique which exploits the magnetic properties of nuclei. ... Mass spectrometry is a technique for separating ions by their mass-to-charge (m/z) ratios. ... Ether is the general name for a class of chemical compounds which contain an ether group — an oxygen atom connected to two (substituted) alkyl groups. ... Diethyl ether, also known as ether and ethoxyethane, is a clear, colorless, and highly flammable liquid with a low boiling point and a typical smell. ... Crown ethers are heterocyclic chemical compounds that, in their simplest form, are cyclic oligomers of dioxane. ... Chemical structure of the polymeric polyethylene glycol Polyethylene glycol (PEG) and polyethylene oxide are polymers of ethylene oxide. ... Methanol, also known as methyl alcohol or wood alcohol, is a chemical compound with chemical formula CH3OH. It is the simplest alcohol, and is a light, volatile, colourless, flammable, poisonous liquid that is used as an antifreeze, solvent, fuel, and as a denaturant for ethyl alcohol. ... In chemistry, the standard state of a material is its state at 1 bar (100. ... For other meanings see gas (disambiguation). ... Ether is the general name for a class of chemical compounds which contain an ether group — an oxygen atom connected to two (substituted) alkyl groups. ... The term smell may refer to one of the following articles: Olfaction - The sense of smell, that is, the ability to perceive odors Odor - the object being perceived by the sense of olfaction See also Wiktionary:Smell This is a disambiguation page — a navigational aid which lists other pages that... A substance is soluble in a fluid if it dissolves in the fluid. ... http://visibleearth. ... Liquified petroleum gas (also called liquefied petroleum gas, liquid petroleum gas, LPG, LP gas, or autogas) is a mixture of hydrocarbon gases used as a fuel in heating appliances and vehicles, and increasingly replacing fluorocarbons as an aerosol propellant and a refrigerant to reduce damage to the ozone layer. ... Liquified Natural Gas (LNG) is natural gas which has been artificially condensed into a liquid form by a combination of pressurisation and cryogenic cooling. ... Diesel fuel is a specific distillate fraction of fuel oil that is used in a diesel engine invented by German engineer Rudolf Diesel, and perfected by Charles F. Kettering. ... Gasoline, as it is known in North America, or petrol, in many Commonwealth countries (sometimes also called motor spirit) is a petroleum-derived liquid mixture consisting primarily of hydrocarbons, used as fuel in internal combustion engines. ... Natural gas rig Natural gas (commonly refered to as gas in many countries) is a gaseous fossil fuel consisting primarily of methane. ... Coal is a fossil fuel extracted from the ground either by underground mining, open-pit mining or strip mining. ... Biomass is organic non-fossil material, collectively. ...


External links

  • Facts about DME from the International DME Association
  • Chemical data and hazard links

  Results from FactBites:
 
Aflatoxin (138 words)
A method is described for removal of aflatoxin from groundnuts by extraction with methoxymethane (dimethylether) at room temperature in an autoclave or in pressure-tight columns.
Contaminated groundnuts are pulverized to pass through a 12 mesh screen, and extracted in stainless steel columns at approximately 6 kg/cm pressure.
The extract can be used for preparation of groundnut oil, as aflatoxin is inactivated during refining, and methoxymethane is easily removed from the defatted product because of its low boiling point.
intermolecular bonding - hydrogen bonds (1180 words)
In methoxymethane, the lone pairs on the oxygen are still there, but the hydrogens aren't sufficiently
Except in some rather unusual cases, the hydrogen atom has to be attached directly to the very electronegative element for hydrogen bonding to occur.
The boiling points of ethanol and methoxymethane show the dramatic effect that the hydrogen bonding has on the stickiness of the ethanol molecules:
  More results at FactBites »


 

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