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Encyclopedia > Nitrous acid
Nitrous acid
General
Systematic name Dioxonitric(III) acid
Other names Nitrous acid
Molecular formula HNO2
Molar mass 47.0134 g/mol
CAS number 7782-77-6
Properties
Density  ? g/cm3
Solubility (water)
Melting point  ? °C
Boiling point  ? °C
Acid dissociation
constant
pKa
3.34
Disclaimer and references

Nitrous acid (molecular formula HNO2) is a weak monobasic acid known only in solution and in the form of nitrite salts. IUPAC nomenclature is a systematic way of naming organic chemical compounds. ... A chemical formula (also called molecular formula) is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... General Name, Symbol, Number hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1, 1, s Appearance colorless Atomic mass 1. ... General Name, Symbol, Number nitrogen, N, 7 Chemical series nonmetals Group, Period, Block 15, 2, p Appearance colorless Atomic mass 14. ... General Name, Symbol, Number oxygen, O, 8 Chemical series Nonmetals, chalcogens Group, Period, Block 16, 2, p Appearance colorless (gas) very pale blue (liquid) Atomic mass 15. ... Molar mass is the mass of one mole of a chemical element or chemical compound. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences and alloys. ... Density (symbol: ρ - Greek: rho) is a measure of mass per volume. ... It has been suggested that Solid solubility be merged into this article or section. ... This article describes water from a scientific and technical perspective. ... The melting point of a solid is the temperature at which it changes state from solid to liquid. ... The boiling point of a substance is the temperature at which it can change its state from a liquid to a gas throughout the bulk of the liquid at a given pressure. ... In chemistry and biochemistry, the acid dissociation constant, the acidity constant, or the acid-ionization constant (Ka) is a specific type of equilibrium constant that indicates the extent of dissociation of hydrogen ions from an acid. ... General Name, Symbol, Number hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1, 1, s Appearance colorless Atomic mass 1. ... General Name, Symbol, Number nitrogen, N, 7 Chemical series nonmetals Group, Period, Block 15, 2, p Appearance colorless Atomic mass 14. ... General Name, Symbol, Number oxygen, O, 8 Chemical series Nonmetals, chalcogens Group, Period, Block 16, 2, p Appearance colorless (gas) very pale blue (liquid) Atomic mass 15. ... For other uses, see Acid (disambiguation). ... Dissolving table salt in water In chemistry, a solution is a homogeneous mixture composed of one or more substances, known as solutes, dissolved in another substance, known as a solvent. ... // Definition The nitrite ion is NO2−. A nitrite compound is one that contains this group, either an ionic compound, or an analogous covalent one. ...


Nitrous acid is used to make diazides from amines; this occurs by nucleophilic attack of the amine onto the nitrite, reprotonation by the surrounding solvent, and double elimination of water. The diazide can then be liberated as a carbene. // Definition The nitrite ion is NO2−. A nitrite compound is one that contains this group, either an ionic compound, or an analogous covalent one. ... In chemistry a carbene is a short-lived and highly reactive organic molecule with a divalent carbon atom with only six valence electrons and the general formula: R1R2C: . The carbon atom is sp2 hybridised with an empty p-orbital extending above and below a plane containing R1 and R2 and...

Contents

Preparation

It can be prepared by adding any mineral acid to sodium nitrite. Sodium nitrite, with chemical formula NaNO2, also called nitrous acid, sodium salt, is used as a color fixative and preservative in meats and fish. ...


Decomposition

It rapidly decomposes into nitrogen dioxide, nitrogen monoxide and water when in solution. [1] R-phrases , S-phrases , , , , , Supplementary data page Structure and properties n, εr, etc. ... The chemical compound nitric oxide is a gas with chemical formula NO. It is an important signaling molecule in the body of mammals including humans, one of the few gaseous signaling molecules known. ... Water is a tasteless, odorless substance that is essential to all known forms of life and is known as the universal solvent. ...


Atmospheric relevance

Nitrous acid is an important atmospheric intermediate. It is produced by the heterogeneous reaction of NO2 and water on various surfaces such as atmospheric aerosols. It is readily photolysed to produce hydroxyl radicals which are intricately involved in the ozone budget of the troposphere (lower atmosphere).


See also

Please wikify (format) this article as suggested in the Guide to layout and the Manual of Style. ... The chemical compound nitric acid (HNO3), otherwise known as aqua fortis or spirit of nitre, is a colorless, corrosive liquid, a toxic acid which can cause severe burns. ... General Name, Symbol, Number hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1, 1, s Appearance colorless Atomic mass 1. ... General Name, Symbol, Number nitrogen, N, 7 Chemical series nonmetals Group, Period, Block 15, 2, p Appearance colorless Atomic mass 14. ... General Name, Symbol, Number oxygen, O, 8 Chemical series Nonmetals, chalcogens Group, Period, Block 16, 2, p Appearance colorless (gas) very pale blue (liquid) Atomic mass 15. ... This article or section does not cite its references or sources. ...

External links

  • Link page to external chemical sources.

  Results from FactBites:
 
Process for controlling diazotization reactions involving nitrous reactant by testing the air above the reaction batch ... (1771 words)
Nitrous acid or dissolved matter forming it under the reaction conditions is supplied to the feed amine in the proportions necessary to provide for a content between 5 and 300 ppm nitrous gases in the exhausted air.
As to nitrous acid in excess, it is possible for it to be consumed by the addition of further minor proportions of fresh amine (this operation is known as "balancing") or to be destroyed by means of urea or aminosulfonic acid.
The presence of nitrous acid in excess in the diazonium salt solution often affects the stability of the diazonium salts and also their use in the production of azo dyestuffs and azo pigments which are made by coupling reactions.
  More results at FactBites »


 

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