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Encyclopedia > Partition function

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Partition function (statistical mechanics) - Wikipedia, the free encyclopedia (1596 words)
In statistical mechanics, the partition function Z is an important quantity that encodes the statistical properties of a system in thermodynamic equilibrium.
There are actually several different types of partition functions, each corresponding to different types of statistical ensemble (or, equivalently, different types of free energy.) The canonical partition function applies to a canonical ensemble, in which the system is allowed to exchange heat with the environment at fixed temperature, volume, and number of particles.
An specific example of the partition function, expressed in terms of the mathematical formalism of measure theory, is presented in the article on the Potts model.
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