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Encyclopedia > Racemization

In chemistry racemization refers to partial conversion of one enantiomer into another. Chemistry (in Greek: χημεία) is the science of matter that deals with the composition, structure, and properties of substances and with the transformations that they undergo. ... In chemistry two stereoisomers are said to be enantiomers if they are mirror images of each other. ...


Asymmetric substances have two forms (at each point of asymmetry) which differ in their optical characteristics: the levorotatory form (the (-)-form) will rotate the plane of polarization of a beam of light to the left, while the dextrorotatory form (the (+)-form) will rotate the plane of polarization of a beam of light to the right. The two forms, which are mirror-images, are said to be enantiomorphic: each is the enantiomer of the other.


Many chemical processes take place without regard to a substance's optical characteristics, and result in a racemic mixture in which neither form predominates. However, pure forms of the enantiomers can be obtained: for example, by allowing crystalization, and hand-separating the left-handed and right-handed crystals. Biochemical reactions also prefer one form over another: most amino acids are asymmetric, and the L-form is used preferentially in biological systems.


Racemization is the process of a relatively pure substance becoming a mixture of enantiomeric forms; the rate of racemization (from L-forms to a mixture of L-forms and D-forms) has been used as a way of dating biological specimens.


  Results from FactBites:
 
Raceme - Wikipedia, the free encyclopedia (245 words)
This inflorescence of the terrestrial orchid Spathoglottis plicata is a typical raceme.
A raceme is a type of inflorescence that is unbranched and indeterminate and bears pedicellate flowers flowers having short floral stalks called pedicels — along the axis.
In a raceme, the oldest flowers are borne towards the base and new flowers are produced as the shoot grows.
cut-flower Orchid Grower: UH Cultivars: UH1299 (1755 words)
Raceme (spray) yield was recorded weekly for K706-18 progenies from July 1990 until December 1993, while progenies of the other three amphidiploids were observed from June 1993 to June 1996.
Scape length was measured from the point of attachment to the pseudobulbs to the lowest flower, while raceme length was measured from the point of attachment to the pseudobulbs to the tip of the raceme.
Mean raceme yield per plant from July 1990 to December 1993, scape length, raceme length, and number of flowers per raceme of K706-18 progenies.
  More results at FactBites »


 

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