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Encyclopedia > Raman effect

When light is scattered from a molecule most photons are elastically scattered. The scattered photons have the same energy (frequency) and, therefore, wavelength, as the incident photons. However, a small fraction of light (approximately 1 in 107 photons) is scattered at optical frequencies different from, and usually lower than, the frequency of the incident photons. The process leading to this inelastic scatter is the termed the Raman effect. Raman scattering can occur with a change in vibrational, rotational or electronic energy of a molecule. Chemists are concerned primarily with the vibrational Raman effect. In science, a molecule is the smallest particle of a pure chemical substance that still retains its chemical composition and properties. ... In physics, the photon (from Greek φοτος, meaning light) is a quantum of excitation of the quantised electromagnetic field and is one of the elementary particles studied by quantum electrodynamics (QED) which is the oldest part of the Standard Model of particle physics. ... Sine waves of various frequencies; the lower waves have higher frequencies than those above. ... The wavelength is the distance between repeating units of a wave pattern. ...

Contents

Sir C. V. Raman

Chandrasekhara Venkata Raman was born at Trichy in Tamilnadu in south India on November 7th, 1888. He entered Presidency College, Madras, in 1902, and in 1904 passed his B.A. examination, winning the first place and the gold medal in physics; in 1907 he gained his M.A. degree, obtaining the highest distinctions. In 1922 he published his work on the "Molecular Diffraction of Light," the first of a series of investigations with his collaborators which ultimately led to his discovery of the radiation effect, on the 28th of February, 1928, which bears his name ("A new radiation", Indian J. Phys., 2 (1928) 387), and which gained him the 1930 Nobel Prize in Physics. In 1934, Raman became the director of the newly established Indian Institute of Science in Bangalore, where two years later he continued as a professor of physics. In 1947, he was appointed as the first National Professor by the new government of Independent India. He retired from the Indian Institute in 1948 and a year later he established the Raman Research Institute in Bangalore, serving as its director and remained active there until his death on November 21, 1970, at the age of eighty two. Chandrasekhara Venkata Raman (चन्द्रशेखर वेङ्कट रामन्) (November 7, 1888-November 21, 1970) was an Indian physicist. ... Tiruchirapalli (also spelled Tiruchchirappalli, commonly known as Tiruchi or Trichy, formerly known as Trichinopoly under British rule) is a city situated on the banks of the Kaveri river, centrally located in the Indian state of Tamil Nadu. ... 1922 was a common year starting on Sunday (see link for calendar). ... Photographs of Nobel Prize Medals. ... Wikibooks Wikiversity has more about this subject: School of Physics sci. ... The Indian Institute of Science (IISc) is one of the premier post-graduate institutions of research and higher learning located in Bangalore, India. ... Bangalore (ಬೆಂಗಳೂರು in Kannada) is the capital city of Karnataka. ... 1970 was a common year starting on Thursday. ...


The Classical Raman Effect

The distortion of a molecule in an electric field is determined by its polarisability .


The Raman Effect is used in materials analysis. The frequency of light scattered from a molecule may be changed based on the structural characteristics of the molecular bonds. A monochromatic light source (laser) is required for illumination, and a spectrogram of the scattered light then shows the deviations caused by state changes in the molecule.


His Work

  • "Dynamical Theory of the Motion of Bowed Strings", Bulletin, Indian Association for the Advancement of Science, 1914
  • "On the molecular scattering of light in water and the colour of the sea", Proceedings of the Royal Society, 1922
  • "A new type of Secondary Radiation", Nature, 1928
  • "A new radiation", Indian Journal of Physics, 1928
  • Aspects of Science, 1948
  • The New Physics: Talks on Aspects of Science, 1951
  • Lectures on Physical Optics, 1959

External Links

  • Raman Spectroscopy - Tutorial (http://www.kosi.com/raman/resources/tutorial/)

  Results from FactBites:
 
Raman Spectroscopy Tutorial (2108 words)
The difference in energy between the incident photon and the Raman scattered photon is equal to the energy of a vibration of the scattering molecule.
The Raman effect arises when a photon is incident on a molecule and interacts with the electric dipole of the molecule.
Raman scatter is partially polarized, even for molecules in a gas or liquid, where the individual molecules are randomly oriented.
Raman spectroscopy - Wikipedia, the free encyclopedia (928 words)
Raman spectroscopy is a spectroscopic technique used in condensed matter physics and chemistry to study vibrational, rotational, and other low-frequency modes in a system.
Spontaneous Raman scattering is typically very weak, and as a result the main difficulty of Raman spectroscopy is separating the weak inelastically scattered light from the intense Rayleigh scattered laser light.
Raman won the Nobel Prize in Physics in 1930 for this discovery, accomplished using filtered sunlight as a monochromatic source of photons, a colored filter as a monochromator, and a human eye as detector.
  More results at FactBites »


 

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