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Encyclopedia > Rate constant

In chemical kinetics a reaction rate constant quantifies the speed of a chemical reaction. A rate equation is a mathematical expression used in chemistry to link the rate of a reaction to each reactant and their various orders. ... A chemical reaction is a process involving one, two or more substances (called reactants), characterized by a chemical change and yielding one or more product(s) which are different from the reactants. ...


For a chemical reaction k A + m B → C + D, the reaction rate is typically of the form A chemical reaction is a process involving one, two or more substances (called reactants), characterized by a chemical change and yielding one or more product(s) which are different from the reactants. ... The reaction rate for a reactant or product in a particular reaction is defined as the amount (in moles or mass units) per unit time per unit volume that is formed or removed. ...

frac{d[C]}{dt} = k(T)[A]^{k'}[B]^{m'}

Here [X] denotes, for a reaction between liquids, gases, or solutes, the concentration of X; for a reaction taking place at a boundary it would denote something like moles per area of X. Concentration is a very common concept used in chemistry and related fields. ...


In this equation k(T) is the reaction rate constant that depends on temperature.


The exponents k' and m' are called orders and depend on the reaction mechanism. In a single-step reaction can also be written as Order in the context of a chemical reaction is a concept of reaction kinetics, a subdiscipline of physical chemistry. ... An overall description of how a reaction occurs. ...

frac{d[C]}{dt} = ke^frac{-E_a}{RT}[A]^k[B]^m

Ea is the activation energy and R is the Gas constant. Since at temperature T the molecules have energies according to a Boltzmann distribution, one can expect the proportion of collisions with energy greater than Ea to vary with e-Ea/RT. K is the pre-exponential factor or frequency factor The activation energy in chemistry is the energy needed by a system to initiate a particular process. ... Molar gas constant (also known as universal gas constant, usually denoted by symbol R) is the constant occurring in the universal gas equation, i. ... Temperature is the physical property of a system which underlies the common notions of hot and cold; the material with the higher temperature is said to be hotter. ... The Maxwell-Boltzmann distribution is a probability distribution with applications in physics and chemistry. ...



The Arrhenius equation gives the quantitative basis of the relationship between the activation energy and the reaction rate at which a reaction proceeds. The Arrhenius equation predicts the rate of a chemical reaction at a certain temperature, given the activation energy and chance of successful collision of molecules. ... The activation energy in chemistry is the energy needed by a system to initiate a particular process. ... The reaction rate for a reactant or product in a particular reaction is defined as the amount (in moles or mass units) per unit time per unit volume that is formed or removed. ...


  Results from FactBites:
 
Constant bitrate - Wikipedia, the free encyclopedia (188 words)
Constant bit rate (CBR) is a term used in telecommunications, relating to the quality of service.
When referring to codecs, constant bit rate encoding means that the rate at which a codec's output data should be consumed is constant.
CBR is useful for streaming multimedia content on limited capacity channels since it is the maximum bit rate that matters, not the average, so CBR would be used to take advantage of all of the capacity.
Reaction rate - Wikipedia, the free encyclopedia (832 words)
The reaction rate for a reactant or product in a particular reaction is defined as the amount of the chemical that is formed or removed (in moles or mass units) per unit time per unit volume.
For a chemical reaction n A + m B → C + D, the rate equation or rate law is a mathematical expression used in chemical kinetics to link the rate of a reaction to the concentration of each reactant and their various orders.
In this equation k(T) is the reaction rate coefficient or rate constant, although it is not really a constant, because it includes everything that affects reaction rate outside concentration: mainly temperature but also ionic strength or light irradiation.
  More results at FactBites »

 

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