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Raul has been replaced in the squad by Valencia's attacking midfielder Miguel Angel Angulo, who at 29 is the oldest member of the squad, while the new captain is Madrid goalkeeper Iker Casillas.
Raul's usual goal celebration involves a brief kiss of his wedding ring but this time he careered off to the corner packed with Spanish fans, punched his chest and pointed to the crest on his red shirt.
Raul has been playing at an elite level for 12 seasons and has a medal collection, which includes three European Cups, four league titles and two World Club Cups, that would be the envy of most players when they end their careers.
Raul Castro, Cuban leader Fidel Castro's younger brother and designated successor, is no spring chicken.
Raul Castro has headed the Cuban armed forces ever since as minister of defense, and is first vice-president of the Council of State, constitutionally first in line to take over from the president in case of absence, illness or death.
Yet most analysts believe Raul is bound to play a crucial role, at least initially, in any political transition once his brother has left the scene, while ensuring military stability.