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Encyclopedia > Silicone resin

Silicone resins is a type of silicone material which is formed by branched, and cage-like oligosiloxanes with the general formula of RnSiXmOy, where R is a non reactive substituent, usually Me or Ph, and X is a functional group H, OH, Cl or OR. These groups are further condensed in many applications, to give highly crosslinked, insoluble polysiloxane networks. Wikipedia does not have an article with this exact name. ... Silicones, or polysiloxanes, are inorganic polymers consisting of a silicon-oxygen backbone (...-Si-O-Si-O-Si-O-...) with side groups attached to the silicon atoms. ... In chemistry a methyl-group is a hydrophobic Alkyl functional group which is derived from methane (CH4). ... In chemistry, a phenyl-group is a hydrophobic aromatic functional group which is derived from benzene (C6H6). ... General Name, Symbol, Number Hydrogen, H, 1 Chemical series nonmetals Group, Period, Block 1 (IA), 1, s Density, Hardness 0. ... Hydroxide is a functional group consisting of oxygen and hydrogen: -O−H It has a charge of 1-. The term hydroxyl group is used when the functional group -OH is counted as a substituent of an organic compound. ... General Name, Symbol, Number chlorine, Cl, 17 Series halogens Group, Period, Block 17 (VIIA), 3, p Density, Hardness 3. ... In chemistry, the alkoxyl group is an alkyl group linked to oxygen thus: R-O- In this function, R represents the alkyl group. ... Silicones, or polysiloxanes, are inorganic polymers consisting of a silicon-oxygen backbone (...-Si-O-Si-O-Si-O-...) with side groups attached to the silicon atoms. ...


When R is methyl, the four possible functional siloxane monomeric units are described as follows:

  • "M" stands for Me3SiO,
  • "D" for Me2SiO2,
  • "T" for MeSiO3 and
  • "Q" for SiO4.

The most abundant silicone resins are built of D and T units (DT resins) or from M and Q units (MQ resins), however many other combinations (MDT, MTQ, QDT) are also used in industry.


Silicone resins represent a broad range of products. Materials of molecular weight in the range of 1000-10 000 are very useful in pressure sensitive adhesives, silicone rubbers, coatings and additives.


Silicone resins are prepared by hydrolitic condensation of various silicone precursors. In early processes of preparation of silicone resins sodium silicate and various chlorosilanes were used as starting materials. Although the starting materials were the least expensive ones (something typical for industry), structural control of the product was very difficult. More recently, a less reactive tetraethoxysilane - (TEOS) or ethyl polysilicate and various disiloxanes are used as starting materials. Sodium silicate, also known as water glass, is a compound used in cements and textile processing. ...


  Results from FactBites:
 
Silicone - Wikipedia, the free encyclopedia (474 words)
Silicones, or polysiloxanes, are inorganic polymers consisting of a silicon-oxygen backbone (...-Si-O-Si-O-Si-O-...) with side groups attached to the silicon atoms.
Silicone is often mistaken colloquially for elemental silicon, because of the similarity in pronunciation and spelling, but they are entirely different.
A true silicone group has a double bond between oxygen and silicon (see figure), like a ketone group with Si in place of C (the same terminology is used for compounds such as silane, which is an analogue of methane).
Chemistry, Properties and Applications of Silicones (797 words)
Silicon resins are prepared by hydrolysis of a mixture of difunctional and trifunctional chlorosilanes containing methyl or/and phenyl groups.
Silicone resins are also used in electrical impregnating and insulation applications: they give effective protection against weathering and high temperature.
Special silicone resins are used in the water repellent treatment of construction materials, of façades and in the consolidation of ancient monuments.
  More results at FactBites »


 

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