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Encyclopedia > Single bond
Covalently bonded hydrogen and carbon in a molecule of . One way of representing covalent bonding in a molecule is with a .
Covalently bonded hydrogen and carbon in a molecule of methane. One way of representing covalent bonding in a molecule is with a dot and cross diagram.

Covalent bonding is a form of chemical bonding characterized by the sharing of one or more pairs of electrons between atoms, in order to produce a mutual attraction, which holds the resultant molecule together. Atoms tend to share electrons in such a way that their outer electron shells are filled. Such bonds are always stronger than the intermolecular hydrogen bond and similar in strength to or stronger than the ionic bond. from meta, Ive removed the title from the diagram to a) reduce size -hence faster download b) allow title to be altered on the page in future if required by changing the caption on the table. ... The simplest hydrocarbon, methane, is a gas with a chemical formula of CH4. ... A dot and cross diagram of a molecule of water showing the outer shells of each atom. ... In chemistry, a chemical bond is the force, which holds together atoms in molecules or crystals. ... Properties The electron (sometimes called negatron; commonly represented as e−) is a subatomic particle. ... Properties For alternative meanings see atom (disambiguation). ... An energy level is a quantified stable energy, which a physical system can have; the term is most commonly used in reference to the electron configuration of electrons, in atoms or molecules. ... Intermolecular forces are electromagnetic forces which act between molecules or between widely separated regions of a macromolecule. ... http://www. ... An ionic bond can be formed after two or more atoms give up (or gain) electrons, so as to become ions. ...


Covalent bonding most frequently occurs between atoms with similar (high) electronegativities, where to completely remove an electron from one atom requires too much energy. Covalent bonds are more common between non-metals, whereas ionic bonding is more common between a metal atom and a non-metal atom. Electronegativity is a measure of the attraction that an atom has for the bonding pair of electrons in a covalent bond. ... In chemistry, a metal (Greek: Metallon) is an element that readily forms ions (cations) and has metallic bonds, and it is sometimes said that it is similar to a cation in a cloud of electrons. ...


Covalent bonding tends to be stronger than other types of bonding, such as ionic bonding. Unlike ionic bonds, where ions are held together by a non-directional coulombic attraction, covalent bonds are highly directional. As a result, covalently bonded molecules tend to form in a relatively small number of characteristic shapes, exhibiting specific bonding angles. Electrostatics is the branch of physics that deals with the force exerted by a static (i. ...

Contents

History of the covalent bond

The idea of covalent bonding can be traced to Gilbert N. Lewis, who in 1916 described the sharing of electron pairs between atoms. He introduced the so called Lewis Notation or Electron Dot Notation in which valence electrons (those in the outer shell) are represented as dots around the atomic symbols. Pairs of electrons located between atoms represent covalent bonds. Multiple pairs represent multiple bonds, such as double and triple bonds. Some examples of Electron Dot Notation are shown in the following figure. An alternate form, in which bond-forming electron pairs are represented as solid lines, is shown in blue. PNG version of Electron_dot. ... Lewis in the Berkeley Lab Gilbert Newton Lewis (October 23, 1875-March 23, 1946) was a famous physical chemist. ... 1916 is a leap year starting on Saturday (link will take you to calendar) Events January-February January 1 -The first successful blood transfusion using blood that had been stored and cooled. ... Categories: Chemistry stubs | Chemistry ... Categories: Chemistry stubs | Chemistry ...


While the idea of shared electron pairs provides an effective qualitative picture of covalent bonding, quantum mechanics is needed to understand the nature of these bonds and predict the structures and properties of simple molecules. Heitler and London are credited with the first successful quantum mechanical explanation of a chemical bond, specifically that of molecular hydrogen, in 1927. Their work was based on the valence bond model, which assumes that a chemical bond is formed when there is good overlap between the atomic orbitals of participating atoms. These atomic orbitals are known to have specific angular relationships between each other, and thus the valence bond model can successfully predict the bond angles observed in simple molecules. Fig. ... Fritz London (March 7, 1900 in Breslau, Germany-March 30, 1954 in Durham, North Carolina, USA) is a German-American physicist. ... Molecular hydrogen, H2, is a molecule formed from two atoms of hydrogen. ... 1927 was a common year starting on Saturday (link will take you to calendar). ... An atomic orbital is the description of the behavior of an electron in an atom according to quantum mechanics. ...


Bond order

Bond order is the scientific term used to describe the number of pairs of electrons shared between atoms forming a covalent bond. The most common type of covalent bond is the single bond, the sharing of only one pair of electrons between two individual atoms. All bonds with more than one shared pair are called multiple covalent bonds. The sharing of two pairs is called a double bond and the sharing of three pairs is called a triple bond. An example of a double bond is nitrous acid (between N and O), and an example of a triple bond is in hydrogen cyanide (between C and N).


Quadruple bonds, though rare, also exist. Both carbon and silicon can theoretically form these; however, the formed molecules are explosively unstable. Stable quadruple bonds are observed as transition metal-metal bonds, usually between two transition metal atoms in organometallic compounds. General Name, Symbol, Number Carbon, C, 6 Chemical series Nonmetals Group, Period, Block 14 (IVA), 2, p Density, Hardness 2267 kg/m3 0. ... General Name, Symbol, Number silicon, Si, 14 Series metalloid Group, Period, Block 14 (IVA), 3, p Density, Hardness 2330 kg/m3, 6. ...


Sextuple bonds of order 6 have also been observed in transition metals in the gaseous phase and are even more rare.


A special case is called a dative covalent bond, also known as a coordinate covalent bond, which occurs when one atom gives both of the electrons in the bond. A coordinate covalent bond (also known as dative covalent bond) is a special type of covalent bond in which the shared electrons come from one of the atoms only. ... A coordinate covalent bond (also known as dative covalent bond) is a special type of covalent bond in which the shared electrons come from one of the atoms only. ...


Resonance

Some structures can have more than one valid Lewis Dot Structure; for example, Ozone, O3. The LDS tells us the center O will have a single bond with one O and a double bond with the other O. However, it does not tell us which O should receive the double bond, and, as a result, the first O and the second O have equal chance of having the double bond. These two structures are called resonance structures. In actuality, the true structure is a resonance hybrid between all of its resonance structures. In our example, instead of having one double bond and one single bond, there are actually two 1.5 bonds with approximately three electrons in each at all times. Resonance structures are diagrammatic tools in organic chemistry to symbolize resonant bonds between atoms in molecules. ...


A special resonance case is exhibited in aromatic rings of atoms; for example, Benzene. Aromatic rings are composed of atoms arranged in a circle (held together by covalent bonds) that alternate between single and double bonds according to their LDS. In actuality, the electrons tend to be disambiguously spaced out evenly within the ring of atoms. Electrons in aromatic structures are often represented with a ring inside of the circle of atoms instead of lines or dots. In chemistry, an aromatic molecule is one in which electrons are free to cycle around circular arrangements of atoms, which are alternately singly and doubly bonded to one another. ...


Current theory

Today the valence bond model has been supplemented with the molecular orbital model. In this model, as atoms are brought together, the atomic orbitals interact to form hybrid molecular orbitals. These molecular orbitals are a cross between the original atomic orbitals and generally extend between the two bonding atoms. In quantum chemistry, molecular orbitals are the statistical states electrons can have within molecules. ...


Using quantum mechanics it is possible to calculate the electronic structure, energy levels, bond angles, bond distances, dipole moments, and frequency spectra of simple molecules with a high degree of accuracy. Currently, bond distances and angles can be calculated as accurately as they can be measured (distances to a few pm and bond angles to a few degrees). For the case of small molecules, energy calculations are sufficiently accurate to be useful for determining thermodynamic heats of formation and kinetic activation energy barriers.


  Results from FactBites:
 
Bond (chemistry) - ninemsn Encarta (1649 words)
When a bond is formed between atoms, energy is normally given out because the resulting compound is at a lower energy level, and therefore more stable, than the original atoms.
The energy required to break a bond is called its bond energy (or bond enthalpy), and is a useful quantity when the stability of compounds is being studied.
Covalent bonds are formed when atoms share electrons, one from each atom in a single bond, to form electron pairs, usually making their outermost shells up to eight electrons by this means.
  More results at FactBites »


 

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