| Sodium chlorite | | Image:Sodium chlorite.jpg | | General | | Systematic name | Sodium chlorite | | Other names | Sodium chlorate(III) | | Molecular formula | NaClO2 | | Molar mass | 90.44 g/mol | | Appearance | white solid | | CAS number | [7758-19-2] | | Properties | | Density and phase | 2.5 g/cm3, solid | | Solubility in water | 39 g/100 ml (17 °C) | | Melting point | 180–200 °C decomp. | | Structure | Coordination geometry | ? | | Crystal structure | ? | | Hazards | | MSDS | External MSDS | | EU classification | not listed | | NFPA 704 | | | Flash point | non flammable | | RTECS number | VZ4800000 | | Supplementary data page | Structure and properties | n, εr, etc. | Thermodynamic data | Phase behaviour Solid, liquid, gas | | Spectral data | UV, IR, NMR, MS | | Related compounds | | Other anions | Sodium chloride Sodium hypochlorite Sodium chlorate Sodium perchlorate | | Other cations | Potassium chlorite Barium chlorite | | Related compounds | Chlorine dioxide Chlorous acid | Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references | Sodium chlorite is a chemical compound used in the manufacture of paper. IUPAC nomenclature is a system of naming chemical compounds and of describing the science of chemistry in general. ...
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Molar mass is the mass of one mole of a chemical element or chemical compound. ...
CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences, mixtures and alloys. ...
In physics, density is mass m per unit volume V. For the common case of a homogeneous substance, it is expressed as: where, in SI units: Ï (rho) is the density of the substance, measured in kg·m-3 m is the mass of the substance, measured in kg V is...
In the physical sciences, a phase is a set of states of a macroscopic physical system that have relatively uniform chemical composition and physical properties (i. ...
It has been suggested that this article or section be merged with Solution. ...
This article describes water from a scientific and technical perspective. ...
The melting point of a crystalline solid is the temperature at which it changes state from solid to liquid. ...
The coordination geometry of an atom is the geometrical pattern formed by its neighbors in a molecule or a crystal. ...
Enargite crystals In mineralogy and crystallography, a crystal structure is a unique arrangement of atoms in a crystal. ...
An example MSDS in a US format provides guidance for handling a hazardous substance and information on its composition and properties. ...
Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (as amended) is the main European Union law concerning chemical safety. ...
NFPA 704 is a standard maintained by the U.S. National Fire Protection Association. ...
Image File history File links NFPA_704. ...
The flash point of a flammable liquid is the lowest temperature at which it can form an ignitable mixture with air. ...
RTECS, also known as Registry of Toxic Effects of Chemical Substances, is a database of toxicity information compiled from the open scientific literature that is available for charge. ...
The refractive index (or index of refraction) of a medium is a measure for how much the speed of light (or other waves such as sound waves) is reduced inside the medium. ...
The relative dielectric constant of a material under given conditions is a measure of the extent to which it concentrates electrostatic lines of flux. ...
Ultraviolet-Visible Spectroscopy or Ultraviolet-Visible Spectrophotometry (UV/ VIS) involves the spectroscopy of photons (spectrophotometry). ...
Infrared spectroscopy (IR Spectroscopy) is the subset of spectroscopy that deals with the IR region of the EM spectrum. ...
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Mass spectrometry (also known as mass spectroscopy (deprecated)[1] or informally, mass-spec and MS) is an analytical technique used to measure the mass-to-charge ratio of ions. ...
An electrostatic potential map of the nitrate ion (NO3â). Areas coloured red are lower in energy than areas colored yellow An ion is an atom or group of atoms which have lost or gained one or more electrons, making them negatively or positively charged. ...
Jordanian and Israeli salt evaporation ponds at the south end of the Dead Sea Sodium chloride, also known as common salt, table salt, or halite, is a chemical compound with the formula NaCl. ...
Sodium hypochlorite is a chemical compound with the formula NaClO. A solution of sodium hypochlorite is frequently used as a disinfectant and as a bleaching agent; indeed, often it is simply called bleach, though other chemicals are sometimes given that name as well. ...
Sodium chlorate (NaClO3) is an oxidizing agent. ...
Sodium perchlorate is a perchlorate of sodium and has the formula NaClO4. ...
An electrostatic potential map of the nitrate ion (NO3â). Areas coloured red are lower in energy than areas colored yellow An ion is an atom or group of atoms which have lost or gained one or more electrons, making them negatively or positively charged. ...
Chlorine dioxide is a reddish-yellow gas which is one of several known oxides of chlorine. ...
Chlorous acid, HClO2, is unstable, but chlorites such as sodium chlorite can be considered the salts of this acid. ...
In chemistry, the standard state of a material is its state at 1 bar (100 kilopascals) and 25 degrees Celsius (298. ...
A blank sheet of paper Paper is a commodity of thin material produced by the amalgamation of fibers, typically vegetable fibers composed of cellulose, which are subsequently held together by hydrogen bonding. ...
Manufacture
The free acid, chlorous acid, HClO2, is only stable at low concentrations. Since it cannot be concentrated, it is not a commercial product. However, the corresponding sodium salt, sodium chlorite, NaClO2 is stable and inexpensive enough to be commercially available. The corresponding salts of heavy metals (Ag+, Hg+, Tl+, Pb2+, and also Cu2+ and NH4+) decompose explosively with heat or shock. Sodium chlorite is derived indirectly from sodium chlorate, NaClO3. First, the explosively unstable gas chlorine dioxide, ClO2 is produced by reducing sodium chlorate in a strong acid solution with a suitable reducing agent (for example, sodium chloride, sulfur dioxide, or hydrochloric acid). The chlorine dioxide is then absorbed into an alkaline solution and reduced with hydrogen peroxide, H2O2 yielding sodium chlorite. How is it possible to reduce anything with H2O2? Sodium chlorate (NaClO3) is an oxidizing agent. ...
Chlorine dioxide is a reddish-yellow gas which is one of several known oxides of chlorine. ...
Chlorine dioxide is a reddish-yellow gas which is one of several known oxides of chlorine. ...
Hydrogen peroxide (H2O2) is a very pale blue liquid which appears colourless in a dilute solution, slightly more viscous than water. ...
Usage The main application of sodium chlorite is the generation of chlorine dioxide for bleaching and stripping of textiles, pulp, and paper. It is also used for disinfection in a few municipal water treatment plants after conversion to chlorine dioxide. An advantage in this application, as compared to the more commonly used chlorine, is that trihalomethanes are not produced from organic contaminants. Sodium chlorite, NaClO2 also finds application as a component in therapeutic rinses, mouthwashes, toothpastes and gels, mouth sprays chewing gums and lozenges, and also in contact lens cleaning solution under the trade name purite. Chlorine dioxide is a reddish-yellow gas which is one of several known oxides of chlorine. ...
In organic synthesis, sodium chlorite is frequently used for the oxidation of aldehydes to carboxylic acids. The reaction is usually performed in the presence of a chlorine scavenger. Organic synthesis is the construction of organic molecules via chemical processes. ...
An aldehyde. ...
Structure of a carboxylic acid The 3D structure of the carboxyl group A space-filling model of the carboxyl group Carboxylic acids are organic acids characterized by the presence of a carboxyl group, which has the formula -C(=O)OH, usually written -COOH or -CO2H. [1] Carboxylic acids are Bronsted...
Sodium chlorite, like many oxidizing agents, should be protected from inadvertent contamination by organic materials to avoid the formation of an explosive mixture. European Union Chemical hazard symbol for oxidizing agents Dangerous goods label for oxidising agents An oxidizing agent (also called an oxidant or oxidizer) is referred to as A chemical compound that readily transfers oxygen atoms or A substance that gains electrons in a redox chemical reaction. ...
References: - "Chemistry of the Elements", N.N. Greenwood and A. Earnshaw, Pergamon Press, 1984.
- "Kirk-Othmer Concise Encyclopedia of Chemistry", Martin Grayson, Editor, John Wiley & Sons, Inc., 1985
External links - International Chemical Safety Card 1045
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