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Encyclopedia > Sulphide

In chemistry, a sulfide (sulphide in British and Canadian English) is a combination of sulfur with an oxidation number of -2, with another chemical element or a radical thereof. A few covalent sulfur compounds, such as carbon disulfide (CS2) and hydrogen sulfide (H2S) are also considered to be sulfides. It is also known as a thioether.


Hydrogen sulfide gas has the odor of rotten eggs, and is also highly toxic. It is formed biologically in the sediments of swamps and in the treatment of sewage sludge by anaerobic digestion of sulfur containing proteins, or bacterial reduction of sulfates. It also occurs in the emissions of some volcanoes, and as a byproduct of some industrial processes.

Contents

Uses

Natural occurrence

Many important metal ores are sulfides. Significant sulfide minerals include:

Safety

Many sulfides are significantly toxic by inhalation or injection, especially if the metal ion is toxic. Additionally many sulfides, when exposed to a strong mineral acid, will release toxic hydrogen sulfide - and this includes your stomach acids!


Also, many sulfides are somewhat flammable, and a few are highly flammable. When a sulfide burns, the fumes usually include toxic sulfur dioxide (SO2) gas.


See also


  Results from FactBites:
 
Hydrogen Sulphide 1 (438 words)
The hydrogen sulphide boundary is usually deepest in summer and shallowest in spring.
Garkavaya (unpublished data) recently recorded hydrogen sulphide concentrations of 1.5 to 2.25 ml/l in the lower water column on the north-western shelf at depths of 10-30 m.
Yet hydrogen sulphide on the shelf is still transitory, occurring primarily in summer and autumn, as intense water column mixing during winter and spring reoxygenates the bottom waters.
NASD: MANURE GAS -- HYDROGEN SULPHIDE (1024 words)
Hydrogen sulphide is produced continuously in all un-aerated manure storage systems, including shallow barn gutters, underground storage tanks or outside manure holding ponds or lagoons.
Because hydrogen sulphide is heavier than air, the gas has a tendency to accumulate on the surface of the manure.
During agitation, hydrogen sulphide is released from the manure in the same manner as carbon dioxide is liberated after shaking a carbonated soft drink.
  More results at FactBites »


 

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