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Encyclopedia > Sulphur hexafluoride

Sulfur hexafluoride (SF6) is a gas that consists of one part sulfur and six parts fluorine. It is colorless, odorless, non-toxic, and non-flammable. It is soluble in water and some other liquids. It is generally transported as a liquified compressed gas.


SF6 is used by the electricity industry as an insulator for circuit breakers, switch gear, and other electrical equipment, often replacing harmful PCBs. It is used in the semiconductor industry as an etchant. It has been used successfully as a tracer in oceanography. It is also emitted during the aluminium smelting process.


According to the Intergovernmental Panel on Climate Change (IPCC), SF6 is the most potent greenhouse gas that it has evaluated, with GWP (global warming potential) of 23,900 (CO2 is 1). However, because its mixing ratio in the atmosphere is low vs. CO2 (ca. 5 ppt vs. 365 ppm), its contribution to global warming is accordingly low.


Sulfur hexafluoride can affect the sound of a persons voice if it is inhaled in small quantities. When SF6 is inhaled, the pitch of a persons voice decreases dramatically because the speed of sound in SF6 is considerably less than it is in air. This is the opposite of what is heard when a person inhales helium.


Although this is a novel amusement, it can be somewhat dangerous as the SF6 displaces the oxygen needed for breathing. It is best to inhale only very small quantities at a time, and to allow several minutes of breathing fresh air for every one breath of SF6. Much more dangerous is attempting to inhale SF6 from the pressurised cylinders used for storage. The high flow rate can fatally overpressure the lungs and rupture the alveoli in a fraction of a second, without time to react. It is much safer to fill a small balloon with the gas, and then inhale from there.


External link

High GWP Gases and Climate Change (http://www.epa.gov/highgwp/scientific.html) from the U.S. EPA website.


  Results from FactBites:
 
Sulphur Mineral,Sulfur,Physical Characteristics of Sulfur,Sulphur Exporters (616 words)
The Romans used sulphur or fumes from its combustion as an insecticide and to purify a sick room and cleanse its air of evil (Cunningham 1935).
Sulphur is found in meteorites, volcanoes, hot springs, and as galena, gypsum, Epsom salts, and barite.
Although sulphur is in the same group in the periodic table as oxygen, there are more differences in the chemical characteristics of these elements than there are similarities.
Inorganic Fluorides - PSL1 (3791 words)
Gaseous inorganic fluoride compounds (e.g., hydrogen fluoride and sulphur hexafluoride) are primarily released into the atmosphere whereas particulate compounds (e.g., sodium fluoride and calcium fluoride) are released into aquatic and terrestrial environments.
Inorganic fluoride compounds (except sulphur hexafluoride) are not expected to remain in the troposphere very long or migrate to the stratosphere.
Even though sulphur hexafluoride is long-lived enough to migrate into the stratosphere, its contribution to stratospheric ozone depletion is considered minimal, because fluorine is much less efficient and less available than chlorine in the catalytic destruction of ozone in the stratosphere (Chu, 1991).
  More results at FactBites »


 

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