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Encyclopedia > Thermocouple

In electronics, thermocouples are a widely used type of temperature sensor and can also be used as a means to convert thermal potential difference into electric potential difference. They are cheap and interchangeable, have standard connectors, and can measure a wide range of temperatures. The main limitation is precision; system errors of less than 1 °C can be difficult to achieve. This article is about the engineering discipline. ... Temperature sensors are used in a wide variety of scientific and engineering applications, especially measurement systems. ... Potential difference is a quantity in physics related to the amount of energy that would be required to move an object from one place to another against various types of force. ... Celsius is, or relates to, the Celsius temperature scale (previously known as the centigrade scale). ...

Contents

Principle of operation

In 1821, the German-Estonian physicist Thomas Johann Seebeck discovered that when any conductor (such as a metal) is subjected to a thermal gradient, it will generate a voltage. This is now known as the thermoelectric effect or Seebeck effect. Any attempt to measure this voltage necessarily involves connecting another conductor to the "hot" end. This additional conductor will then also experience the temperature gradient, and develop a voltage of its own which will oppose the original. Fortunately, the magnitude of the effect depends on the metal in use. Using a dissimilar metal to complete the circuit will have a different voltage generated, leaving a small difference voltage available for measurement, which increases with temperature. This difference can typically be between 1 and 70 microvolts per degree Celsius for the modern range of available metal combinations. Certain combinations have become popular as industry standards, driven by cost, availability, convenience, melting point, chemical properties, stability, and output. Year 1821 (MDCCCXXI) was a common year starting on Monday (link will display the full calendar) of the Gregorian Calendar (or a common year starting on Saturday of the 12-day slower Julian calendar). ... Thomas Johann Seebeck (April 9, 1770 – December 10, 1831) was a physicist who in 1821 discovered the thermoelectric effect. ... The Peltier–Seebeck effect, or thermoelectric effect, is the direct conversion of heat differentials to electric voltage and vice versa. ...


It is important to note that thermocouples measure the temperature difference between two points, not absolute temperature. In traditional applications, one of the junctions — the cold junction — was maintained at a known (reference) temperature, while the other end was attached to a probe.


Thermocouples can be connected in series with each other to form a thermopile, where all the hot junctions are exposed to the higher temperature and all the cold junctions to a lower temperature. Thus, the voltages of the individual thermocouple add up, which allows for a larger voltage and increased power. With the radioactive decay of transuranic elements providing a heat source this arrangement has been used to power spacecraft on missions too far from the sun to utilize solar power.


Having available a known temperature cold junction, while useful for laboratory calibrations, is simply not convenient for most directly connected indicating and control instruments. They incorporate into their circuits an artificial cold junction using some other thermally sensitive device (such as a thermistor or diode) to measure the temperature of the input connections at the instrument, with special care being taken to minimize any temperature gradient between terminals. Hence, the voltage from a known cold junction can be simulated, and the appropriate correction applied. This is known as cold junction compensation.


Additionally, cold junction compensation can be performed by software. Device voltages can be translated into temperatures by two methods. Values can either be found in look-up tables or approximated using polynomial coefficients.


Usually the thermocouple is attached to the indicating device by a special wire known as the compensating or extension cable. The terms are specific. Extension cable uses wires of nominally the same conductors as used at the thermocouple itself. These cables are less costly than thermocouple wire, although not cheap, and are usually produced in a convenient form for carrying over long distances - typically as flexible insulated wiring or multicore cables. They are usually specified for accuracy over a more restricted temperature range than the thermocouple wires. They are recommended for best accuracy.


Compensating cables on the other hand, are less precise, but cheaper. They use quite different, relatively low cost alloy conductor materials whose net thermoelectric coefficients are similar to those of the thermocouple in question (over a limited range of temperatures), but which do not match them quite as faithfully as extension cables. The combination develops similar outputs to those of the thermocouple, but the operating temperature range of the compensating cable is restricted to keep the mis-match errors acceptably small.


The extension cable or compensating cable must be selected to match the thermocouple. It generates a voltage proportional to the difference between the hot junction and cold junction, and is connected in the correct polarity so that the additional voltage is added to the thermocouple voltage, compensating for the temperature difference between the hot and cold junctions.


Voltage-Temperature Relationship

The relationship between the temperature difference and the output voltage of a thermocouple is nonlinear and is approximated by a polynomial interpolation. In mathematics, a nonlinear system is one whose behavior cant be expressed as a sum of the behaviors of its parts (or of their multiples. ... In the mathematical subfield of numerical analysis, polynomial interpolation is the interpolation of a given data set by a polynomial. ...


T = sum_{n = 0}^N a_n v^n


The coefficients an are given for n from 0 to between 5 and 9.


To achieve accurate measurements the equation is usually implemented in a digital controller or stored in a lookup table. Some older devices use analog filters.


Different types

A variety of thermocouples are available, suitable for different measuring applications (industrial, scientific, food temperature, medical research, etc.). They are usually selected based on the temperature range and sensitivity needed. Thermocouples with low sensitivities (B, R, and S types) have correspondingly lower resolutions. Other selection criteria include the inertness of the thermocouple material, and whether or not it is magnetic. The thermocouple types are listed below with the positive electrode first, followed by the negative electrode. An electrode is an electrical conductor used to make contact with a metallic part of a circuit (e. ...

Type K -- Chromel (Nickel-Chromium Alloy) / Alumel (Nickel-Aluminium Alloy)
This is the most commonly used general purpose thermocouple. It is inexpensive and, owing to its popularity, available in a wide variety of probes. They are available in the −200 °C to +1200 °C range. The type K was specified at a time when metallurgy was less advanced than it is today and, consequently, characteristics vary considerably between examples. Another potential problem arises in some situations since one of the constituent metals is magnetic (Nickel). The characteristic of the thermocouple undergoes a step change when a magnetic material reaches its Curie point. This occurs for this thermocouple at 354°C. Sensitivity is approximately 41 µV/°C.
Type E -- Chromel / Constantan (Copper-Nickel Alloy)
Type E has a high output (68 µV/°C) which makes it well suited to cryogenic use. Additionally, it is non-magnetic.
Type J -- Iron / Constantan
Limited range (−40 to +750 °C) makes type J less popular than type K. The main application is with old equipment that cannot accept modern thermocouples. J types cannot be used above 760 °C as an abrupt magnetic transformation causes permanent decalibration. The magnetic properties also prevent use in some applications. Type J's have a sensitivity of ~52 µV/°C.
Type N -- Nicrosil (Nickel-Chromium-Silicon Alloy) / Nisil (Nickel-Silicon Alloy)
High stability and resistance to high temperature oxidation makes type N suitable for high temperature measurements without the cost of platinum (B, R, S) types. They can withstand temperatures above 1200 °C. Sensitivity is about 39 µV/°C at 900°C, slightly lower than a Type K. Designed to be an improved type K, it is becoming more popular.

Thermocouple types B, R, and S are all noble metal thermocouples and exhibit similar characteristics. They are the most stable of all thermocouples, but due to their low sensitivity (approximately 10 µV/°C) they are usually only used for high temperature measurement (>300 °C). Chromel is an alloy made of approximately 90 percent nickel and 10 percent chromium that is used to make the positive conductors of ANSI Type E and K thermocouples. ... For other uses, see Nickel (disambiguation). ... General Name, symbol, number chromium, Cr, 24 Chemical series transition metals Group, period, block 6, 4, d Appearance silvery metallic Standard atomic weight 51. ... An alloy is a homogeneous hybrid of two or more elements, at least one of which is a metal, and where the resulting material has metallic properties. ... Alumel is an alloy consisting of 95% nickel, 3% manganese, 2% aluminium and 1% silicon. ... Aluminum redirects here. ... The Curie point is a term in physics and materials science, named after Pierre Curie (1859-1906), and refers to a characteristic property of a ferromagnetic material. ... Constantan is an alloy usually consisting of 55% of copper and 45% of nickel (Cu55Ni45). ... For other uses, see Copper (disambiguation). ... Cryogenics is the study of very low temperatures or the production of the same, and is often confused with cryobiology, the study of the effect of low temperatures on organisms, or the study of cryopreservation. ... For other uses, see Iron (disambiguation). ... Not to be confused with Silicone. ... Nisil is an alloy of nickel and silicon. ... Noble metals are metals that are resistant to corrosion or oxidation, unlike most base metals. ...

Type B -- Platinum 30% Rhodium / Platinum 6% Rhodium
Suited for high temperature measurements up to 1800 °C. Type B thermocouples (due to the shape of their temperature-voltage curve) give the same output at 0 °C and 42 °C. This makes them useless below 50 °C.
Type R -- Platinum 13% Rhodium / Platinum
Suited for high temperature measurements up to 1600 °C. Low sensitivity (10 µV/°C) and high cost makes them unsuitable for general purpose use.
Type S -- Platinum 10% Rhodium / Platinum
Suited for high temperature measurements up to 1600 °C. Low sensitivity (10 µV/°C) and high cost makes them unsuitable for general purpose use. Due to its high stability, type S is used as the standard of calibration for the melting point of gold (1064.43 °C).
Type T -- Copper / Constantan
Suited for measurements in the −200 to 350 °C range. Often used as a differential measurement since only copper wire touches the probes. As both conductors are non-magnetic, type T thermocouples are a popular choice for applications such as electrical generators which contain strong magnetic fields. Type T thermocouples have a sensitivity of ~43 µV/°C.
Type C -- Tungsten 5% Rhenium / Tungsten 26% Rhenium
Suited for measurements in the 32 to 4208°F ((0 to 2320°C). This thermocouple is well-suited for vacuum furnaces at extremely high temperatures and must never be used in the presence of oxygen at temperatures above 500°F.
Type M -- Nickel Alloy 19 / Nickel-Molybdenum Alloy 20
This type is used in the vacuum furnaces as well for the same reasons as with type C above. Upper temperature is limited to 2500°F (~1400°C). Though it is a less common type of thermocouple, look-up tables to correlate temperature to EMF (milli-volt output) are available.

General Name, Symbol, Number platinum, Pt, 78 Chemical series transition metals Group, Period, Block 10, 6, d Appearance grayish white Standard atomic weight 195. ... General Name, Symbol, Number rhodium, Rh, 45 Chemical series transition metals Group, Period, Block 9, 5, d Appearance silvery white metallic Standard atomic weight 102. ... GOLD refers to one of the following: GOLD (IEEE) is an IEEE program designed to garner more student members at the university level (Graduates of the Last Decade). ... Constantan is an alloy usually consisting of 55% of copper and 45% of nickel (Cu55Ni45). ... ... For other uses, see Tungsten (disambiguation). ... General Name, Symbol, Number rhenium, Re, 75 Chemical series transition metals Group, Period, Block 7, 6, d Appearance grayish white Standard atomic weight 186. ... General Name, symbol, number oxygen, O, 8 Chemical series nonmetals, chalcogens Group, period, block 16, 2, p Appearance colorless (gas) pale blue (liquid) Standard atomic weight 15. ...

Identification

Thermocouple types can be identified based on wire insulation color.

Type Temperature range °c (continuous) Temperature range °c (short term) Tolerance class 1 (°c) Tolerance class 2 (°c) IEC Colour code BS Colour code ANSI Colour code
K 0 to +1100 -180 to +1300 -40 to +375 ± 1.5 °c, 375 to 1000 ± 0.004*[t]°c -40 to +333 ± 2.5 °c, 333 to 1200 ± 0.0075*[t]°c width=64
J 0 to +700 -180 to +800 -40 to +375 ± 1.5 °c, 375 to 750 ± 0.004*[t]°c -40 to +333 ± 2.5 °c, 333 to 750 ± 0.0075*[t]°c Image:Iectypejthermocouple.gif
N 0 to +1100 -270 to +1300 -40 to +375 ± 1.5 °c, 375 to 1000 ± 0.004*[t]°c -40 to +333 ± 2.5°c, 333 to 1200 ± 0.0075*[t]°c Image:Iectypenthermocouple.gif
R 0 to +1600 -50 to +1700 0 to +1100 ± 1.0°c, 1100 to 1600 ± (1+0.003 (t-1100))*[t]°c 0 to +600 ± 1.5 °c, 600 to 1600 ± 0.0025*[t]°c Image:Iectyperthermocouple.gif Not defined.
S 0 to 1600 -50 to +1750 0 to +1100 ± 1.0 °c, 1100 to 1600 ± (1+0.003(t-1100))*[t]°c 0 to +600 ± 1.5°c, 600 to 1600 ± 0.0025*[t]°c Image:Iectyperthermocouple.gif Not defined.
B +200 to +1700 0 to +1820 Not Available 600 to 1700 ± 0.0025*[t]°c No standard use copper wire No standard use copper wire Not defined.
T -185 to +300 -250 to +400 -40 to +125 ± 0.5°c, 125 to 350 ± 0.004*[t]°c -40 to +133 ± 1.0°c,133 to 350 ± 0.0075*[t]°c Image:Iectypetthermocouple.gif
E 0 to +800 -40 to +900 -40 to + 375 ± 1.5°c, 375 to 800 ± 0.004*[t]°c -40 to +333 ± 2.5°c, 333 to 900 ± 0.0075*[t]°c Image:Iectypeethermocouple.gif

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Applications

Thermocouples are most suitable for measuring over a large temperature range, up to 1800 K. They are less suitable for applications where smaller temperature differences need to be measured with high accuracy, for example the range 0–100 °C with 0.1 °C accuracy. For such applications, thermistors and RTDs are more suitable. NTC thermistor, bead type, insulated wires Thermistor symbol A thermistor is a type of resistor used to measure temperature changes, relying on the change in its resistance with changing temperature. ... A resistance temperature detector measures the relationship between electrical resistance and temperature. ...


Steel Industry

Type B, S, R and K thermocouples are used extensively in the steel and iron industry to monitor temperatures and chemistry throughout the steel making process. Disposable, immersible, Type S thermocouples are regularly used in the electric arc furnace process to accurately measure the steel's temperature before tapping. The cooling curve of a small steel sample can be analyzed and used to estimate the carbon content of molten steel. An electric arc furnace is a system that heats charged material by means of an electric arc. ...


Heating appliance safety

Many gas-fed heating appliances like ovens and water heaters make use of a pilot light to ignite the main gas burner as required. If the pilot light becomes extinguished for any reason, there is the potential for un-combusted gas to be released into the surrounding area, thereby creating both risk of fire and a health hazard. To prevent such a danger, some appliances use a thermocouple as a fail-safe control to sense when the pilot light is burning. The tip of the thermocouple is placed in the pilot flame. The resultant voltage, typically around 20 mV, operates the gas supply valve responsible for feeding the pilot. So long as the pilot flame remains lit, the thermocouple remains hot and holds the pilot gas valve open. If the pilot light goes out, the temperature will fall along with a corresponding drop in voltage across the thermocouple leads, removing power from the valve. The valve closes, shutting off the gas and halting this unsafe condition. This article is about the fossil fuel. ... The word appliance has several different areas of meaning, all usually referring to a device with a narrow function: One class of objects includes items that are custom-fitted to an individual for the purpose of correction of a physical or dental problem, such as prosthetic, orthotic appliances and dental... Oven depicted in a painting by Millet An oven is an enclosed compartment for heating, baking or drying. ... A trio of propane hot water heaters. ... A pilot light is a small gas flame, usually natural gas or liquefied petroleum gas, which is kept alight in order to provide an ignition source for a more powerful gas burner. ... This article is about The Stargate SG-1 episode. ...


Many systems (Millivolt control systems) extend this concept to the main gas valve as well. Not only does the voltage created by the pilot thermocouple activate the pilot gas valve, it is also routed through a thermostat to power the main gas valve as well. Here, a larger voltage is needed than in a pilot flame safety system described above, and a thermopile is used rather than a single thermocouple. Such a system requires no external source of electricity for its operation and so can operate during a power failure, provided all the related system components allow for this. Note that this excludes common forced air furnaces because external power is required to operate the blower motor, but this feature is especially useful for un-powered convection heaters. Bi-metallic thermostat for buildings A thermostat is a device for regulating the temperature of a system so that the systems temperature is maintained near a desired setpoint temperature. ... Battle between persian and greece forces took place at Thermoopile ...


A similar gas shut-off safety mechanism using a thermocouple is sometimes employed to ensure that the main burner ignites within a certain time period, shutting off the main burner gas supply valve should that not happen.


Out of concern for wasted energy, many newer appliances have switched to an electronically controlled pilot-less ignition, also called intermittent ignition. This eliminates the need for a standing pilot flame but loses the benefit of any operation without a continuous source of electricity.


Thermopile radiation sensors

Thermopiles are used for measuring the intensity of incident radiation, typically visible or infrared light, which heats the hot junctions, while the cold junctions are on a heat sink. It is possible to measure radiative intensities of only a few μW/cm2 with commercially available thermopile sensors. For example, laser power meters are based on such sensors. In physics, intensity is a measure of the time-averaged energy flux. ... For other uses, see Laser (disambiguation). ... In physics, power (symbol: P) is the rate at which work is performed or energy is transferred. ...


Radioisotope thermoelectric generators (RTGs)

Thermopiles can also be applied to generate electricity in radioisotope thermoelectric generators. // A radioisotope thermoelectric generator (RTG) is a simple electrical generator which obtains its power from radioactive decay. ...


See also

Rendition of an imaging bolometer from Los Alamos National Laboratory A bolometer is a device for measuring incident electromagnetic radiation. ... Resistance thermometers, also called resistance temperature detectors (RTDs), are temperature sensors that exploit the predictable change in electrical resistance of some materials with changing temperature. ... NTC thermistor, bead type, insulated wires Thermistor symbol A thermistor is a type of resistor used to measure temperature changes, relying on the change in its resistance with changing temperature. ... Battle between persian and greece forces took place at Thermoopile ... Bi-metallic thermostat for buildings A thermostat is a device for regulating the temperature of a system so that the systems temperature is maintained near a desired setpoint temperature. ...

External links


  Results from FactBites:
 
Thermocouple application note from Pico Technology (1843 words)
In practice, however, thermocouples junctions are made by welding the two metals together (usually by capacitive discharge) as this ensures that the performance is not limited by the melting point of solder.
If thermocouples with thin leads or long cables are needed, it is worth keeping the thermocouple leads short and then using thermocouple extension wire (which is much thicker, so has a lower resistance) to run between the thermocouple and measuring instrument.
A similar problem can occur if the thermocouple is not sufficiently immersed in the liquid, due to the cooler ambient air temperature on the wires, thermal conduction may cause the thermocouple junction to be a different temperature to the liquid itself.
Thermocouple (3826 words)
Thermocouples are calibrated in terms of the emf generated by the measuring junctions relative to the reference junction at 0ฐC; referencing at another temperature therefore does present problems.
If a thermocouple is to be used reliably for surface sensing, it must be in either exposed, welded junction form with very small thermal mass or be housed in a construction which permits true surface contact whilst attaching to the surface.
Thermocouples are ideal for such applications since their measuring junctions have a very small thermal mass and are physical small.
  More results at FactBites »


 

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