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Encyclopedia > Triphosgene
The chemical structure of triphosgene
The chemical structure of triphosgene
Space-filling model of triphosgene
Space-filling model of triphosgene

Triphosgene (Bis(trichloromethyl) carbonate, C3Cl6O3) is a chemical compound that is used as a substitute for phosgene. At room temperature, the compound is a white crystalline solid that decomposes around 130 °C. The decomposition temperature of impure samples is lower. Image File history File links Size of this preview: 800 × 369 pixelsFull resolution (1920 × 885 pixel, file size: 30 KB, MIME type: image/png) File historyClick on a date/time to view the file as it appeared at that time. ... Image File history File links Size of this preview: 800 × 369 pixelsFull resolution (1920 × 885 pixel, file size: 30 KB, MIME type: image/png) File historyClick on a date/time to view the file as it appeared at that time. ... Image File history File links Size of this preview: 800 × 471 pixelsFull resolution (1100 × 647 pixel, file size: 171 KB, MIME type: image/png) File historyClick on a date/time to view the file as it appeared at that time. ... Image File history File links Size of this preview: 800 × 471 pixelsFull resolution (1100 × 647 pixel, file size: 171 KB, MIME type: image/png) File historyClick on a date/time to view the file as it appeared at that time. ... Phosgene is a highly toxic chemical compound with the formula COCl2. ...


Being a solid, even small amounts may be weighed easily to add the exact desired amount to a reaction.


See also

Phosgene is a highly toxic chemical compound with the formula COCl2. ... Diphosgene (ClCO2CCl3) Diphosgene (Trichloromethyl chloroformate, ClCO2CCl3) is a chemical originally developed for chemical warfare, a few months after the first use of phosgene. ...

External links

  • Technical datasheet from Aldrich

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Sciencemadness Discussion Board - Powered by XMB (233 words)
I'm doing one reaction in which an aliphatic isocyanate is formed thro' reaction of Amine HCl with Triphosgene (0.35-4 eq.) in aq.
The reaction goes so well but only the problem here is I could not get rid of the excess triphosgene remained after the reaction.
Unless the isocyanate reacts faster you might use ammonia to remove triphosgene.
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