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Encyclopedia > Zirconia

Zirconia (ZrO2) is a white crystalline oxide of zirconium. Its commonest naturally occurring form, with a monoclinic crystalline structure, is called Baddeleyite. Its cubic crystalline form, called 'cubic zirconia', is rarely, if ever, found in nature, but is made in various colours for sale as a gemstone. General Name, Symbol, Number Zirconium, Zr, 40 Chemical series transition metals Group, Period, Block 4, 5, d Density, Hardness 6511 kg/m3, 5 Appearance Silvery white Atomic properties Atomic weight 91. ... General Name, Symbol, Number oxygen, O, 8 Chemical series nonmetals Group, Period, Block 16, 2, p Appearance colorless Atomic mass 15. ... An oxide is a chemical compound of oxygen with other chemical elements. ... General Name, Symbol, Number Zirconium, Zr, 40 Chemical series transition metals Group, Period, Block 4, 5, d Density, Hardness 6511 kg/m3, 5 Appearance Silvery white Atomic properties Atomic weight 91. ... In crystallography, the monoclinic crystal system is one of the 7 lattice point groups. ... Baddeleyite is a mineral that consists of zirconia (ZrO2). ... A round brilliant-cut cubic zirconia Cubic Zirconia (or CZ) is zirconium oxide (ZrO2), a mineral that is extremely rare in nature but is widely synthesized for use as a diamond simulant. ...


It is used as a refractory, in insulation, abrasives, enamels and glazes, in high-temperature fuel cells and oxygen sensors. Insulators are materials which prevent the flow of heat (thermal insulators) or electric charge (electrical insulators). ... An abrasive is a usually rough object that is used to smooth another through extensive rubbing. ... In a discussion of art or technology, enamel (or vitreous enamel, or porcelain enamel in American English) is the colorful result of fusion of powdered glass to a substrate through the process of firing, usually between 750 and 850 degrees Celsius. ... Painting technique Glaze is a term for painting with a transparent medium. ... A fuel cell is an electrochemical device similar to a battery, but differing from the latter in that it is designed for continuous replenishment of the reactants consumed; i. ... An oxygen sensor is an electronic device that measures the proportion of oxygen in the gas being analyzed. ...


Zirconia is one of the most studied ceramic materials. Pure ZrO2 has a monoclinic crystal structure at room temperature and transitions to tetragonal and cubic at increasing temperatures. The volume expansion caused by the cubic to tetragonal to monoclinic transformation induces very large stresses, and will cause pure ZrO2 to crack upon cooling from high temperatures. Several different oxides are added to zirconia to stabilize the tetragonal and/or cubic phases. magnesium oxide (MgO), yttrium oxide, (Y2O3), calcium oxide (CaO), and cerium oxide (CeO), amongst others. The word ceramic is derived from the Greek word Κεραμεικος (the name of a suburb of Athens), and in its strictest sense refers to clay in all its forms. ... In crystallography, the monoclinic crystal system is one of the 7 lattice point groups. ... Rose des Sables (Sand Rose), a formation of gypse crystal In mineralogy and crystallography, a crystal structure is a unique arrangement of atoms in a crystal. ... In crystallography, the tetragonal crystal system is one of the 7 lattice point groups. ... Cubic can mean several things: cubic polynomial, a polynomial with a degree of at most three. ... Cubic can mean several things: cubic polynomial, a polynomial with a degree of at most three. ... In crystallography, the tetragonal crystal system is one of the 7 lattice point groups. ... In crystallography, the monoclinic crystal system is one of the 7 lattice point groups. ... In crystallography, the tetragonal crystal system is one of the 7 lattice point groups. ... Cubic can mean several things: cubic polynomial, a polynomial with a degree of at most three. ... Magnesium oxide is a white solid mineral that occurs naturally as periclase and is a source of magnesium. ... Yttrium oxide is an oxide of yttrium. ... Calcium oxide (CaO), commonly known as lime, quicklime or burnt lime, is a widely used chemical compound. ... Cerium oxide, or ceric oxide, is a pale yellow-white powder, CeO2. ...


Zirconia is very useful in its 'stabilized' state. In some cases, the tetragonal phase can be metastable. If sufficient quantities of the metastable tetragonal phase is present, then an applied stress, magnified by the stress concentration at a crack tip, can cause the tetragonal phase to convert to monoclinic, with the associated volume expansion. This phase transformation can then put the crack into compression, retarding its growth, and enhancing the fracture toughness. This mechanism is known as transformation toughening, and significantly extends the reliability and lifetime of products made with stabilized zirconia. A special case of zirconia is that of tetragonal zirconia polycrystaline or TZP, which is indicative of polycrystalline zirconia composed of only the metastable tetragonal phase. Metastability is the ability of a non-equilibrium state to persist for a long period of time. ... A stress concentration is a phenomenon encounterered in mechanical engineering where an object under load has higher than average local stresses due to its shape. ...


The cubic phase of zirconia also has a very low thermal conductivity, which has led to its use as a thermal barrier coating or TBC in jet turbine and diesel engines to allow operation at higher temperatures. The laws of thermodynamics tell us that the higher temperature you operate an engine at, the greater the possible efficiency (see Carnot heat engine). As of 2004, a great deal of research is ongoing to improve the quality and durability of these coatings. A round brilliant-cut cubic zirconia Cubic Zirconia (or CZ) is zirconium oxide (ZrO2), a mineral that is extremely rare in nature but is widely synthesized for use as a diamond simulant. ... A Pratt and Whitney turbofan engine for the F-15 Eagle is tested at Robins Air Force Base, Georgia, USA. The tunnel behind the engine muffles noise and allows exhaust to escape. ... The diesel engine is a type of internal combustion engine; more specifically, it is a compression ignition engine, in which the fuel is ignited by being suddenly exposed to the high temperature and pressure of a compressed gas containing oxygen (usually atmospheric air), rather than a separate source of ignition... A heat engine is an engine that uses heat to produce mechanical work by carrying a working substance through a cyclic process. ...


Stabilized zirconia is used in oxygen sensors and fuel cell membranes because it has a unique ability to allow oxygen ions to move freely through the crystal structure at high temperatures.


Single crystals of the cubic phase of zirconia are commonly used as a substitute for diamond in jewelry. Like diamond, cubic zirconia has a cubic crystal structure and a high index of refraction. Discerning a good quality cubic zirconia gem from a diamond is difficult, and most jewelers will have a thermal conductivity tester to identify cubic zircona by its low thermal conductivity (diamond is a very good thermal conductor). This state of zirconia is commonly called "cubic zirconium" or "zircon" by jewellers, but these names are not chemically accurate. A round brilliant-cut cubic zirconia Cubic Zirconia (or CZ) is zirconium oxide (ZrO2), a mineral that is extremely rare in nature but is widely synthesized for use as a diamond simulant. ... A scattering of round-brilliant cut diamonds shows off the many reflecting facets. ... A round brilliant-cut cubic zirconia Cubic Zirconia (or CZ) is zirconium oxide (ZrO2), a mineral that is extremely rare in nature but is widely synthesized for use as a diamond simulant. ... The refractive index of a material is the factor by which electromagnetic radiation is slowed down (relative to vacuum) when it travels inside the material. ... It is the quantity of heat, Q, transmitted through a unit thickness, L, in a direction normal to a surface of unit area, A, due to a unit temperature gradient, ΔT, under steady state conditions and when the heat transfer is dependent only on the temperature gradient. ... A round brilliant-cut cubic zirconia Cubic Zirconia (or CZ) is zirconium oxide (ZrO2), a mineral that is extremely rare in nature but is widely synthesized for use as a diamond simulant. ... Jewellery (spelled jewelry in American English) consists of ornamental devices worn by persons, typically made with gems and precious metals. ...


Zirconia also occurs as a white powder and possesses both acidic and basic properties. On account of its infusibility, and brilliant luminosity when incandescent, it was used as an ingredient of sticks for limelight. An acid (often represented by the generic formula AH) is typically a water-soluble, sour-tasting chemical compound. ... The common (Arrhenius) definition of a base is a chemical compound that either donates hydroxide ions or absorbs hydrogen ions when dissolved in water. ... Limelight is a type of stage lighting once used in theatres and music halls. ...


Zirconium silicate (ZrSiO4), a natural mixture of zirconia and silica, is called zircon. Its transparent form is used as a gemstone, and its opaque form as a refractory. There is a red variety called hyacinth and a yellow or brown variety from Sri Lanka called jargon. The chemical compound silicon dioxide, also known as silica, is the oxide of silicon, chemical formula SiO2. ... Zircon dust Zircon is a mineral belonging to the group of nesosilicates. ... The name Hyacinth can refer to: the Hyacinth from Greek mythology. ... A jargon is a type of slang which is used in conjunction with a specific activity, e. ...


  Results from FactBites:
 
zirconia - definition of zirconia in Encyclopedia (479 words)
A special case of zirconia is that of tetragonal zirconia polycrystaline or TZP, which is indicative of polycrystalline zirconia composed of only the metastable tetragonal phase.
The cubic phase of zirconia also has a very low thermal conductivity, which has led to its use as a thermal barrier coating or TBC in jet turbine and diesel engines to allow operation at higher temperatures.
Zirconia also occurs as a white powder and possesses both acidic and basic properties.
Zirconia (274 words)
Zirconia is popularly known in its cubic crystal structure as a diamond simulant.
Zirconia is also very useful in its 'stabilized' state.
Its transparent form is used as a gemstone, and its opaque form as a refractory.
  More results at FactBites »


 

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