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Encyclopedia > Zinc sulfide
Zinc sulfide
Sphalerite, the more common polymorph of zinc sulfide Wurtzite, the less common polymorph of zinc sulfide

Above left: sphalerite, above right: wurtzite.

Systematic name Zinc
Other names Zinc sulphide
Molecular formula ZnS
Molar mass 97.475 g mol−1
Density 4.090 g cm−3
Solubility (water) insoluble
Melting point 1991 K
Boiling point 14839 °C
Band gap at 300 K 3.54 eV(cubic form)
3.91 eV (hexagonal form)
CAS number [1314-98-3]
Disclaimer and references

Zinc sulfide (or zinc sulphide) is a chemical compound with the formula ZnS. Zinc sulfide is a white to yellow colored powder or crystal. It is typically encountered in the more stable cubic form, known also as the mineral sphalerite. The hexagonal form is also known both as a synthetic material and as the mineral wurtzite. Both sphalerite and wurtzite are intrinsic, wide-bandgap semiconductors. The cubic form has a band gap of 3.54 eV at 300 K whereas the hexagonal form has a band gap of 3.91 eV. Image File history File links Download high-resolution version (1100x1073, 273 KB) File links The following pages on the English Wikipedia link to this file (pages on other projects are not listed): Sphalerite Zinc sulfide User:Benjah-bmm27/Gallery ... Image File history File links Size of this preview: 540 × 600 pixelsFull resolution (990 × 1100 pixel, file size: 223 KB, MIME type: image/png) File history Legend: (cur) = this is the current file, (del) = delete this old version, (rev) = revert to this old version. ... Sphalerite sample Another sphalerite sample The unit cell of sphalerite Sphalerite (ZnS) is a gay mineral that is the chief ore of zinc. ... Zinc sulfide is a chemical compound with the formula ZnS. Zinc sulfide is a white to yellow colored powder or crystal. ... IUPAC nomenclature is a systematic way of naming organic chemical compounds. ... A chemical formula (also called molecular formula) is a concise way of expressing information about the atoms that constitute a particular chemical compound. ... Molar mass is the mass of one mole of a chemical element or chemical compound. ... In physics, density is mass m per unit volume V. For the common case of a homogeneous substance, it is expressed as: where, in SI units: ρ (rho) is the density of the substance, measured in kg·m-3 m is the mass of the substance, measured in kg V is... Solubility refers to the ability for a given substance, the solute, to dissolve in a solvent. ... This article describes water from a scientific and technical perspective. ... The melting point of a crystalline solid is the temperature at which it changes state from solid to liquid. ... The boiling point of a substance is the temperature at which it can change its state from a liquid to a gas throughout the bulk of the liquid at a given pressure. ... This article or section does not adequately cite its references or sources. ... eV may stand for: electronvolt eingetragener Verein, i. ... CAS registry numbers are unique numerical identifiers for chemical compounds, polymers, biological sequences, mixtures and alloys. ... A chemical compound is a chemical substance of two or more different chemically bonded chemical elements, with a fixed ratio determining the composition. ... This article or section does not cite any references or sources. ... General Name, Symbol, Number zinc, Zn, 30 Chemical series transition metals Group, Period, Block 12, 4, d Appearance bluish pale gray Standard atomic weight 65. ... General Name, Symbol, Number sulfur, S, 16 Chemical series nonmetals Group, Period, Block 16, 3, p Appearance lemon yellow Standard atomic weight 32. ... Sphalerite sample Another sphalerite sample The unit cell of sphalerite Sphalerite (ZnS) is a gay mineral that is the chief ore of zinc. ... Zinc sulfide is a chemical compound with the formula ZnS. Zinc sulfide is a white to yellow colored powder or crystal. ... In solid state physics and related applied fields, the band gap is the energy difference between the top of the valence band and the bottom of the conduction band in insulators and semiconductors. ... A semiconductor is a fuckin solid whose electrical conductivity is in between that of a metal and that of an insulator, and can be controlled over a wide range, either permanently or dynamically. ... This article or section does not adequately cite its references or sources. ... An electronvolt (symbol: eV) is the amount of energy gained by a single unbound electron when it falls through an electrostatic potential difference of one volt. ... The kelvin (symbol: K) is a unit increment of temperature and is one of the seven SI base units. ... An electronvolt (symbol: eV) is the amount of energy gained by a single unbound electron when it falls through an electrostatic potential difference of one volt. ...


A transition from the sphalerite form to the wurtzite form occurs at around 1293.15 K. Sphalerite melts at 1991 K. It has a standard enthalpy of formation of −204.6 kJ mol−1 at 298 K. The kelvin (symbol: K) is a unit increment of temperature and is one of the seven SI base units. ... The kelvin (symbol: K) is a unit increment of temperature and is one of the seven SI base units. ... The standard enthalpy of formation of a compound is the change of enthalpy that accompanies the formation of 1 mole of that substance from its component elements, at their standard states (the most stable form of the element at 25 degrees Celsius and 100 kilopascals). ... The joule (IPA pronunciation: or ) (symbol: J) is the SI unit of energy. ... The mole (symbol: mol) is the SI base unit that measures an amount of substance. ...


Applications

ZnS was used by Ernest Rutherford and others in the early years of nuclear physics as a scintillation detector, because it emits light on excitation by x-rays or electron beam, making it useful for x-ray screens and cathode ray tubes. It also exhibits phosphorescence due to impurities on illumination with blue or ultraviolet light. Ernest Rutherford, 1st Baron Rutherford of Nelson OM PC FRS (30 August 1871 - 19 October 1937), widely referred to as Lord Rutherford, was a nuclear physicist who became known as the father of nuclear physics. ... Nuclear physics is the branch of physics concerned with the nucleus of the atom. ... A scintillator is a device or substance that absorbs high energy (ionizing) electromagnetic or charged particle radiation then, in response, fluoresces photons at a characteristic Stokes-shifted (longer) wavelength, releasing the previously absorbed energy. ... In the NATO phonetic alphabet, X-ray represents the letter X. An X-ray picture (radiograph) taken by Röntgen An X-ray is a form of electromagnetic radiation with a wavelength approximately in the range of 5 pm to 10 nanometers (corresponding to frequencies in the range 30 PHz... A charged particle beam is a group of electrically charged particles that have approximately the same kinetic energy and move in approximately the same direction. ... Cathode ray tube employing electromagnetic focus and deflection Cutaway rendering of a color CRT Electron guns Electron beams Focusing coils Deflection coils Anode connection Mask for separating beams for red, green, and blue part of displayed image Phosphor layer with red, green, and blue zones Close-up of the phosphor... Phosphorescent powder under visible light, ultraviolet light, and total darkness. ... “UV” redirects here. ...


Zinc sulfide, with addition of few ppm of suitable activator, is used as phosphor in many applications, from cathode ray tubes through x-ray screens to glow in the dark products. When silver is used as activator, the resulting color is bright blue, with maximum at 450 nm. Manganese yields an orange-red color at around 590 nm. Copper provides long glow time and the familiar glow-in-the-dark greenish color. Copper doped zinc sulfide (ZnS:Cu) is used also in electroluminescent panels. Parts per million (ppm) is a measure of concentration that is used where low levels of concentration are significant. ... Green screen A phosphor is a substance that exhibits the phenomenon of phosphorescence (sustained glowing after exposure to light or energised particles such as electrons). ... Cathode ray tube employing electromagnetic focus and deflection Cutaway rendering of a color CRT Electron guns Electron beams Focusing coils Deflection coils Anode connection Mask for separating beams for red, green, and blue part of displayed image Phosphor layer with red, green, and blue zones Close-up of the phosphor... In the NATO phonetic alphabet, X-ray represents the letter X. An X-ray picture (radiograph) taken by Röntgen An X-ray is a form of electromagnetic radiation with a wavelength approximately in the range of 5 pm to 10 nanometers (corresponding to frequencies in the range 30 PHz... Phosphorescence is a radiative transition involving a change in the spin multiplicity of a molecule. ... General Name, Symbol, Number silver, Ag, 47 Chemical series transition metals Group, Period, Block 11, 5, d Appearance lustrous white metal Standard atomic weight 107. ... A nanometre (American spelling: nanometer, symbol nm) is a unit of length in the metric system, equal to one thousand-millionth of a metre, which is the current SI base unit of length. ... General Name, Symbol, Number manganese, Mn, 25 Chemical series transition metals Group, Period, Block 7, 4, d Appearance silvery metallic Standard atomic weight 54. ... General Name, Symbol, Number copper, Cu, 29 Chemical series transition metals Group, Period, Block 11, 4, d Appearance metallic pinkish red Standard atomic weight 63. ... Animation of LCD, both unlit and with electroluminiscent backlight switched on Electroluminescence (EL) is an optical phenomenon and electrical phenomenon where a material emits light in response to an electric current passed through it, or to a strong electric field. ...


Zinc sulfide is also used as an infrared optical material, transmitting from visible wavelengths to over 12 micrometres. It can be used planar as an optical window or shaped into a lens. It is made as microcrystalline sheets by the synthesis from H2S gas and zinc vapour and sold as FLIR (Forward Looking IR) grade ZnS a pale milky yellow visibly opaque form. This material when hot isostatically pressed (HIPed) can be converted to a water-clear form known as Cleartran (trademark). Early commercial forms were marketed as Irtran-2 but this designation is now obsolete. Image of two girls in mid-infrared (thermal) light (false-color) Infrared (IR) radiation is electromagnetic radiation of a wavelength longer than that of visible light, but shorter than that of radio waves. ... The wavelength is the distance between repeating units of a wave pattern. ... A micrometre (American spelling: micrometer, symbol µm) is an SI unit of length equal to one millionth of a metre, or about a tenth of the diameter of a droplet of mist or fog. ... In astronomy, the optical window is that portion of the electromagnetic spectrum that passes through the atmosphere all the way to the ground. ... A lens. ... A manufacturing process, where materials are pressed into shape. ...


It can be doped as both n-type semiconductor and p-type semiconductor, which is unusual for the II-VI semiconductors. ZnS is a covalently bonded solid. In semiconductor production, doping refers to the process of intentionally introducing impurities into an intrinsic semiconductor in order to change its electrical properties. ... An N-type semiconductor is obtained by carrying out a process of doping, that is adding a certain type of atoms to the semiconductor in order to increase the number of free (in this case negative) charge carriers. ... A P-type semiconductor is obtained by carrying out a process of doping, that is adding a certain type of atoms to the semiconductor in order to increase the number of free (in this case positive) charges. ... II-VI semiconductors are a family of semiconductors, which are formed by sandwiching two elements from groups II and VI of the periodic table each. ... Covalent bonding is a form of chemical bonding that is characterized by the sharing of pairs of electrons between atoms, or sometimes between atoms and other covalent bonds. ...


See also

Zinc oxide is a chemical compound with formula ZnO. It is nearly insoluble in water but soluble in acids or alkalis. ... Zinc selenide (ZnSe), is a light yellow binary solid compound. ... Cadmium sulfide (UK English sulphide), the mineral greenockite, is an hexagonal, yellowish crystal with specific gravity of 4. ...

External links

  • Composition of CRT phosphors
  • IR filters University of Reading

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